• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.165-173
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• 2020

The activity of living microorganism directly or indirectly affects to the biomineralization in sediments and rocks that display the unique biotic structure. Minerals in the biotic structures showed unique properties and bypass the thermodynamic and kinetic barriers. Therefore, investigations on the biotically induced microstructure is essential to identify the new mineral formation mechanism by analyzing crystal structures and morphology at a nano-scale. The significant implication as well as advantages of using scanning electron microscopy to characterize the biotic structures were discussed in this paper for the examples of hydrothermal vent area microbial mat and deep-sea ferromanganese crust sample.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.293-305
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• 2020

An eruption of Taal Volcano in the Philippines began on January 12, 2020. The Philippine Institute of Volcanology and Seismology (PHIVOLCS) subsequently issued an Alert Level 4, indicating that "a hazardous explosive eruption is possible within hours to days." It was a phreatic eruption and phreatomagmatic eruption from the main crater that spewed ashes to Calabarzon, Metro Manila, some parts of Central Luzon, and Pangasinan in Ilocos Region, resulting in the suspension of classes, work schedules, and flights. By January 26, 2020, PHIVOLCS observed inconsistent, but decreasing volcanic activity in Taal, prompting the agency to downgrade its warning to Alert Level 3. After February 14, Alert status was set to Level 2 because of overall decreasing trend of volcanic activities, but it does not mean that the threat of an eruption has disappeared. In addition, the Alert Level can be raised to Alert Level 3 if there is a symptom of increasing unrest at any time.

• Particle and aerosol research
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• v.12 no.2
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• pp.43-50
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• 2016

The influence of basalt fibres on the compressive strength of the geopolymer type binders has been studied. For the experiments 2 types of the basalt fibres were used, namely chopped and spooled fibres. Both types of basalt fibres were 7-10 micron thick in diameter and cut into pieces of 6 mm length. The fibres were mixed with 1% weight to the fly ash powder, followed by the addition of the activator solution (8M NaOH). The pastes obtained were cured at $70^{\circ}C$ for 20 h revealing compact bodies. Compressive strength was measured after 7 days and microstructure observation performed with SEM. The cube bodies ($2{\times}2{\times}2cm$) reveal compressive strength of 47.25(4.03) MPa, while it decreased to 34.0(9.05) MPa in spooled basalt fibres and to 17.33(5.86) MPa in the chopped basalt fibres containing binder, i.e 76% and 36% of the strength without fibres, respectively. The much weaker compressive strength of the chopped fibres containing binder is related to the absence of significant adhesion between the geopolymer binder and the basalt fibres, forming voids instead. Alkali leaching effect of basalt fibres could probably explain the drop in the compressive strength with spooled and chopped fibres, respectively.

• Economic and Environmental Geology
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• v.19 no.2
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• pp.133-146
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• 1986

Primary uraninite and secondary uranium minerals such as torbernite, metatorbernite, tyuyamunite, metatyuyamunite, autunite and metaautunite have been identified from various types of uranium ores. Uranium minerals occur as accessory minerals in both the primary and secondary ores. Low·grade uranium ores consist of various kinds of primary and secondary minerals. Major constituent minerals of primary uranium ores are graphite. quartz. Ba-feldspar and sericite/muscovite, and accessories are calcite, chlorite, fluorapatite, barite, diopside, sphene, rutile, biotite, laumontite, heulandite, pyrite, sphalerite and chalcopyrite, and secondary minerals consist of kaolinite, gypsum and goethite. Uraninite grains occur as microscopic very fine-grained anhedral to euhedral disseminated particles in the graphitic matrix, showing well·stratified or zonal distribution of uranium on auto-radiographs of low-grade uranium ores. Some uraninite grains are closely associated with very fine-grained pyrite aggregates, showing an elliptical form parallel to the schistosity. Some uraninite grains include extremely fine-grained pyrite particle. Sphalerite and pyrite are often associated with uraninite in graphite-fluorapatite nodule. The size of uraninite is $2{\mu}m$ to $20{\mu}m$ in diameter. Low-grade uranium ores are classified into 5 types on the basis of geometrical pattern of mineralization. They are massive, banded, nodular, quartz or sulfide veinlet-rich and cavity filling types. Well-developed alternation of uranium-rich and uranium-poor layers, concentric distribution of uranium in graphite-fluorapatite nodule and geopetal fabrics due to the load cast of the nodule suggest that the uranium was originally deposited syngenetically. Uraninite crystals might have been formed from organo-uranium complex during diagenesis and recrystallized by metamorphism. Secondary uranium minerals such as torbernite, tyuyamunite and autunite have been formed by supergene leaching of primary ores and subsequent crystallization in cavities.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1171-1171
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• 2001

Quantitative analysis is an important requirement in exploration, mining and processing of minerals. There is an increasing need for the use of quantitative mineralogical data to assist with bore hole logging, deposit delineation, grade control, feed to processing plants and monitoring of solid process residues. Quantitative analysis using X-Ray Powder Diffraction (XRD) requires fine grinding and the addition of a reference material, or the application of Rietveld analysis to XRD patterns to provide accurate analysis of the suite of minerals present. Whilst accurate quantitative data can be obtained in this manner, the method is time consuming and limited to the laboratory. Mid infrared when combined with multivariant analysis has also been used for quantitative analysis. However, factors such as the absorption coefficients and refractive index of the minerals requires special sample preparation and dilution in a dispersive medium, such as KBr to minimize distortion of spectral features. In contrast, the lower intensity of the overtones and combinations of the fundamental vibrations in the near infrared allow direct measurement of virtually any solid without special sample preparation or dilution. Thus Near Infrared Spectroscopy (NIR) has found application for quantitative on-line/in line analysis and control in a range of processing applications which include, moisture control in clay and textile processing, fermentation processes, wheat analysis, gasoline analysis and chemicals and polymers. It is developing rapidly in the mineral exploration industry and has been underpinned by the development of portable NIR spectrometers and spectral libraries of a wide range of minerals. For example, iron ores have been identified and characterized in terms of the individual mineral components using field spectrometers. Data acquisition time of NIR field instruments is of the order of seconds and sample preparation is minimal. Consequently these types of spectrometers have great potential for in-line or on-line application in the minerals industry. To demonstrate the applicability of NIR field spectroscopy for quantitative analysis of minerals, a specific example on the quantification of lateritic bauxites will be presented. It has been shown that the application of Partial Least Squares regression analysis (PLS) to the NIR spectra can be used to quantify chemistry and mineralogy in a range of lateritic bauxites. Important, issues such as sampling, precision, repeatability, and replication which influence the results will be discussed.

• The Journal of the Petrological Society of Korea
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• v.8 no.2
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• pp.81-91
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• 1999

The area of the study is located in Ogcheon district, middle part of Ogcheon Fold Belt. The area is covered by metasedimentary rocks of Ogcheon Supergroup at northern, eastern and southern part. Jurassic Ogcheon granite which intruded into Ogcheon Supergroup at central part, was intruded by Cretaceous quartz porphyry at western part. The granite consists of quartz, plagioclase, alkali feldspar, biotite, sphene, apatite, epidote, opaque and so on. It is generally characterized by grey to light grey, medium-grained, mafic enclave and partly weak foliation. In terms of geochmical compositions, the granite is felsic, peraluminous, subalkaline and calc-alkaline, and it was differentiated from single granitic magma. It shows parallel LREE enrichment and HREE depletion patterns with 0.84 Eu negative anomaly, which has REE variation trend and anomaly value similar to Jurassic granites in Korea. From charactristics of petrology, mineralogy and geochmistry, it may be interpreted that the Ogcheon granite body was derived from melting of I-type crustal material related to syn-collisional tectonic setting and emplaced more or less rapidly into the Ogcheon Supergroup.

• Journal of the Mineralogical Society of Korea
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• v.5 no.2
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• pp.93-101
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• 1992

Several "Napseok" mines are distribute in the Miryang area where the volcanic rocks are hydrothermally altered. The "Napseok" are pyrophyllite and dickite, with a small amount of silicates such as quartz, illite, tosudite and dumortierite. Other associated minerals are oxides, hydroxides, sulfides, sulfates and phosphates. Pyrophyllite which occurs as 2M polytype exhibits that the basal spacing increases due to dehydroxylation at 750${\circ}C$. Halloysite shows tubular forms. Wavellite is precipitated in fissures during the latest stage of the hydrothermal alteration process. Five mineral zones, that is pyrophyllite-deckite, illite, halloysite, silica, and albite-chlorite zones, are recognized with decreasing alteration degree. Clay minerals were formed by leaching of Si and alkali ions fron the country rocks, considering mineral assemblages, pyrophyllite polytype and thermodynamical data reported in the literature, temperatures of formation of main clay deposits are assumed to be 270 to 350${\circ}C$.

• Economic and Environmental Geology
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• v.32 no.3
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• pp.293-306
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• 1999

The lower Permian jungseong Formation, Taebaegsan basin (Baegunsan Syncline), represents a coal-bearing siliciclastic succession which was later modified by the Songrim or Dabo orogeny. Sandstone perography and clay mineralogy were studied to understand the thermal history of the Jangseong Formation during basin evolution. Petrographic study indicates the Jangseong sandstones are composed of quartz, feldspar, lithic fragments (metamorphic and sedimetary), and varying proportions of matrix and cement. The dominance of quartz(<97%) over feldspar (<1%) and lithic fragments (<2%) classifies most Jangseong sandstones as quartz arenotes or quartzwackes, but lithic graywackes and sublithic arenite locally occur. The diagentic features of these sandstones include mechanical compaction, cemenation by quartz and clay minerals indentified in the Jangseong Formation by X-ray diffraction analysis are late-stage clay pore-filling. Clay minerals isdentified in the Jangseong Formation by X-ray diffaction analysis are illite, kaolinte, and pyrophyllite with a minor amount of chlorite and micas. The illite, kaolinite, and pyrophyllite appear to be largely autjigenic based on their well-crystallinity forms. There authigenic clay minerals form clay minerals form clay coats/rims and late-stage pore-filling cements, Illitecrystallinity shows that the Jangseong formation has been in late-diagenetic zone to early-epizone, which ranges in temperature from $200^{\circ}C$ to $300^{\circ}C$. In assition, kaolinite-pyrophyllite transition suggests that paleotemperature of the formation has reached at least $265^{\circ}C$. Such temperatureis likely to be consistent with homogenixation temperatures of fluid inclusions in quartz veins in the formation. Thus, the Jangseong Formation has been subjected to paleotemperature of about $265^{\circ}C$. The major heat source responsible for paleotemperature may be hydrothermal solutions. The passage of hydrothermal solutions was probably assisted by fractures created during the basin-modifying tectonism of the taebaegsan basin.

• Economic and Environmental Geology
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• v.23 no.1
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• pp.25-33
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• 1990

Gold-silver deposits of Deogheun and Beopjeon mines are composed of veins emplaced in Jurassic granite batholith. Based on ore structure and ore mineralogy, four distinct stages of mineral deposition are recognized in these ore deposits. Gold and silver minerals in Deogheun and Beopjeon-A ore deposits are precipitated in stage III and stage II, respectively. Mineral constituents of ores from these deposits are pyrite, sphalerite, arsenopyrite, pyrrhotite, chalcopyrite, galena, tetrahedrite, electrum, quartz and rhodochrosite. Cubanite, argentite and pyrargyrite occur only in Deogheun ore deposits. Ag content of electrum range from 42 to 66 atomic % in both ore deposits. Filling temperature of fluid inclusion from both ore deposits are as follows; stage I, $211-289^{\circ}$ ; stage II, $205-290^{\circ}$ ; stage III, $190-260^{\circ}$ ; stage IV, $136-222^{\circ}$ in Deogheun ore deposits. In Beopjeon-A ore deposits, stage I, $255-305^{\circ}$ ; stage II, $135-222^{\circ}$ ; stage III, $148-256^{\circ}$ ; stage IV, $103-134^{\circ}$. Salinities of fluid inclusions range from 1.6-8.5 wt. % equivalent NaCl in both ore deposits. Sulfur fugacities through stage II and III in Deogheun ore deposits inferred from data of mineral assemblage and fluid inclusion range from $10^{-11.0}-10^{-16.1}$1bars. Fluid pressure estimated from fluid inclusions which reveal boiling evidence range from 30-190 bars during mineralization in Deogheun ore deposits.

• Economic and Environmental Geology
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• v.30 no.5
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• pp.443-450
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• 1997

The main purpose of this study is to investigate mineralogical and chemical changes during natural weathering, and assess the mobility of major and trace elements. Yongwol power plant utilize anthracite coal which is mainly composed of illite, kaolinite, pyrophyllite and quartz in mineralogy. Coal and coal-derived fly ash samples were sampled by the electrostatic precipitator in Yongwol coal-fired power plant in Korea. Short term weathered fly ash were also collected in ash disposal mound, and two profile soil samples were taken from an ash near the power plant. Amorphous materials are the main component of the fly ash, and mullite, quartz, magnetite and heamatite are present in all coal-derived fly ash. In chemistry, Si and Al are the most abundant elements of the total content. The ash samples were fractionated into upper $90{\mu}m$ and under $45{\mu}m$ size. Finer particles show higher concentrations in metal contents including Co, Cr, Cu, Ni, V, Zn and Pb. Concentration of Zn and Pb are nearly 4 times higher concentration in the finer particles. For the profile samples, the concentrations of $SiO_2$, $Na_2O$, MgO and $K_2O$ generally show increasing trends with depth, whereas those of $Fe_2O_3$ and $TiO_2$ appear to decrease with depth. Content of MnO does not show any specific depth trend. For the trace elements, Co, Cu, Ni and V show increasing concentrations with depth.