• 콘크리트학회논문집
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• 제19권6호
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• pp.701-706
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• 2007

본 연구는 장기간 숏크리트의 강도를 유지할 수 있는 영구지보재로서 알칼리 프리계 및 시멘트 광물계 급결제를 사용한 적정 배합비의 고성능 숏크리트의 내구성을 평가하였다. 내구성 실험은 염소이온 투과 시험, 동결융해 반복 시험, 촉진 중성화 시험 및 숏크리트에 염해의 영향 실험을 실시하였다. 실험 결과 실리카퓸을 사용한 모든 배합이 낮은 투과성을 나타내었다. 실험 결과 실리카퓸을 사용한 모든 배합이 모두 낮은 투과성을 나타내었다. 또한 동결융해 300회 반복 후에 상대동탄성계수가 85% 이상을 초과하는 우수한 동결융해 저항성을 보였다. 촉진 중성화 시험 결과 급결제에 따른 영향은 나타나지 않았으며 실리카퓸을 사용한 배합에서 중성화 깊이가 약간 깊게 나타났다. 염해 환경에서는 어떠한 영향도 없었다. 따라서 본 연구에서의 고성능 숏크리트 배합은 우수한 내구 성능을 보여주었다.

• 한국산학기술학회논문지
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• 제19권2호
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• pp.623-631
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• 2018

공용중인 콘크리트 구조물의 내구성 연구는 한 가지 원인에 대한 단독열화 연구를 주로 연구하였지만 실제 구조물의 공용시기에는 두 가지 이상의 환경에 노출되어 있어 이러한 복합열화에 대한 관심이 최근 증가하고 있는 실정이다. 복합열화에 대해 일반적으로 염해와 동결융해에 대해서는 일부 연구가 진행되어 있지만 콘크리트의 양생 직후부터 발생하는 탄산화와 다른 내구성능저하에 대한 복합열화 연구는 매우 미흡한 실정이다. 특히, 탄산화를 중심으로 하는 복합열화는 탄산화의 경우 탄산화 진행시 콘크리트 조직이 치밀해진다는 문헌고찰에 따라 조직의 치밀해지는 이유로 연구가 미흡하다. 본 연구에서는 콘크리트의 탄산화 및 동결융해에 대한 복합열화를 평가 분석한 결과이다. 평가를 위하여 탄산화된 콘크리트를 동결융해 300싸이클까지 복합열화 시험을 실시하여 동탄성계수와 압축강도를 측정하였다. 그 결과 물-결합재비에 대한 영향 평가에서 35 %의 콘크리트가 55 %의 콘크리트에 비해 복합열화 성능이 낮은 것을 확인하였고, 광물질혼화재료를 사용한 경우 플라이애시와 고로슬래그미분말을 사용한 경우 동일 물-결합재비에서 보통포틀랜드 시멘트 사용 콘크리트보다 복합열화에 대한 성능이 개선되는 것으로 나타났다.

• 환경생물
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• 제34권2호
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• pp.73-78
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• 2016

Bhutanese forests have been well preserved and can sequester the atmospheric carbon (C). In spite of its importance, understanding Bhutanese forest C dynamics was very limited due to the lack of available data. However, forest C model can simulate forest C dynamics with comparatively limited data and references. In this study, we aimed to simulate Bhutanese forest C dynamics at 6 plots with the Forest Biomass and Dead organic matter Carbon (FBDC) model, which can simulate forest C cycles with small amount of input data. The total forest C stock ($Mg\;C\;ha^{-1}$) ranged from 118.35 to 200.04 with an average of 168.41. The C stocks ($Mg\;C\;ha^{-1}$) in biomass, litter, dead wood, and mineral soil were 3.40-88.13, 4.24-24.95, 1.99-20.31, 91.45-97.90, respectively. On average, the biomass, litter, dead wood, and mineral soil accounted for 36.0, 5.5, 2.5, and 56.0% of the total C stocks, respectively. Although our modeling approach was applied at a small pilot scale, it exhibited a potential to report Bhutanese forest C inventory with reliable methodology. In order to report the national forest C inventory, field work for major tree species and forest types in Bhutan are required.

• Ocean and Polar Research
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• 제25권4호
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• pp.653-662
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• 2003

Changes in the area of geo-ecosystem $(62^{\circ}09'S,\;58^{\circ}31'w)$ reflect climatic changes in the South Shetland Islands. Air temperature and deglaciation will increase. The ice-free space area at the SSSS 8- (ASPA 121) site has enlarged threefold during the last 21 years, thus creating conditions for inhabitation and succession. Wind, water and snow play important roles in transportation of geochemical components. They distribute nutrients, mineral substances, seeds, fragments of plants and animals, etc. Plant and animal colonization is patchy and it happens at random in an 'island' - like manner. The colonization pattern is dependant, to a high degree on physical factors. The newly uncovered ice-free areas are at first inhabited by a vascular plant known as the Deschampsia antarctica. The border of the land-oasis with Admiralty Bay is the place where the processes related to animal feeding at the sea and reproduction on the land take place. Bird colonies and pinniped lairs form centers of fertilization surrounded by high chemical gradients dependent on the direction of the flow of nutrients $(e.g.\;NH_4)$. During the last 25 years, the numbers of penguins in this region have decreased, and thus the amount of materials excreted on land has diminished. The numbers of fur seals change in multi-annual cycles, and their migration into this area is related to the E1 $Ni\~{n}o$ phenomenon. The numbers of elephant seals in the area did not change. Organic matter deposited by the sea onto the shore are a source of nutrients and deficient chemical elements on land. Mineral matter is washed out into the waters of Admiralty Bay. These processes change seasonally, and multi annually. Negative effects on the environment at Arctowski Station induced by man are slight, but noticeable nevertheless. Physical processes have the largest influence on the living conditions and distribution of plants and animals, and as a consequence, on the functioning of the geo-ecosystem in the coastal-shore zone of the Maritime Antarctic.

• 자원환경지질
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• 제4권2호
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• pp.77-90
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• 1971

About four hundred deposits of iron, talc, fluorite, tungsten, molybdenum, lead, zinc and other polymetallic mineral deposits were plotted on the Ore Distribution Map of the Ockcheon Geosynclinal Area. These mineral deposits plotted on the map can be divided into the several metallogenic zones by the consideration of their geologic background including the sedimentary and tectonic cycles and the igneous activities in the geosynclinal evolution, as follows: a. Chungju iron and talc zones. b. Cheong-san copper bearing iron sulphide zone c. Kumsan-Muju fluorite-polymetallic zones. d. Cheong-an Puyong and Ein Suckseong gold zone e. Hwang-gan Seolcheon and Sangju gold zones. Chungju iron zone originated in the iron bed in the Kemyongsan Series corresponding to the Pre-Ockcheon Cycle of evolution history. In early period of the Ockcheon Cycle, Hyangsanri quartzite and Munjuri phyllitic formation corresponding to the lower terrigenous sequence were not mineralized while the next sequence of the Samsungsan basic igneous-metamorphic formation and the Changri limestone formation were mineralized by the copper bearing iron sulphide and the fluorite-polymetallic deposits respectively. Two generations of the gold zones are recognized. The earlier generation distributes directionaly in the outside of the Ockcheon sedimentary belt was followed by the earlier grantitic invasion of Jurasic in age, while the later generation scatters at random which was related to the nondirectional Cretaceous granitic intrusion of the Post-Ockcheon Cycle. Conclusively speaking, it was disclosed that the endogenic mineralization in the Ockcheon geosyn clinal zone was not conspicuous in its inner sedimentary belt except its limestone area but in its outer peripheral granitic or gneissic zones, and the related igneous activities occured in the Post-Ockcheon Cycle of evolution history.

• Computers and Concrete
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• 제30권2호
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• pp.99-111
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• 2022

In this study, deep learning and k-Nearest Neighbor (kNN) models were used to estimate the sorptivity and freeze-thaw resistance of self-compacting mortars (SCMs) having binary and ternary blends of mineral admixtures. Twenty-five environment-friendly SCMs were designed as binary and ternary blends of fly ash (FA) and silica fume (SF) except for control mixture with only Portland cement (PC). The capillary water absorption and freeze-thaw resistance tests were conducted for 91 days. It was found that the use of SF with FA as ternary blends reduced sorptivity coefficient values compared to the use of FA as binary blends while the presence of FA with SF improved freeze-thaw resistance of SCMs with ternary blends. The input variables used the models for the estimation of sorptivity were defined as PC content, SF content, FA content, sand content, HRWRA, water/cementitious materials (W/C) and freeze-thaw cycles. The input variables used the models for the estimation of sorptivity were selected as PC content, SF content, FA content, sand content, HRWRA, W/C and predefined intervals of the sample in water. The deep learning and k-NN models estimated the durability factor of SCM with 94.43% and 92.55% accuracy and the sorptivity of SCM was estimated with 97.87% and 86.14% accuracy, respectively. This study found that deep learning model estimated the sorptivity and durability factor of SCMs having binary and ternary blends of mineral admixtures higher accuracy than k-NN model.

• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2741-2746
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• 2013

The immobilization of enzyme is one of the key issues both in the field of enzymatic research and industrialization. In this work, we reported a facile method to immobilize Candida Antarctica lipase B (CALB) in alginate carrier. In the presence of calcium cation, the enzyme-alginate suspension could be cross-linked to form beads with porous structure at room temperature, and the enzyme CALB was dispersed in the beads. Activity of the enzyme-alginate composite was verified by enzymatic hydrolysis reaction of p-nitrophenol butyrate in aqueous phase. The effects of reaction parameters such as temperature, pH, embedding and lyophilized time on the reactive behavior were discussed. Reuse cycle experiments for the hydrolysis of p-nitrophenol butyrate demonstrated that activity of the enzyme-alginate composite was maintained without marked deactivation up to 6 repeated cycles.

• 한국식물병리학회지
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• 제11권4호
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• pp.292-297
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• 1995

We developed an in vitro assay method for evaluating plant growth promotion and providing an evidence that the growth promotion is rendered by growth enhancing factors. The amendment of culture filtrates of Trichoderma harzianum T95 and Gliocladium virens G872 and G872B in Murashige and Skoog (MS) agar medium enhanced the cotyledon growth of cucumber in terms of fresh weight and primary leaf area of cucumber cotyledon cuttings, of which the treatment of G. virens G872B was the most effective. The mycelial culture filtrate of G872B was more effective in the growth promotion than its conidial germling filtrate. The addition of 1% sucrose in MS mineral medium with 0.1% culture filtrates of the antagonists (T95 and G872B) was optimum for enhancing the effect of the filtrates on the growth of cotyledon cuttings in vitro. When cucumber seeds treated with G872B, Pseudomonas putida Pf3 or the G872B-Pf3 mixture were planted in a greenhouse, the rate of seed germination, biomass of shoot and root, and yield of cucumber fruits were increased, especially by G872B or the G872B-Pf3 mixture. Correspondingly, cucumber fruit yields in early to middle-cycles of harvest were significantly greater in the plots of G872B than the control and Pf3-treated plots, and the final yield was highest in the plots of the G872B-Pf3 mixture applications.

• 한국지하수토양환경학회지:지하수토양환경
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• 제23권1호
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• pp.14-24
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• 2018

In soil washing, there are many variables including types of reagent and contaminant, washing time, soil-liquid ratio, washing cycles, washing agent concentrations, and etc. To identify the most influencing factors on soil washing process, regression analysis was performed for eight single variables and five combined variables. A quantitative model that employs W/H (molar ratio of washing agent to heavy metal) as a major variable was established based on the regression. The validity of the model was demonstrated by conducting lab experiments with Cu, Pb, Zn, Ni and As-contaminated soils, and various washing reagents including acetic acid, citric acid, malic acid, oxalic acid, ethylenediamine tetraacetic acid (EDTA) and nitriloacetic acid (NTA). The washing efficiencies were compared with the EDTA washing data reported in the literature. The correlation between W/H and removal efficiency was analyzed after dividing data into two groups according to the heavy metal mobility.

• Membrane and Water Treatment
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• 제8권6호
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• pp.575-590
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• 2017

PolyHIPEs membrane prepared with styrene (St), divinylbenzene (DVB), and ethylhexyl acrylate (EHA) can yield a unique pore structure provided by large voids highly interconnected by many small window throats. With the advantageous pore structure, PolyHIPE presents a potential as a support for carrier facilitated transport membrane. Tricaprylmethylammonium chloride (Aliquat 336) can be efficiently incorporated into the PolyHIPE membrane by a two-step solvent-nonsolvent method to obtain an Aliquat 336-immobilized PolyHIPE membrane with good stability. The study of Cr (VI) transport through Aliquat 336-immobilized PolyHIPE membrane indicates that the membrane has high initial flux and maxima stripping flux ($J_f^o=15.01({\mu}mol/m^2s)$, $J_s^{max}=6.15({\mu}mol/m^2s)$). The reusability study shows that the Aliquat 336-immobilized PolyHIPE membrane can maintain high Cr(VI) recovery efficiency even after 15 cycles of operations. The developed membrane was also used in the separation of Cr (VI) from other anions (i.e., $SO_4{^{2-}}$ and $NO_3{^-}$) and other cations (i.e., Ni (II), Mg (II) and Cu (II)) with good selectivity.