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Study on the Oxidative Polymerization of EDOT Induced by Graphene Oxide (산화 그래핀에 의한 EDOT의 산화중합에 관한 연구)

  • Kim, Min Chae;Park, Min Ui;Park, No Il;Lee, Seul Bi;Lee, Seong Min;Yang, So Yeon;Choi, Jong Hyuk;Chung, Dae-won
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.45-49
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    • 2016
  • In the presence of poly(4-styrene sulfonate) (PSS) and excess amount of graphene oxide (GO), we conducted in-situ polymerization of 3,4-ethylenedioxythiophene (EDOT) without an oxidant. XPS and IR spectroscopies of the product (GO-P) showed that PEDOT/PSS was successfully synthesized by oxidative polymerization of EDOT and hybridized with GO. GO-P displayed a stable aqueous suspension, however, the high content (42%) of GO in GO-P diminished electrical conductivity down to $15S{\cdot}m^{-1}$. Annealing of GO-P films at $200^{\circ}C$ for 8 hr induced partial reduction of GO and finally enhanced electrical conductivity up to $212S{\cdot}m^{-1}$.

Effects of Oxygen Plasma-treated Graphene Oxide on Mechanical Properties of PMMA/Aluminum Hydroxide Composites (산소 플라즈마 처리된 그래핀 산화물이 PMMA/수산화알루미늄 컴포지트의 기계적 물성에 미치는 영향)

  • Kim, Hyo-Chul;Jeon, Son-Yeo;Kim, Hyung-Il;Choi, Ho-Suk;Hong, Min-Hyuk;Choi, Ki-Seop
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.565-573
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    • 2011
  • The nanocomposites containing graphene oxide (GO) were prepared in order to improve the mechanical properties of poly(methyl methacrylate)/aluminum hydroxide (PMMA/AH) composites. GO was prepared from graphite by oxidation of Hummers method followed by exfoliation with thermal treatment. The surface of GO was modified by oxygen plasma in various exposure times from 0 to 70 min to improve interfacial compatibility. Compared with PMMA/AH composites, the nanocomposites containing GO modified with oxygen plasma for the exposure time up to 50 min showed significant increases in flexural strength, flexural modulus, Rockwell hardness, Barcol hardness, and Izod impact strength. The morphology of fracture surface showed an improved interfacial adhesion between PMMA/AH composites and GO, which was properly treated with oxygen plasma. The mechanical properties of nanocomposites were deteriorated by increasing the content of GO above 0.07 phr due to the nonuniform dispersion of GO.

Motion Sensing System for Automation of Neuropsycological Test (신경인지 검사를 위한 모션 센싱 시스템)

  • Jo, Wonse;Cheon, Kyeong-Min;Rew, Keun-Ho
    • Journal of Sensor Science and Technology
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    • v.26 no.2
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    • pp.128-134
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    • 2017
  • Until now, neuropsychological tests can diagnose the brain dysfunction, however, cannot distinguish the objective data of experiment enough to distinguish the relationships between brain dysfunction and cerebropathia. In this paper, an automatic cognitive test equipment system with 6-axis motion sensors was proposed for the automation of neuropsychological tests. Fist-Edge-Palm(FEP) test and Go-no go test were used to evaluate motor programming of frontal lobe. The motion data from the specially designed motion glove are transmitted wirelessly to a computer to detect the gestures automatically. The healthy 20 and 11 persons are investigated for the FEP and Go-No go test, respectively. The recognition rates of gestures of FEP and Go-No go test are min. 91.38% and 89.09%. In conclusion, the automations of cognitive tests are successful to diagnose the brain diagnostics quantitatively.

Modulation of Rit Activation by the Alpha Subunit of Go

  • Yang, Chul-Min;Ghil, Sung-Ho
    • Biomedical Science Letters
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    • v.15 no.4
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    • pp.327-333
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    • 2009
  • Heterotrimeric GTP binding proteins, G-proteins, mediate signal transduction generated by neurotransmitters and hormones. Among G-proteins, Go proteins are the most abundant in brain and classified as a member of Gi family. Ras-like protein in all tissues (Rit), one of the small GTPases, is a member of a Ras superfamily and identified as an important regulator of neuronal differentiation and cell transformation. Recently, we have reported that Rit functioned as a candidate downstream effector for alpha subunit of Go proteins ($Go{\alpha}$) and regulated neurite outgrowth triggered by $Go{\alpha}$ activation. In this study, we showed that the GTPase domain of $Go{\alpha}$ contributed to the direct interaction with Rit. We also demonstrated that $Go{\alpha}$ could lead to an increase of Rit activity suggesting that Rit play a role as a downstream effector of $Go{\alpha}$.

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Synthesis and Characterization of Polypropylene-grafted Graphene Oxide via "Grafting-to" Method (폴리프로필렌으로 그래프트된 그래핀 옥사이드 제조 및 특성 분석)

  • Lee, Jong-Hee;Oh, Chang-Ho;Lim, Jung-Hyurk;Kim, Kyung-Min
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.180-184
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    • 2015
  • PP-grafted GO was prepared by the reaction of graphene oxide (GO) containing 2-bromoisobuyryl groups and polypropylene (PP) having hydroxyl groups (PP-OH) via a "grafting-to" method. GO-Br was synthesized by the reaction of GO and 2-bromoisobutyryl bromide under a basic condition. PP-MAH was reacted with ethanolamine to produce PP-OH. The melting temperature of PP-grafted GO was shifted to the higher temperature than that of PP-OH. Also, the thermal stability of PP-grafted GO was increased as compared to PP-OH and GO. These results demonstrated that the grafted coating polymer PP was effective for enhancing the thermal stability of GO. The higher surface roughness of PP-grafted GO was resulted from the chemical attachment of PP on the surface of GO. The characterization of PP-grafted GO was conducted from Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscope (SEM).

Time-to-go Polynomial Guidance Law for Target Observability Enhancement (표적 가관측성 향상을 위한 Time-to-go 다항식 유도법칙)

  • Kim, Tae-Hun;Lee, Chang-Hun;Tahk, Min-Jea
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.1
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    • pp.16-24
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    • 2011
  • In this paper, we propose a new guidance law for target observability enhancement, which can control both terminal impact angle and acceleration. The proposed guidance law is simple form, combined conventional time-to-go polynomial guidance and a additional bias term which consists of relative position and proportional gain. The guidance law provides oscillatory flight trajectory and it maintains the conventional time-to-go polynomial guidance performance. To investigate the characteristics of the guidance law, we derive the closed-form solution, and various simulations are performed for proving the validity of the proposed guidance.

Investigation on the Characteristics of Interfacial Transition Zone (ITZ) of High-Strength Cement Mortar Incorporating Graphene Oxide (그래핀 옥사이드 혼입 고강도 시멘트 모르타르의 Interfacial Transition Zone (ITZ) 특성에 관한 연구)

  • Im, Su-Min;Cho, Seong-Min;Liu, Jun-Xing;Lim, Seungmin;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.343-350
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    • 2022
  • In recent years, nanomaterials, such as nano-silica, carbon nanotubes, and graphene oxide (GO), have been suggested to improve the properties of the interfacial transition zone (ITZ) between aggregates and cement pastes, which has most adversely affected the strength of quasi-brittle concrete. Among the nanomaterials, GO with superior dispersibility has been reported to be effective in improving the properties of ITZ of normal-strength concrete by forming interfacial chemical bonds with Ca2+ ions abundant in ITZ. In this study, the effect of GO on the properties of ITZ in the high-strength mortar was elucidated by calculating the change in hydration heat release, ITZ thickness, and the porosity around ISO sand, which was obtained with isothermal calorimetry tests and scanning electron microscope image analysis, respectively.