• Publications of The Korean Astronomical Society
• /
• v.32 no.1
• /
• pp.63-65
• /
• 2017

The zodiacal light emission is the thermal emission from the interplanetary dust and the dominant diffuse radiation in the mid- to far-infrared wavelength region. Even in the far-infrared, the contribution of the zodiacal emission is not negligible at the region near the ecliptic plane. The AKARI far-infrared all-sky survey covered 97% of the whole sky in four photometric bands with band central wavelengths of 65, 90, 140, and $160{\mu}m$. AKARI detected the small-scale structure of the zodiacal dust cloud, such as the asteroidal dust bands and the circumsolar ring, in far-infrared wavelength region. Although the most part of the zodiacal light structure in the AKARI far-infrared all-sky image can be well reproduced with the DIRBE zodiacal light model, there are discrepancies in the small-scale structures. In particular, the intensity and the ecliptic latitude of the peak position of the asteroidal dust bands cannot be reproduced precisely with the DIRBE models. The AKARI observational data during more than one year has advantages over the 10-month DIRBE data in modeling the full-sky zodiacal dust cloud. The resulting small-scale zodiacal light structure template has been used to subtract the zodiacal light from the AKARI all-sky maps.

• Publications of The Korean Astronomical Society
• /
• v.32 no.1
• /
• pp.157-161
• /
• 2017

The dusty torus of Active Galactic Nuclei (AGNs) is one of the important components for the unification theory of AGNs. The geometry and properties of the dusty torus are key factors in understanding the nature of AGNs as well as the formation and evolution of AGNs. However, they are still under discussion. Infrared observation is useful for understanding the dusty torus as thermal emission from hot dust with the dust sublimation temperature (~ 1500 K) has been observed in the infrared. We have analyzed infrared spectroscopic data of low-redshift and high-redshift quasars, which are luminous AGNs. For the low-redshift quasars, we constructed the spectral energy distributions (SEDs) with AKARI near-infrared and Spitzer mid-infrared spectra and decomposed the SEDs into a power-law component from the nuclei, silicate features, and blackbody components with different temperatures from the dusty torus. From the decomposition, the temperature of the innermost dusty torus shows the range between 900-2000 K. For the high-redshift quasars, AKARI traced rest-frame optical and near-infrared spectra of AGNs. Combining with WISE data, we have found that the temperature of the innermost dusty torus in high redshift quasars is lower than that in typical quasars. The hydrogen $H{\alpha}$ emission line from the braod emission line region in the quasars also shows narrow full width at half maximum of $3000-4000km\;s^{-1}$. These results indicate that the dusty torus and the broad emission line region are more extended than those of typical quasars.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.38 no.6
• /
• pp.577-585
• /
• 2010

This paper is a part of developing a software that predicts the infrared signal emitted from a ground object by considering solar irradiation. The radiance emitted from a surface can be calculated by using the temperature and optical characteristics of the surface object. The bidirectional reflectance distribution function (BRDF) is defined as the ratio of reflected radiance to incident irradiance. It is a very important surface reflection property that decides the reflected radiance from the object. In this paper, the spectral radiance received by a remote sensor over the mid-wave infrared(MWIR), and the long-wave infrared(LWIR) regions are computed and compared each other for several different materials. The results show that the optical surface properties such as the BRDF and the emissivity of the object surface can play a major role in generating the infrared signatures of various objects, and the largest infrared signal may reach up to 10 times the smallest one when the infrared signals obtained from a flat plate with different surface conditions under the sun light.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.14 no.6
• /
• pp.272-276
• /
• 2004

Inorganic materials, including gemstones, also have characteristic vibrational energies in the infrared that can be used for identification. For infrared spectroscopy, absorptions associated with the vibrations of the crystal structure (lattice vibrations) are characteristic of the given combination of atoms constituting the gemstone. Natural turquoise $CuAl_6(PO_4)_4\cdot(OH)_8\cdot 5H_2O$ can be distinguished easily from its common substitutes in the infrared range 2000~450$\textrm{cm}^{-1}$ by features in the mid-infrared. Gilson turquoise, which is a synthetic, exhibits a significantly smoother pattern when compared with natural turquoise, because of a different state of aggregation. Also, because the natural turquoise and gibbsite are so different chemically, their patterns are very different. The technique, which is infrared spectroscopy, is nondestructive and, with Fourier transform instrumentation, extremely rapid.

• Publications of The Korean Astronomical Society
• /
• v.32 no.1
• /
• pp.281-285
• /
• 2017

We present a summary of our spectroscopic redshift catalogue of 404 sources in the AKARI Deep Field South (ADF-S). We have used the AAOmega spectrograph to target mid-infrared and far-infrared sources selected primarily from AKARI observations in this field for which we were able to obtain optical counterparts. Our sources with identified redshifts include 316 with $H{\alpha}$ detections at $z{\leq}0.345$ and 15 sources at z > 1 with MgII or $Ly{\alpha}$ emission lines. About 13% of our $z{\leq}0.345$ sources are dominated by active galactic nuclei (AGN) emission, although many show emission from both star formation and AGNs. The median Balmer decrement is 5.9. Ultra-luminous infrared galaxies (ULIRGs) were found only in the higher-redshift sources. Optical and near infrared data will be available shortly, enabling calibration of the line luminosities and spectral energy distribution (SED) fitting for these sources.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
• /
• 2001.06a
• /
• pp.1171-1171
• /
• 2001

Quantitative analysis is an important requirement in exploration, mining and processing of minerals. There is an increasing need for the use of quantitative mineralogical data to assist with bore hole logging, deposit delineation, grade control, feed to processing plants and monitoring of solid process residues. Quantitative analysis using X-Ray Powder Diffraction (XRD) requires fine grinding and the addition of a reference material, or the application of Rietveld analysis to XRD patterns to provide accurate analysis of the suite of minerals present. Whilst accurate quantitative data can be obtained in this manner, the method is time consuming and limited to the laboratory. Mid infrared when combined with multivariant analysis has also been used for quantitative analysis. However, factors such as the absorption coefficients and refractive index of the minerals requires special sample preparation and dilution in a dispersive medium, such as KBr to minimize distortion of spectral features. In contrast, the lower intensity of the overtones and combinations of the fundamental vibrations in the near infrared allow direct measurement of virtually any solid without special sample preparation or dilution. Thus Near Infrared Spectroscopy (NIR) has found application for quantitative on-line/in line analysis and control in a range of processing applications which include, moisture control in clay and textile processing, fermentation processes, wheat analysis, gasoline analysis and chemicals and polymers. It is developing rapidly in the mineral exploration industry and has been underpinned by the development of portable NIR spectrometers and spectral libraries of a wide range of minerals. For example, iron ores have been identified and characterized in terms of the individual mineral components using field spectrometers. Data acquisition time of NIR field instruments is of the order of seconds and sample preparation is minimal. Consequently these types of spectrometers have great potential for in-line or on-line application in the minerals industry. To demonstrate the applicability of NIR field spectroscopy for quantitative analysis of minerals, a specific example on the quantification of lateritic bauxites will be presented. It has been shown that the application of Partial Least Squares regression analysis (PLS) to the NIR spectra can be used to quantify chemistry and mineralogy in a range of lateritic bauxites. Important, issues such as sampling, precision, repeatability, and replication which influence the results will be discussed.

• Korean Journal of Soil Science and Fertilizer
• /
• v.41 no.4
• /
• pp.267-272
• /
• 2008

Mid-infrared (MIR) spectroscopy, particularly Fourier transform infrared spectroscopy (FTIR), has emerged as an important analytical tool in quantification as well as identification of multi-atomic inorganic ions such as nitrate. In the present study, the possibility of quantifying soil nitrate via diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) without change of a sample phase or with least treated samples was examined. Four types of soils were spectrally characterized in terms of unique bands of soil contents and interferences with nitrate bands in the range of $2000-1000cm^{-1}$. In order to reduce the effects of soil composition on calibration model for nitrate, spectra transformed to the 1st order derivatives were used in the partial least squared regression (PLSR) model and the classification procedure associated with input soil types was involved in calibration system. PLSR calibration models for each soil type provided better performance results ($R^2$>0.95, RPD>6.0) than the model considering just one type of soil as a standard.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.23 no.3
• /
• pp.85-92
• /
• 2015

For concerning the climate change issues, the carbon sequestration and importance of soil organic matter are receiving high attention. To evaluate carbon sequestration in soil is important to determine the soil organic carbon (SOC) fractions such as WESOC (Water extractable soil organic carbon), and $CO_2$ emission by soil microbial respiration. However, the analyses for those contents are time-consuming procedure. There were studied the feasibility of MIRS (Mid-Infrared Spectroscopy), which has short analysis time for determining the WESOC and an incubated carbon in this study. Oven-dried soils at $100^{\circ}C$ and $350^{\circ}C$ were scanned with MIRS and compared with the chemically analyzed WESOC and cumulative carbon dioxide generated during 30, 60, 90, and 120 days of incubation periods, respectively. It was observed that an optimized determination coefficient was 0.6937 between WESOC and untreated soil processed by spectrum vector normalization (SNV) and 0.8933 between cumulative $CO_2$ from 30 days incubation and soil dried at $350^{\circ}C$ after subtracting air-dried soil processed by 1st derivatives. Therefore, it was shown that Quantification of soil organic carbon fractions was possibility to be analyzed by using MIRS.

• Journal of the Korean Institute of Gas
• /
• v.12 no.2
• /
• pp.48-52
• /
• 2008

According to extremely industrial growth, gas facilities, equipments and chemical plants are gradually increased due to incremental demands of annual amount of gases. The safety management of gases, however, is still far from their requirements. Methane, the principal ingredient of natural gas, is inflammable and explosive and is much used in factories and houses. Therefore, these gas safety management is essential. So, we, with a program of the gas safety management, hope to develop the detection system of methane gas leak using mid-infrared ray LED and PD with $3.2\;{\mu}m$. The cryogenic cooling device is indispensible at laser but needless at LED driven on the room temperature if manufacturing optical sensor with $3.2\;{\mu}m$. It, consequently, is not only possible to implement for subminiature and portable type but also able to speedily detect methane of extremely small quantities because the $CH_4$ absorption intensity at $3.2\;{\mu}m$ is stronger than that at $1.67\;{\mu}m$. Our objective of research is to prevent gas leak accidents from occurring previously and to minimize the extent of damage from them.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.33 no.6
• /
• pp.250-254
• /
• 2023

In this study, Li₂O-BaO-Ga₂O₃-TeO₂-TiO₂-GeO₂ glasses with high transmittance in mid-infrared region and high refractive indices were successfully synthesized. The relationship between glass properties and glass composition was analyzed. In Li₂O-BaO-Ga₂O₃-TeO₂-TiO₂-GeO₂ glass system, as increasing TeO₂ concentration, the refractive index increases and the glass transition temperature decreases. In addition, as increasing BaO concentration, the refractive index increases without decrease of Abbe number. The IR-cut off wavelength shifted to the longer wavelength with increasing TeO₂ and BaO contents due to their large molecular weight. The glass transition temperature significantly decreases when BaO was replaced with Li₂O.