• Title/Summary/Keyword: Micropollutants

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Quantitative Assessment of Micropollutants in the Southern Coastal Waters of Korea (남해 연안 해역에 있어서 미량유기오염물질의 정량적 평가)

  • Han, Sang-Kuk;Park, Ji-Young;Lee, Jong-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.4
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    • pp.213-219
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    • 2005
  • In this study, we try to Quantitatively assess the micropollutants in Gwangyang bay, Gamag bay and Yeoa bay, using simultaneous analytical method fir 310 chemicals. In the results, several dozen organic pollutants were detected in sampling sites, and the major chemicals detected were CH type chemicals, such as aliphatic and polycyclic compounds, and CHN(O) type chemicals, such as aromatic ammines and nitro compounds. The concentration of organic pollutants was higher in summer than in winter. However, there was no association of species of organic pollutants with season. The total concentration of pesticides at each sampling site was measured within the range of $ND{\sim}9.11{\mu}g/L$. Insecticides and fungicides of pesticide type were detected in Gwangyang bay and Gamag bay, while six kinds of endocrine disrupter were detected in southern coastal waters. From the results of this study, we should estimated that the insecticides, the fungicides, and a few of the endocrine disrupters are major pollutant factors in southern coastal waters.

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A Study on the Management of Micropollutants in Water System Considering Climate Change and other Potential Effects (기후변화 등 잠재적 영향을 고려한 수중 미량오염물질의 관리방향 연구)

  • Kim, Hojeong;Hong, Yongsuk;Ahn, Jong Ho
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.645-654
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    • 2013
  • In this study, the management polices of micropollutants (MPs) were reviewed and the future management strategy was discussed considering climate change and etc. In Korea, the investigation of drinking water has been actively carried out for the priority contaminants as well as MPs. Recently river and lake waters have been also examined for MPs. However, the coverage and depth of the investigation is limited. Moreover, climate change is likely to increase air & water temperature and it will affect the hydrological cycle. Such changes may increase the residual concentrations of MPs in water system. As water reuse increases, the residual MPs of the recycled water may create public concerns. Thus, in a viewpoint of the precautionary principle, more stringent management of MPs is recommended for the drinking water and the body-contact water use. For the surface water, more studies are necessary to understand the ecological risk by MPs.

Toxic Effect of Micropollutants on Coastal Organisms -I. Toxicity on Some Marine Fishes- (Micropollutants가 연안 생물에 미치는 독성효과에 관한 연구 -1. 어류에 미치는 독성-)

  • CHOI Moon-Sul;KINAE Naohide
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.5
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    • pp.529-534
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    • 1994
  • The lethal concentration(LC50) of several micropollutants for three species of the fish Paralichthys olivaceus, Mugil cephalus and Sebastes schlegeli were determined by acute toxicity tests. For the determination of definitive test concentrations, the fish were exposed to three test material concentrations spaced at order-of-magnitude intervals based on a logarithmic ratio in range finding tests. LC50 was determined by five concentrations of test material in a geometric progression by means of range finding tests. The 96hr-LC50 values(mg/l) were estimated by the graphical interpolation of probability-logarithm transformations. These indicated that the order of sensitivities to three kind of micropollutants was Mugil cephalus > Paralichthys olivaceus > Sebastes schlegeli.

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Investigation on the occurrence and fate of micropollutants in domestic wastewater treatment plants based on full-scale monitoring and simple statistical analysis (현장 모니터링과 기초통계분석에 기반한 국내 하수처리장 미량오염물질 발생 및 거동 조사)

  • Chae, Sung Ho;Lim, Seung Ji;Lee, Jiho;Gashaw, Seid Mingizem;Lee, Woongbae;Choi, Sangki;Lee, Yunho;Lee, Woorim;Son, Heejong;Hong, Seok-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.2
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    • pp.107-119
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    • 2022
  • The frequent detection and occurrence of micropollutants (MPs) in aquatic ecosystems has raised public health concerns worldwide. In this study, the behavior of 50 MPs was investigated in three different domestic wastewater treatment plants (WWTPs). Furthermore, the Kruskal-Wallis test was used to assess the geographical and seasonal variation of MPs in the WWTPs. The results showed that the concentrations of 43 MPs ranged from less than 0.1 to 237.6 ㎍ L-1, while other seven MPs including 17-ethynylestradiol, 17-estradiol, sulfathiazole, sulfamethazine, clofibric acid, simvastatin, and lovastatin were not detected in all WWTPs. Among the detected MPs, the pharmaceuticals such as metformin, acetaminophen, naproxen, and caffeine were prominent with maximum concentrations of 133.4, 237.6, 71.5, and 107.7 ㎍ L-1, respectively. Most perfluorinated compounds and nitrosamines were found at trace levels of 1.2 to 55.3 ng L-1, while the concentration of corrosion inhibitors, preservatives (parabens), and endocrine disruptors ranged from less than 0.1 to 4310.8 ng L-1. Regardless of the type of biological treatment process such as MLE, A2O, and MBR, the majority of pharmaceuticals (except lincomycin, diclofenac, iopromide, and carbamazepine), parabens (except Methyl paraben), and endocrine disruptors were removed by more than 80%. However, the removal efficiencies of certain MPs such as atrazine, DEET, perfluorinated compounds (except PFHxA), nitrosamines, and corrosion inhibitors were relatively low or their concentration even increased after treatment. The results of statistical analysis reveal that there is no significant geographical difference in the removal efficacy of MPs, but there are temporal seasonal variations in all WWTPs.

Removal of Total Organic Carbon and Micropollutants in Tertiary Treated Sewage by Medium Pressure UV/H2O2 (중압 자외선과 과산화수소 공정을 이용한 하수 3차 처리수중 총유기탄소와 미량오염물질 제거)

  • Lee, Jai-Yeop;Kim, Ilho
    • Journal of Korean Society on Water Environment
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    • v.36 no.4
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    • pp.314-321
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    • 2020
  • This study evaluated the applicability of UV-AOP process using medium-pressure UV lamp and H2O2 to remove TOC and emerging micropollutants in the effluent from a sewage treatment plant. The UV lamp with higher output(1.6~8.0 kW) showed slightly higher amount of power in removing TOC of 1 mg/L(0.09 kWh/mg/L~0.11 kWh/mg/L), however it was found that there was no significant difference for each cases. In addition, under the condition that the H2O2 concentration is sufficient, as the power consumption of the UV lamp increases, the unit TOC removal concentration per unit H2O2 decomposition concentration also increases, resulting in effective removal of TOC. The removal rate of 7 new trace contaminants, such as antibiotics by the UV-AOP tested, was at least 89.4%, and the ability to remove the emerging micro pollutants in the process was very effective. But, it was judged that it could not be excluded that the probablity of transforming to oxidated by-product in the case of a low TOC removal efficiency. Depending on the operating conditions of the UV and H2O2 processes, a higher BOD concentration is found in the treated water than in the influent, and it is necessary to review the UV power and proper injection conditions of H2O2 to maintain the BOD concentration increase below a certain level.

Rejection Behavior of 2-MIB and Geosmin Using Polyethersulfone Nanofiltration Membrane and Surface Hydrophilicity Effect Using $TiO_2$ Particles (2-MIB와 Geosmin의 Polyethersulfone 나노 분리막 배제율 거동 및 $TiO_2$ 적용 표면 친수화 효과 관찰)

  • Nam, Dowoo;Kim, Mooin;Kim, Jeonghwan
    • Membrane Journal
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    • v.22 no.5
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    • pp.326-331
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    • 2012
  • In this study, rejection behavior of 2-MIB (methylisoborneal) and geosmin which are known as taste-and-odor (T & O) causing micropollutants in drinking water source was investigated using hydrophobic polyethersulfone (PES) nanofiltration "loose" membrane (MWCO : 400 Da). It was found that the rejection of the geosmin was higher than that of the 2-MIB in all experimental conditions tested. This study also showed that the rejections of 2-MIB and geosmin were increased by increasing solution pH due to enhancing electrostatic repulsions between micropollutants and membrane surface. The presence of natural organic matter led to increase the rejection of the hydrophobic 2-MIB and geosmin and the effectiveness was more pronounced at higher solution pH. Increasing hydrophilicity of the hydrophobic membrane surface by coating with $TiO_2$ particles resulted in the significant increase in the rejection of 2-MIB and geosmin. In addition to the charge repulsion, this result suggests that hydrophobic-hydrophobic interaction should be one of main rejection mechanisms of T & O compounds by NF membrane.

Removal characteristic on micropollutants as ibuprofen, acetaminophen, caffeine in small water fall system using HBC ring media (생물막 끈상여재를 이용한 낙차형태별 수중 미량유해물질 ibuprofen, acetaminophen, caffeine분해특성)

  • Dockko, Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.1
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    • pp.129-135
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    • 2009
  • PPCP (pharmaceuticals and personal care products) is known as micropollutant that is released from wastewater treatment plant. Research represents that these contaminants have increased in the last 10 years. This study tries to make four different trickling filter systems using plastic fiber media to remove PPCP such as acetaminophen, ibuprofen, caffeine. The results of the experiment that compares the process efficiencies of four different systems (A, B, C and D) using HBC media show that almost all the reactor has around 95% removal efficiency. Slope type HBC reactor has twice higher efficiency rather than submerged type reactor to remove PPCP in water system. In 8 hours, 89% of acetaminophen, ibuprofen, caffeine are removed in slope type reactor while 39% of them in submerged type.

Study on Water Treatment Improvement Measures based on Case Studies of Ozone Disinfection at Domestic Water Treatment Plants (국내 정수장의 오존 소독능 평가사례를 통한 정수처리기준 개선방안 연구)

  • Noh, Hee-Su;Lee, Kyung-Hyuk;Wang, Chang-Keun;Son, Dae-Ik;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.153-160
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    • 2011
  • Ozone process is currently applied in 24 water treatment plants in Korea to control micropollutants and taste & odor compounds. However, one of the chlorine resistant protozoa, cryptosporidium, is not being considered as ozone disinfection performance whereas U.S. is already regulate Cryptosporidium by ozone disinfection. two ozone plants(PH, UH WTP) operation conditions are investigated for disinfection performance comparing Korea disinfection regulation and U.S. regulation. The ozone plants are unable to get Cryptosporidium inactivation credits by Korea disinfection regulation. However, the inactivation credit for Cryptosporidum was increased when the U.S. disinfection regulation was applied. The Korea disinfection credit regulation need revision to practical aspects.

Evaluation of Removal Efficiencies of Micropollutants in Wastewater Treatment Plants (산업폐수처리장에서의 미량유해물질 제거율 평가)

  • Lee, In-Seok;Sim, Won-Jin;Oh, Jeong-Eun;Kim, Chang-Won;Chang, Yoon-Seok;Yoon, Young-Sam
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.214-219
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    • 2007
  • 66 micropollutants analyses in 9 wastewater treatment plants(WWTPs) along Nak-dong river were implemented to identify the concentrations and removal efficiencies before and after treatment processes. As a result of study, the concentration levels discharged from WWTP effluents to water system were below the water quality criteria and the levels of other studies. The removal efficiencies were 84.6%(DAF/CCR) and 81.6%(AC) for 1,4-dioxane. Phenol, Clphs and PAHs were removed 94.6%, 66.4% and 80.6% respectively by the activated sludge(AS) process. The removal efficiencies of Clbzs were 45.3% for the activated sludge(AS) process and 60.6% for the activated carbon(AC) process. However, other processes besides AS and AC, the removal efficiencies of Clbzs were very low(<20%). The sand filtration(SF) process that could remove particle matters showed the best efficiency for PCDDs / Fs removal$(\geq99%)$. However, in case of relatively low PCDDs/Fs concentration level in influent, the removal efficiency was not so high$(\leq50%)$.