• Title/Summary/Keyword: Microcellular polymer

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Synthesis of Microcellular Cordierite Ceramics Derived from a Preceramic Polymer (Preceramic Polymer를 이용한 마이크로셀룰라 코디어라이트 세라믹스의 합성)

  • Song, In-Hyuck;Kim, Young-Mi;Kim, Hai-Doo;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.184-189
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    • 2007
  • In this study, a novel-processing route for producing microcellular cordierite ceramics has been developed. The proposed strategy for making the microcellular cordierite ceramics involves three steps: (i) fabricating ceramic-filled preceramic foams by heating a mixture of polysiloxane, expandable microspheres, talc, and alumina in a mold, (ii) cross-linking the foamed body, and (iii) transforming the body into microcellular cordierite ceramics by sintering. Cu jig was used for near net shaping in the foaming step. The experimental variables such as the shape of foaming jig and the content of expendable microsphere were investigated. By controlling the content of expendable microsphere, it was possible to make the porous cordierite ceramics with cell density of ${\sim}1.0{\times}10^9\;cells/cm^3$.

Weight Change of Microcellular Plastics by Using nitrogen Gas (질소 가스를 이용한 초미세 발포 고분자 재료의 무게변화)

  • Jeing, Dae-Jin;Cha, Sung-Woon;Yoon, Jae-Dong
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.9
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    • pp.196-201
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    • 2000
  • There is a great demand for reducing the amount of material used in mass-produced plastics parts for material cost constitutes a large percentage of the total cost of a product up to 75% It may be noted that the price of plastics is directly related to the price of petroleum. Material reduction therefore decreases the amount of oil needed for the manufacture of plastics and thus help conserve this natural resource. Therefore microcellular foaming process(MCPs) was studied for solving this problems alternatively in 1980's at M. I. T. Until now in microcellular plastics processes carbon dioxide gas was mainly used for microcellular foaming Because carbon dioxide has more solubility than any other gases such as nitrogen gas or helium gas. The purpose of the this research is measurement of changing of the microcellular plastics' weight by using nitrogen gas in injection molding an comparing weight reduction of microcellular foamed plastics for using carbon dioxide gas with nitrogen gas.

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Flow behavior of high internal phase emulsions and preparation to microcellular foam

  • Lee, Seong Jae
    • Korea-Australia Rheology Journal
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    • v.16 no.3
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    • pp.153-160
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    • 2004
  • Open microcellular foams having small-sized cell and good mechanical properties are desirable for many practical applications. As an effort to reduce the cell size, the microcellular foams combining viscosity improvers into the conventional formulation of styrene and water system were prepared via high internal phase emulsion polymerization. Since the material properties of foam are closely related to the solution properties of emulsion state before polymerization, the flow behavior of emulsions was investigated using a controlled stress rheometer. The yield stress and the storage modulus increased as viscosity improver concentration and agitation speed increased, due to the reduced cell size reflecting both a competition between the continuous phase viscosity and the viscosity ratio and an increase of shear force. Appreciable tendency was found between the rheological data of emulsions and the cell sizes of polymerized foams. Cell size reduction with the concentration of viscosity improver could be explained by the relation between capillary number and viscosity ratio. A correlative study for the cell size reduction with agitation speed was also attempted and the result was in a good accordance with the hydrodynamic theory.

Processing of Microcellular Nanocomposite Foams by Using a Supercritical Fluid

  • Wee, Dongho;Seong, Dong Gi;Youn, Jae Ryoun
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.160-169
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    • 2004
  • Polystyrene/layered silicate nanocomposites were prepared by melt intercalation. To examine the distribution of the clay in polymer matrix, small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) were used. Intercalated nanocomposites were obtained and their rheological properties were investigated. Microcellular nanocomposite foams were produced by using a supercritical fluid. As clay contents increased, the cell size decreased and the cell density increased. It was found that layered silicates could operate as heterogeneous nucleation sites. As the saturation pressure increased and the saturation temperature decreased, the cell size decreased and the cell density increased. Microcellular foams have different morphology depending upon the dispersion state of nanoclays.

Emulsion rheology and properties of polymerized high internal phase emulsions

  • Lee, Seong-Jae
    • Korea-Australia Rheology Journal
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    • v.18 no.4
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    • pp.183-189
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    • 2006
  • High internal phase emulsions are highly concentrated emulsion systems consisting of a large volume of dispersed phase above 0.74. The rheological properties of high internal phase water-in-oil emulsions were measured conducting steady shear, oscillatory shear and creep/recovery experiments. It was found that the yield stress is inversely proportional to the drop size with the exponent of values between 1 and 2. Since the oil phase contains monomeric species, microcellular foams can easily be prepared from high internal phase emulsions. In this study, the microcellular foams combining a couple of thickeners into the conventional formulation of styrene and water system were investigated to understand the effect of viscosity ratio on cell size. Cell size variation on thickener concentration could be explained by a dimensional analysis between the capillary number and the viscosity ratio. Compression properties of foam are important end use properties in many practical applications. Crush strength and Young's modulus of microcellular foams polymerized from high internal phase emulsions were measured and compared from compression tests. Of the foams tested in this study, the foam prepared from the organoclay having reactive group as an oil phase thickener showed outstanding compression properties.

A study on the effect of twice foaming process on microcellular foamed plastics (재발포가 MCPs에 미치는 영향)

  • Park J.Y.;Cha S.W.;Seo J.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.421-422
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    • 2006
  • According to the industrialization the using of polymers is increased by their mechanical or commercial demands. At now, the using of polymers is become bigger and bigger than yet. On the other words, our whole life is covered by the polymers. Due to the extended polymer using, the material cost is higher and higher. Therefore, the people used the polymer foaming process using the gas. The polymer foaming using the pentane or butane gas is prohibited by the government cause of the explosiveness and non-environmental friendly. Therefore, the members of MIT invented the Micro-cellular Polymer Foaming in 1980. The Micro-cellular Polymers has many cells in the polymer matrix. By compare between non-foamed polymers, the Micro-cellular Polymers have low material cost, soundproof and shock less. The purpose of this study is to study the twice foamed polymer by batch process. To know the reaction by step of microcellular foaming process, we measure the density of polymer. And to viewing the cell morphology, we used the scanning electron microscopy(SEM).

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Preparation, Morphology and Electrical Conductivity of Polystyrene/Polydopamine- Carbon Nanotube Microcellular Foams via High Internal Phase Emulsion Polymerization (고내상 에멀젼 중합에 의한 폴리스티렌/폴리도파민-탄소나노튜브 미세기공 발포체의 제조, 모폴로지 및 전기 전도도)

  • Kim, Haseung;Na, Hyo Yeol;Lee, Jong Heon;Lee, Seong Jae
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.293-299
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    • 2015
  • Conductive microcellular foams consisted of polystrene (PS) and polydopamine-coated carbon nanotube (PDA-CNT) were prepared via high internal phase emulsion (HIPE) polymerization and their morphology and electrical conductivity were investigated. CNT as a conductive nanofiller was modified to PDA-CNT by coating with hydrophilic PDA on the surface of CNT to increase aqueous phase dispersion and emulsion stability. It was possible to prepare the HIPEs having higher PDA-CNT content and the resultant foams having improved conductivity due to its good dispersion. The foams showed the morphology of interconnected cell structure. As PDA-CNT content increased, yield stress and storage modulus increased and cell size reduced. The PDA-CNT content showing electrical percolation threshold was ca. 0.58 wt% and the conductivity at PDA-CNT content of 5 wt% was increased to $10^{-3}S/m$.

Change of Glass Transition Temperature of PETG Containing Gas (가스를 포함하는 고분자 재료(PETG)의 유리전이온도 변화)

  • Cha, Seong-Un;Yun, Jae-Dong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.824-829
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    • 2000
  • The industries use polymer materials for many purposes because they have many merits. But these materials' costs take up too much proportion in overall cost of products that use these materials as their major material. So it is very economical for polymer industries to reduce these costs. Microcellular foaming process appeared in 1980's to solve this problem and it proved to be quite successful. This process uses inert gases such as CO2, N2. As these gases are dissolved into polymer matrices. many properties are changed. Glass transition temperature is one of these properties. DSC, DMA are devices that measures this temperature, but these are not sufficient to measure the temperature of polymer containing gas. In this paper, we devised a new tester that uses magnetism. We used this device to acquire data of the change of glass transition temperature and made Cha-Yoon model that can predict the change of glass transition temperature. Using this model, the change of this temperature can be estimated as a function of weight gain of gas. Cha-Yoon model proved that Chow's model is inappropriate to predict the change of glass transition temperature of polymer matrices containing gas.

Coarsening Phenomena in Polymer-Solvent Systems-A Review (고분자 용액에서의 Coarsening 현상)

  • 송승원
    • Membrane Journal
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    • v.7 no.2
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    • pp.49-56
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    • 1997
  • In order to understand the formation of polymeric membranes or microcellular foams, phase separation phenomena in polymer solutions should be understood. The present review examines the progress made in the understanding of these phenomena, with emphasis on selected polymer-solvent systems. In the case of polymer-solvent systems, coarsening is of particular importance as it may come to dominate or overshadow spinodal decomposition effects within the first minute or few minutes of phase separation. In this article, some of the most important theoretical models of late stage of phase separation are reviewed, and recent experimental studies on coarsening in polymer-solvent systems are studied.

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