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http://dx.doi.org/10.4191/KCERS.2007.44.5.184

Synthesis of Microcellular Cordierite Ceramics Derived from a Preceramic Polymer  

Song, In-Hyuck (Department of Materials Engineering, Korea Institute of Machinery and Materials)
Kim, Young-Mi (Department of Materials Engineering, Korea Institute of Machinery and Materials)
Kim, Hai-Doo (Department of Materials Engineering, Korea Institute of Machinery and Materials)
Kim, Young-Wook (Department of Materials Science and Engineering, The University of Seoul)
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Abstract
In this study, a novel-processing route for producing microcellular cordierite ceramics has been developed. The proposed strategy for making the microcellular cordierite ceramics involves three steps: (i) fabricating ceramic-filled preceramic foams by heating a mixture of polysiloxane, expandable microspheres, talc, and alumina in a mold, (ii) cross-linking the foamed body, and (iii) transforming the body into microcellular cordierite ceramics by sintering. Cu jig was used for near net shaping in the foaming step. The experimental variables such as the shape of foaming jig and the content of expendable microsphere were investigated. By controlling the content of expendable microsphere, it was possible to make the porous cordierite ceramics with cell density of ${\sim}1.0{\times}10^9\;cells/cm^3$.
Keywords
Cordierite; Porous material; Foaming; Porosity;
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1 Y.-W. Kim. Y. J. Jin, Y. S. Chun, I. H. Song, and H. D. Kim, 'A Simple Pressing Route to Closed-Cell Microcellular Ceramics,' Scripta Mater., 53 921-25 (2005)   DOI   ScienceOn
2 Y.-W. Kim, S. H. Kim, H. D. Kim, and C. B. Park, 'Processing of Closed-Cell Silicon Oxycarbide Foams from a Preceramic Polymer,' J. Mater. Sci., 39 5647-52 (2004)   DOI   ScienceOn
3 Y.-W. Kim, H. D. Kim, and C. B. Park, 'Processing of Microcellular Mullite,' J. Am. Ceram. Soc., 88 [12] 3311-15 (2005)   DOI   ScienceOn
4 Y. Dong, X. Liu, Q. Ma, and G. Meng, 'Preparation of Cordierite-based Porous Ceramic Micro-filtration Membranes Using Waste Fly Ash as the Main Raw Materials,' J. Memb. Sci., 285 [1-2] 173-81 (2006)   DOI   ScienceOn
5 A. Yamuna, S. Honda, K. Sumita, M. Yanagihara, S. Hashimoto, and H. Awaji 'Synthesis, Sintering and Thermal Shock Resistance Estimation of Porous Cordierite by IR Heating Technique,' Micro. Meso. Mater., 85 [1-2] 169-75 (2005)   DOI   ScienceOn
6 F. A. Costa Oliveira, 'Elastic Moduli of Open-cell Cordierite Foams,' J. of Non-Crystalline Solids, 351 [19-20] 1623-29 (2005)   DOI   ScienceOn
7 R. Goren, C. Ozgur, and H. Gocmez, 'The Preparation of Cordierite from Talc, Fly Ash, Fused Silica and Alumina Mixtures,' Ceram. Int., 32 [1] 53-6 (2006)   DOI   ScienceOn
8 P. Sepulveda, 'Gelcasting Foams for Porous Ceramics,' Am. Ceram. Soc. Bull., 76 [10] 61-5 (1997)
9 J. Saggio-Woyansky, C. E. Scott, and W. P. Minnear, 'Processing of Porous Ceramics,' Am. Ceram. Soc. Bull., 71 [11] 1674-82 (1992)
10 W. Wu, T. Fujiu, and G. L. Messing, 'Synthesis of Cellular Inorganic Materials by Foaming Sol-Gels,' J. Non-Cryst. Solids, 121 407-12 (1990)   DOI   ScienceOn
11 F. F. Lange and K. T. Miller, 'Open Cell, Low-Density Ceramics Fabricated from Reticulated Polymer Substrates,' Adv. Ceram. Mater., 2 [4] 827-31 (1987)
12 C. Wang, J. Wang, C. B. Park, and Y.-W. Kim, 'Cross-linking Behavior of a Polysiloxane in Preceramic Foam Processing,' J. Mater. Sci., 39 4913-15 (2004)   DOI   ScienceOn
13 O. Delverdier, M. Monthioux, A. Oberlin, A. Lavedrine, D. Bahloul, and P. Goursat, 'Thermal Behaviour of Polymerderived Ceramics. II. Si-C-N System from a New PVSZ Precursor,' J. High Temp, 139-49 (1992)
14 O. Delverdier, M. Monthioux, D. Mocaer, and R. Pailler, 'Thermal Behavior of Polymer-derived Ceramics. I. Si-C and Si-C-O Systems from Both Commercial and New Polycarbosilane (PCS) Precursors,' J. Europ. Ceram. Soc., 27-41 (1993)
15 I. H. Song, M. J. Kim, H. D. Kim, and Y.-W. Kim, 'Processing of Microcellular Cordierite Ceramics from a Preceramic Polymer,' Scripta Mater., 54 1521-25 (2006)   DOI   ScienceOn
16 D. H. Jang, Y.-W. Kim, and H. D. Kim, 'Processing of Porous Cordierite Ceramics with Controlled Porosity,' J. Ceram. Soc. Jpn., 115 [1] 52-8 (2007)   DOI   ScienceOn