• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2009년도 학술대회 초록집
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• pp.147-154
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• 2009

암석의 속도를 정확히 예측하기 위해서는 속도에 1차적인 영향을 미치는 공극구조의 연구가 필수적이다. 이에 본 연구에서는 고해상도 구조 해석에 가장 많이 사용하고 있는 X선 토모그래피 방법을 이용하여 공극구조를 획득하였다. 그러나 X선 토모그래피 방법의 경우 그 역산과정에서 발생하는 smoothing 효과에 의해 공극구조가 왜곡될 수 있다.이를 간단한 공극구조 생성 방법인 single threshold 방법으로 이분화 할 경우 grain contact 부분이 명확히 표현되지 않아 입자의 접촉면적에 좌우되는 속도의 경우 많은 오차를 야기한다. 또한 grain contact의 정확한 기술을 위해서는 고해상도 토모그램 획득이 매우 중요하며, 해상도에 따른 속도의 변화양상 또한 정량적 분석이 필요한 부분이다. 이를 위해 본 연구에서는 영상처리 기법을 적용하여 다양한 이분화를 시도하고, 서로 다른 해상도의 토모그램을 이용하여 이들이 속도 계산에 미치는 영향을 분석하였다. 다양한 영상처리 기법을 적용한 결과 single threshold 방법으로 이분화 한 결과보다 정확한 접촉면적을 보여주는 이분화 결과를 얻을 수 있었지만 실제 계산된 속도에서는 그 향상 정도가 미미하였다. 고해상도 토모그램을 이용한 경우에는 입자의 grain contact이 명확하게 표현되었고, 속도 또한 상당히 향상된 결과를 보여주었다. 결론적으로 디지털 공극구조에서 시뮬레이션을 통한 속도 예측의 경우, 입자의 접촉 부분을 정확히 기술 할 수 있는 높은 해상도의 토모그램이 필수적이며, smoothing 효과의 제거 등의 영상처리와 병행된다면 보다 정확한 암석의 속도 예측이 가능할 것으로 판단된다.

• 한국재료학회지
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• 제31권2호
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• pp.101-107
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• 2021

Pores produced by carbonization in bulk graphite process degrade the mechanical and electrical properties of bulk graphite. Therefore, the pores of bulk graphite must be reduced and an impregnation process needs to be performed for this reason. In this study, bulk graphite is impregnated by varying the viscosity of the impregnant. The pore volume and pore size distribution, according to the viscosity of the impregnant, are analyzed using a porosimeter. The total pore volume of bulk graphite is analyzed from the cumulative amount of mercury penetrated. The volume for a specific pore size is interpreted as the amount of mercury penetrating into that pore size. This decreases the cumulative amount of mercury penetrating into the recarbonized bulk graphite after impregnation because the viscosity of the impregnant is lower. The cumulative amount of mercury penetrating into bulk graphite before impregnation and after three times of impregnation with 5.1cP are 0.144 mL/g and 0.125 mL/gm, respectively. Therefore, it is confirmed that the impregnant filled the pores of the bulk graphite well. In this study, the impregnant with 5.1 cP, which is the lowest viscosity, shows the best effect for reducing the total pore volume. In addition, it is confirmed by Raman analysis that the impregnant is filled inside the pores. It is confirmed that phenolic resin, the impregnant, exists inside the pores through micro-Raman analysis from the inside of the pore to the outside.

• Carbon letters
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• 제11권3호
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• pp.201-205
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• 2010

Activated carbons are well known as adsorbents for gases and vapors. Micro porous carbons are used for the sorption/separation of light gases, whereas, carbon with bigger pore size are applied for removal of large molecules. Therefore, the control of pore size of activated carbon plays a vital role for their use in specific applications. In the present work, steam activation parameters have been varied to control pore size of the resulting activated carbon. It was found that flow rate of steam has profound effect on both surface characteristic and surface morphology. The flow rate of steam was optimized to retain monolith structure as well as higher surface area.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2014년도 추계학술대회 논문집
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• pp.270-271
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• 2014

리튬공기전지 및 연료전지의 고용량, 고효율 특성을 달성하기 위해서는 이들 전지를 구성하는 탄소전극물질의 pore구조가 매우 중요 하다. 이에 본 연구에서는 솔루션 플라즈마라는 새로운 공정을 이용하여 micro-pore비율이 극히 적고, meso-pore 중심으로 구성되어 있는 새로운 구조체의 합성에 성공하였고, 실제 리튬공기전지를 제작하여 방전시험을 한 결과, 기존 상업용 탄소재료보다 30~40% 이상의 우수한 고용량을 나타내는 것을 확인 할 수 있었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.202-203
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• 2018

Chemistry and microstructure of steel reinforcement bars play an important role to control the corrosion in concrete environments. In present study, we have chosen two different microstructure of steel rebars produced from companies and assessed their corrosion characteristics in simulated concrete pore (SCP) solution with prolonged exposure periods. Hot rolled steel rebar showed more corrosion resistance compare to thermo-mechanically treated (TMT) one. The growth of passive is greater in hot rolled (A) than TMT (B) due to orientation of microstructure. TMT steel rebar exhibit distorted microstructure with many micro cells which enhances the galvanic coupling and induce the deterioration while on the other hand hot rolled rebars exhibit fine grain boundary which responsible in growth of uniform, adherent and protective passive film resultant improved impedance was observed.

• Carbon letters
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• 제8권1호
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• pp.17-24
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• 2007

Microporous carbons with narrow pore size distribution have been successfully synthesized by using hydrolyzed and calcined silica as templates and phenol formaldehyde (pf) resin as carbon precursor. Phenol formaldehyde-silica micro composites were prepared by solution route. Subsesequently, silica templates were removed by HF leaching. Resulting carbons were steam activated. The porous carbons were characterized by nitrogen adsorption-desorption isotherm, SEM, FTIR analysis, iodine adsorption, thermogravimetry analysis, etc. Adsorption isotherms show that the porous carbon prepared from calcined silica as templates are microporous with 88% pores of size <2 nm porosity and are of type I isotherm, while porous carbon prepared by using hydrolyzed silica are microporous with 89% microporosity, shows hysteresis loop at high relative pressure indicating the presence of some mesoporosity in samples. The microporosity in porous carbon materials has a bearing on the nature of silica templates used for pore formation.

• 대한토목학회논문집
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• 제4권2호
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• pp.25-33
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• 1984

활성탄(活性炭)의 입경변화(粒徑變化)가 trihalomethane의 흡착(吸着)에 미치는 영향(影響)에 관하여 실험적(實驗的)으로 연구(硏究)하였다. 실험(實驗)에 사용(使用)된 활성탄(活性炭)은 평균입경(平均粒徑)이 0.73mm에서 2.03mm까지의 4종류(種類)이었으며 이들에 대하여 물리적(物理的) 특성(特性)을 조사(調査)하고 trihalomethanedml 흡착능력(吸着能力)을 등온흡착실험(等溫吸着實驗)과 micro-column 실험(實驗)을 통해 밝혀냈다. 입경(粒徑)의 증가(增加)에 따라 비표면적(比表面積)이 감소(減少)하였고 활성탄(活性炭) 내부공극(內部空隙)의 반경(半徑)이 크게 증가(增加)하였다. 또한 큰 입자(粒子)의 경우에는 공극(空隙)의 크기가 넓게 분포(分布)하였다. Trihalomethane의 흡착(吸着)은 Freundlich 공식(公式)에 의해 잘 표현(表現)되었고 입경증가(粒徑增加)에 따라 흡착능력(吸着能力)의 감소(減少)가 뚜렷하게 나타났다. Micro-column 실험결과(實驗結果)와 모형(模型)의 Simulation으로부터 물질도달계수(物質導達係數)와 내부표면광산계수(內部表面壙散係數)를 산정(算定)하였다. 입경변화(粒徑變化)에 따른 계수(係數)의 변화(變化)는 무시(無視)할 수 있었으며 입경변화(粒徑變化)에 따른 효율(効率)의 차이(差異)는 주로 흡착능력(吸着能力)의 차이(差異)에서 오는 결과(結果)로 판단(判斷)된다.

• Geomechanics and Engineering
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• 제3권3호
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• pp.219-231
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• 2011

Waste fills resulting from coal mining should consist of large, free-draining sedimentary rocks fragments. The successful performance of these fills is related to the strength and durability of the individual rock fragments. When fills are made of shale fragments, some fragments will be durable and some will degrade into soil particles resulting from slaking and inter-particle point loads. The degraded material fills the voids between the intact fragments, and results in settlement. A laboratory program with point load and slake durability tests as well as thin section examination of sixty-eight shale samples from the Appalachian region of the United States revealed that pore micro-geometry has a major influence on degradation. Under saturated and unsaturated conditions, the shales absorb water, and the air in their pores is compressed, breaking the shales. This breakage was more pronounced in shales with smooth pore boundaries and having a diameter equal to or smaller than 0.060 mm. If the pore walls were rough, the air-pressure breaking mechanism was not effective. However, pore roughness (measured by the fractal dimension) had a detrimental effect on point load resistance. This study indicated that the optimum shales to resist both slaking as well as point loads are those that have pores with a fractal dimension equal to 1.425 and a diameter equal to or smaller than 0.06 mm.

• 펄프종이기술
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• 제30권3호
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• pp.46-56
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• 1998

The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2007년도 학술발표회 논문집
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• pp.499-500
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• 2007