• Carbon letters
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• v.6 no.4
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• pp.243-247
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• 2005

Plasma polymerization of allylamine subsequently after plasma pre-treatment was conducted on the activated carbon fibers (ACFs) for the immobilization of amine groups in the surface of ACFs. The change of structural properties of ACFs with respect to different polymerization conditions was investigated through BET method. The change of surface morphologies of ACFs with respect to different plasma polymerization power was also studied through AFM. It was found that the structural properties such as specific surface area and micropore volume could be optimized under certain plasma deposition conditions. It was reckoned that treatment and deposition showed adverse effect on plasma polymerization, in which the former developed the micro-structures of the ACFs and the latter tended to block the micro pores. The Fourier transform infrared spectroscopy (FTIR) revealed that the poly(allylamine) was successfully immobilized on the surface of ACFs and the amount of the deposited polymer layer was related to the plasma polymerization power. SEM results showed that the plasma deposited polymer layer were small and homogenously distributed. The size and the distribution of particles deposited were closely related to the plasma polymerization power, too.

• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.125-132
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• 2006

Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

• Carbon letters
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• v.16 no.2
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• pp.78-85
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• 2015

Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of $700^{\circ}C-1000^{\circ}C$ for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic electrolyte, as measured by a charge-discharge method in the voltage range of 0-2.7 V. In order to improve the performance of the electric double-layer capacitor electrode, various mixtures of CTP and petroleum pitch (PP) were activated at the optimal activation conditions previously determined for CTP. Although the specific capacitance of AC electrodes prepared from CTP only and the mixtures of CTP and PP was not significantly different at a current density of 1 A/g, the AC electrodes from CTP and PP mixtures showed outstanding specific capacitance at higher current rates. In particular, CTP-PP61 (6:1 mixture) had the highest specific capacitance of 132 F/g, and the specific capacitance remained above 90% at a high current density of 3 A/g. It was found that the high specific capacitance could be attributed to the increased micro-pore volume of ACs with pore sizes from 1 to 2 nm, and the high power density could be attributed to the increased meso-pore volume.

• Journal of the Korea Concrete Institute
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• v.23 no.6
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• pp.817-826
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• 2011

Concrete using eco-cement has a problem with long-term strength development. However, currently, a long-term strength development mechanism is not confirmed, resulting in a lack of application of eco-cement in construction fields. In this study, the curing humidity influence on development in long-term strength of concrete using eco-cement and the relationship between strength and pore structure were examined. The results showed that wet cured eco-cement with a high water/cement ratio showed serious long-term strength reduction due to non-reduction of pore volume (pore size over 10 nm) in mortar caste with eco-cement. Also, the study results on improvement of long-term strength of eco-cement by partial replacement with ordinary portland cement and finely-ground fly ash showed that both of these alternatives improved long-term strength of concrete caste with eco-cement due to gradual refinement of their micro-structure.

• Microbiology and Biotechnology Letters
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• v.29 no.4
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• pp.240-247
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• 2001

The effect of microsparged aeration in mammalian cell bioreactor on the oxygen transfer rate and cell viability was studied. The microspargers with differ- ent micron-sized pores were used to supply oxygen to the medium. The oxygen transfer coefficients (k$_{L}$a) measured in the bioreactor were markedly increased, which is due to the increase of the contacting area between air bubbles and liquid medium when the pore size of microsparger decreases. When the impellers of two different types (square-pitch marine impeller and $45^{\circ}$ pitched flat blade impeller) were used for agitation, the k$_{L}$a values were slightly higher with the marine impeller than with the blade impeller. The detrimental effect of direct gas sparging with microsparger on mammalian cells was investigated in bubble columns with various air flow rates and different pore sized microspargers. The first-order cell death rate constant ($k_{d}$ /7) was shown to be directly proportional to the air flow rate and inversely proportional to the pore size. During the cultivation of hybridoma cells using microsparger with the pore size of $0.57\mu$m in the mammalian cell culture bioreactor, the continuous sparging caused the cell death and suppressed the cell growth. However, cells grew normally and cell viability was maintained above 90% in the logarithmic phase when the air was intermittently sparked in order to maintain the dissolved oxygen level above 20%.

• Journal of Powder Materials
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• v.19 no.6
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• pp.416-423
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• 2012

This paper introduces an effect of a preparing $ZrO_2$-Ag composite on its mechanical properties and microstructure. In present study, $ZrO_2$-Ag was prepared by reduction-deposition route and wetting dispersive milling method, respectively. Two type of Ag powders (nano Ag and micron Ag size, respectively) were dispersed into $ZrO_2$ powder during wetting dispersive milling in D.I. water. Each sample was sintered at $1450^{\circ}C$ for 2hr in atmosphere, and then several mechanical tests and analysis of microstructure were carried out by bending test, hardness, fracture toughness and fracture surface microstructure. As for microstructure, the Ag coated $ZrO_2$ showed homogeneously dispersed Ag in $ZrO_2$ in where pore defect did not appear. However, $ZrO_2$-nano Ag and $ZrO_2$-micro Ag composite appeared Ag aggregation and its pore defect, which carried out low mechanical property and wide error function value.

• Journal of the Korean Applied Science and Technology
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• v.32 no.3
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• pp.480-487
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• 2015

In this study, several kinds of active carbons with high specific surface area and micro pore structure were prepared from the coconut shell charcoal using chemical activation method. The physical property of prepared active carbon was investigated by experimental variables such as activating chemical agents to char coal ratio, flow rate of inert gas and temperature. It was shown that chemical activation with KOH and NaOH was successfully able to make active carbons with high surface area of $1900{\sim}2500m^2/g$ and mean pore size of 1.85~2.32 nm. The coin cell using water-based binder in the electrolyte of LiPF6 dissolved in mixed organic solvents (EC:DMC:EMC=1:1:1 vol%) showed better capacity than that of oil-based binder. Also, it was found that the coin cell of water-based binder shows an improved cycling performance and coulombic efficiency.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.185-197
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• 2019

Deactivation of porous photocatalytic materials was studied using three types of microstructured particles: macroporous titania particles, titania microspheres, and porous silica microspheres containing CNTs and $TiO_2$ nanoparticles. All particles were synthesized by emulsion-assisted self-assembly using micron-sized droplets as micro-reactors. During repeated cycles of the photocatalytic decomposition reaction, the non-dimensionalized initial rate constants (a) were estimated as a function of UV irradiation time (t) from experimental kinetics data, and the results were plotted for a regression according to the exponentially decaying equation, $a=a_0\;{\exp}(-k_dt)$. The retardation constant ($k_d$) was then compared for macroporous titania microparticles with different pore diameters to examine the effect of pore size on photocatalytic deactivation. Nonporous or larger macropores resulted in smaller values of the deactivation constant, indicating that the adsorption of organic materials during the photocatalytic decomposition reaction hinders the generation of active radicals from the titania surface. A similar approach was adopted to evaluate the activation constant of porous silica particles containing CNT and $TiO_2$ nanoparticles to compare the deactivation during recycling of the photocatalyst. As the amount of CNTs increased, the deactivation constant decreased, indicating that the conductive CNTs enhanced the generation of active radicals in the aqueous medium during photocatalytic oxidation.

• Structural Engineering and Mechanics
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• v.86 no.5
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• pp.663-671
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• 2023

Freeze-thaw cycles induce strength loss at the frozen soil-concrete interface and deterioration of bonding, which causes construction engineering problems. To clarify the deterioration characteristics of the interface under the freeze-thaw cycle, a frozen soil-concrete sample was used as the research object, an interface scanning electron microscope test under the freeze-thaw cycle was carried out to identify the micro index information, and an interface shear test was carried out to explore the loss law of interface shear strength under the freeze-thaw cycle. The results showed that the integrity of the interface was destroyed, and the pore number and pore size of the interface increased significantly with the number of freeze-thaw cycles. The connection form gradually deteriorates from surface-to-surface contact to point-to-surface contact and point-to-point contact, and the interfacial shear strength decreases the most at 0-3 freeze-thaw cycles, with small decreases from to 3-8 cycles. After 12 freeze-thaw cycles, the interfacial shear strength tends to be stable, and shear the failure occurs internally in the soil.

• Composites Research
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• v.34 no.1
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• pp.16-22
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• 2021

Polyurethane foam (PUF) can be manufactured in soft, semi-rigid, and hard forms, so it is used in various fields industrially. Among them, rigid PUF has excellent mechanical properties and low thermal conductivity, and is used as a thermal insulation material for buildings and as a cold insulation material in the natural gas transportation field. In this field, there is a steady demand on higher mechanical strength and lower thermal conductivity. In this study, a rigid PUF was manufactured, and the microstructure and physical properties were studied according to the impeller type (propeller, dispersed turbine) of the agitator. Through FE-SEM and Micro-CT analysis, it was confirmed that the average pore size of the foam manufactured with the dispersed turbine was 21.5% smaller than that of the pore made by the propeller. The compressive strength was improved by 15.4%, and the thermal conductivity decreased by 3.1% in the foam with small pores. This result can be utilized for fabricating PUF composites.