• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.235-239
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• 2005

We analyzed the thermal and mechanical behaviors of micro reformer for the purpose of design verifications and modification of micro channels. The reformer designed for hydrogen generation from methanol is essential to PEM(Proton Exchange Membrane) type fuel cell. For the mobile applications, the size and the simplicity would be the most critical issues. We utilized silicon process for micro reformer to obtain the thickness thinner than 2 mm thick. We have used commercial simulation software, IDEAS, to analyze the thermal and mechanical characteristics of micro reformer structure. The heat generation rates of heaters, heat transfer rates, and fluid temperatures are derived from thermal equilibrium relation and these values were used for thermal boundary conditions. We also analyzed the thermal stresses, thermal deformations to examine the possibility of failure.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.217-225
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• 2008

A new micro reformer system consisted of a micro reformer, a microcombustor and a micro evaporator was studied experimentally and computationally. In order to satisfy the primary requirements for designing the microcombustor integrated with a micro evaporator, i.e. stable burning in a small confinement and maximum heat transfer through a wall, the present microcombustor is simply cylindrical to be easily fabricated but two-staged (expanding downstream) to feasibly control ignition and stable burning. Results show that the aspect ratio and wall thickness of the microcombustor substantially affect ignition and thermal characteristics. For the optimized design conditions, a premixed microflame was easily ignited in the expanded second stage combustor, moved into the smaller first stage combustor, and finally stabilized therein. A micro reformer system integrated with a modified microcombustor based on the optimized design condition was fabricated. For a typical operating condition, the designed micro reformer system produced 22.3 sccm hydrogen (3.61 W in LHV) in an overall efficiency of 12%.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2238-2243
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• 2007

A new microcombustor configuration for a micro fuel-cell reformer integrated with a micro evaporator was studied experimentally and computationally. The present microcombustor is simply cylindrical to be easily fabricated but two-staged, expending downstream, to feasibly control ignition and stable burning. Results show that the aspect ratio of the first stage and the wall thickness of the microcombustors substantially affect ignition and thermal characteristics. For the optimized design conditions, a premixed microflame was easily ignited in the expanded second stage combustor, moved into the smaller first stage combustor, and finally stabilized therein. The measured and predicted temperature distributions across the microcombustor walls indicated that heat generated in the microcombustor is well transferred. Thus, the present microcombustor configuration could be applied to the practical micro reformers integrated with a micro evaporator for use of fuel cells.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.225-229
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• 2005

We have designed micro-fuel processor system, which consists of a steam reforming area and a PROX(preferential oxidation) area. Micro-fuel processor system generates $H_2$ rich gas from a methanol. In our experiment, we have integrated micro-fuel processor system using low temperature cofired ceramics (LTCC) process because LTCC is superior to other materials principally due to their high thermal and chemical stability, simpler fabrication processes, and lower materials cost. Therefore, we have studied and integrated micro-fuel processor system containing embedded heaters, cavities, and 3D structures of micro-channel with LTCC. Also we have optimized the LTCC process.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.551-552
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• 2006

The miniature fuel cells have emerged as a promising power source for applications such as cellular phones, small digital devices, and autonomous sensors to embedded monitors or to micro-electro mechanical system (MEMS) devices. Several chemicals run candidate at a fuel in those systems, such as hydrogen. methanol, ethanol, acetic acid, and di-methyl ether (DME). Among them, hydrogen shows most efficient fuel performance. However, there are some difficulties in practical application for portable power sources. Therefore, more recently, there have been many efforts for development of micro-reformer to operate highly efficient micro fuel cells with liquid fuels such as methanol, ethanol, and DME In our experiments, we have integrated a micro-fuel processor system using low temperature co-fired ceramics (LTCC) materials. Our integrated micro-fuel processor system is containing embedded heaters, cavities, and 3D structures of micro- channels within LTCC layers for embedding catalysts (cf. Figs. 1 and 2). In the micro-channels of LTCC, we have loaded $CuO/ZnO/Al_2O_3$ catalysts using several different coating methods such as powder packing or spraying, dipping, and washing of catalyst slurry.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 추계학술대회 논문집
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• pp.615-616
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• 2006

A micro-fuel processor system integrating steam reformer and partial oxidation reactor was manufactured using low temperature cofired ceramic (LTCC). A CuO/ZnO/$Al_2O_3$ catalyst and Pt-based catalyst prepared by wet impregnation were used for steam reforming and partial oxidation, respectively. The performance of the LTCC micro-fuel processor was measured at various operating conditions such as the effect of the feed flow rate, the ratio of $H_2O/CH_3OH$, and the operating temperature on the LTCC reformer and CO clean-up system. The catalyst layer was loaded with "Fill and Dry" coating for small volume. The product gas was composed of $70\sim75%$ hydrogen, $20\sim25%$ carbon dioxide, and $1\sim2%$ carbon monoxide at $250\sim300^{\circ}C$, respectively.

• 대한기계학회논문집B
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• 제30권12호
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• pp.1196-1202
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• 2006

A MEMS methanol reformer was fabricated and its performance was evaluated in the present study. Catalytic steam reforming of methanol was selected because the process had been widely applied in macro scale reformers. Conventional Cu/ZnO catalyst that was prepared by co-precipitation method to give the highest coating quality was used. The reactor structure was made by bonding three layers of glass wafers. The internal structure of the wafer was fabricated by the wet-etching process that resulted in a high aspect ratio. The internal surface of the reactor was coated by catalyst and individual wafers were fusion-bonded to form the reactor structure. The internal volume of the microfabricated reactor was $0.3cm^3$ and the reactor produced exhaust gas with hydrogen concentration at 73%. The production rate of hydrogen was 4.16 ml/hr that could generate power of 350 mW in a typical PEM fuel cell.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2007년도 춘계학술대회 논문집
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• pp.739-740
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• 2007

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 추계학술대회 논문집
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• pp.613-614
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• 2006

• 대한기계학회논문집B
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• 제34권7호
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• pp.689-696
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• 2010

디젤엔진은 높은 열효율과 우수한 연비 성능 등의 장점을 가지고 있으나, 기화된 연료와 주변 공기가 혼합된 후 착화되는 과정을 거치기 때문에 이론 공연비 영역에서는 질소산화물(NOx) 배출이 증가되는 문제점을 가지고 있다. 최근 활발히 연구되고 있는 높은 정화 효율을 가진 LNT 촉매는 희박 분위기 조건에서는 NOx를 흡장하게 되고 과농한 분위기에서는 환원 분위기 형성을 통하여 NOx를 저감시키게 된다. 희박 공연비에서 동작하는 디젤 엔진에서는 이러한 환원 과정을 이루기 위해 주기적으로 과농한 분위기를 형성해주어야만 하는데, 이러한 연구는 NOx 저감을 위해 HC를 포함한 환원제의 농도를 제어하는 기술로서 본 연구에서는 디젤을 연료로 하는 수소농후가스 발생장치를 이용하여 LNT 촉매에 환원제로서 수소농후가스를 직접 공급하는 방식으로 LNT 촉매의 NOx 저감 특성을 파악하였다.