• 한국재료학회지
• /
• 제33권8호
• /
• pp.330-336
• /
• 2023

The effects of Ni²⁺ substitution for Mg²⁺-sites on the microwave dielectric properties of (Mg_1-xNi_x)(Ti_0.95(Mg_1/3Ta_2/3)_0.05)O₃ (0.01 ≤ x ≤ 0.05) (MNTMT) ceramics were investigated. MNTMT ceramics were prepared by conventional solid-state reaction. When the MgO / TiO₂ ratio was changed from 1.00 to 1.02, MgTi₂O₅ was detected as a secondary phase along with the MgTiO₃ main phase in the MNTMT specimens sintered at 1,400 ℃ for 4h. For the MNTMT specimens with MgO / TiO₂ = 1.07 sintered at 1,400 ℃ for 4h, a single phase of MgTiO₃ with an ilmenite structure was obtained from the entire range of compositions. The relative density of all the specimens sintered at 1,400 ℃ for 4h was higher than 95 %. The quality factor (Qf) of the sintered specimens depended strongly on the degree of covalency of the specimens, and the sintered specimens with x = 0.01 showed the maximum Qf value of 489,400 GHz. The dielectric constant (K) decreased with increasing Ni²⁺ content because Ni²⁺ had a lower dielectric polarizability (1.23ų) than Mg²⁺ (1.32ų). As Ni²⁺ content increased, the temperature coefficient of resonant frequency (TCF) improved, from -55.56 to -21.85 ppm/℃, due to the increase in tolerance factor (t) and the lower dielectric constant (K).

• 한국세라믹학회지
• /
• 제28권4호
• /
• pp.338-346
• /
• 1991

The alumina-titania composite powders coated with Al2O3 were prepared by the method of hydrolysis-deposition of mixed aluminium salt solution of Al2(SO)4-Al(NO3)3-Urea. The effects of coating-process parameters on the characteristics of coated composite powders were also investigated. As the content of TiO2 dispersed in deionized water increased, the coated composite powders were found to be more uniform in size and unagglomerated. When TiO2 powders were coated for 30 min, the optimum TiO2 content in the coating process was 400 mg/ι. The size of TiO2 particle was increased approximately from 0.7${\mu}{\textrm}{m}$ to 1.0${\mu}{\textrm}{m}$ through coating of Al2O3. The IEP of coated composite powders was pH=8.3 identical to the value of aluminium hydroxides and the zeta-potential showed nearly similar values each other. When heat treating coated composite powders at 130$0^{\circ}C$, only two phases of TiO2(rutile) and Al2TiO5 were observed. These results showed that the suface of TiO2 could be uniformly coated with the aluminium hydroxide.

• 청정기술
• /
• 제23권1호
• /
• pp.27-33
• /
• 2017

본 연구에서는 중금속 7종(Cu, Cd, Cr, As(III), As(V), Zn, Ni) 및 나노입자 5종(CuO, ZnO, NiO, $TiO_2$, $Fe_2O_3$)에 대한 독성을 수계 대표 생물종인 녹조류 Chlorella vulgaris를 이용한 생물검정법으로 평가하였다. 조류에 미치는 영향은 흡광도, 클로로필 및 개체수 측정에 대한 결과를 통합하여 평가하였다. 중금속의 통합결과독성($TEC_{50}$) 순서는 Cr ($0.7mgL^{-1}$) > Cu ($1.7mgL^{-1}$) > Cd ($3.2mgL^{-1}$) > Zn ($3.9mgL^{-1}$) > Ni ($13.2mgL^{-1}$) > As(III) ($17.8mgL^{-1}$) ${\gg}$ As(V) (> $1000mgL^{-1}$)로 나타났다. 중금속은 측정종말점에 따라 일부 상이한 민감도와 독성이 조사되었다. 나노입자의 독성($TEC_{50}$) 순서는 ZnO ($2.4mgL^{-1}$) > NiO ($21.1mgL^{-1}$) > CuO ($36.6mgL^{-1}$) > $TiO_2$ ($62.5mgL^{-1}$) > $Fe_2O_3$ ($82.7mgL^{-1}$)로 나타났다. 나노입자는 측정종말점간에 비슷한 민감도와 독성을 보였다. 따라서 오염물의 독성을 평가하기 위해서 단일 방법에 의한 결과보다는 다양한 측정종말점의 통합결과에 근거한 접근이 적절할 것이다.

• 한국세라믹학회지
• /
• 제43권1호
• /
• pp.16-21
• /
• 2006

The preparation of $TiB_2$ by SHS in $B_2O_3-Mg-TiO_2$ system was investigated in this study. In the preparation of $TiB_2$, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and $TiO_2$ in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 50atm, the optimum composition for the preparation of pure $TiB_2$ was $B_2O_3+5Mg+TiO_2$. The $TiB_2$ synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1994년도 하계학술대회 논문집 C
• /
• pp.1466-1468
• /
• 1994

In this paper Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics have been investigated as a function of the amount of $SrTiO_3(ST)$. The $SrTiO_3$ content is ranged from 0.01-0.06(wt%). As the amount of ST is increased, dielectric constant has a maximum value at 0.05 mol composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and ramnant polarization has a maximum value at 0.01mol composition.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
• /
• pp.5-8
• /
• 1994

In this paper, Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics hale been investigated as a function of the amount of SrTiO$_3$(ST). The SrTiO$_3$ content is ranged from 0.01-0.05(wt%). As the amount of ST is increased, dielectric constant has a maximun value at 0.05 mol% composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and remnant polarization has a maximum value at 0.01mo1% composiion.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
• /
• pp.15-17
• /
• 2005

In this study, tunable dielectric materials are important for resonator, variable capacitor, phased array antenna and other devices application. In this paper, Dielectric constant increased and tuning range increased with the increased of $BaSrTiO_3/Li_{2}CO_{3}$ content, which probably can be explained by the substitution of Ba3+, Li1+ on BaTiO3 lattice. The tunability and dielectric loss of the $BaSrTiO_2/Li_{2}CO_{3}$ thick film, sintered at $1150^{\circ}C$, were about 43 % and 0.234 at 10$\sim$15 MHz, respectively. In case of BaSrTi/MgO, Dielectric constant decreased and tenability increased with the added of $BaSrTiO_3/MgO$. The ferroelectrics properties were distinct when adding Li to BST ceramic thick film, and paraelectrics pattern was distinct when adding Mg.

• 한국재료학회지
• /
• 제11권1호
• /
• pp.44-47
• /
• 2001

Ni 전극을 사용하는 $BaTiO_3$계 내환원성 X7R 조성에서 $Er_2$$O_3$ 첨가가 유전특성에 미치는 영향에 대하여 환원성 분위기에서 연구하였다. $MnO_2-MgO$가 첨가된 내환원조성에서 첨가량이 조절된 $Er_2O_3$의 복합첨가로 유전율의 온도안정성이 향상되어 X7R 규격을 만족시켰으며 2,970 이상의 상온 유전상수와 1.0% 이하의 유전손실율이 관찰되었다. $Er_2O_3$가 3.0 mol% 이상으로 과량 첨가되었을 경우 유전체의 온도특성은 향상되었으나 상온 유전상수가 현저히 감소하였다. 다른 첨가조성(1.5 mol% $Er_2O_3$2.0 mol% MgO)이 고정될 때 TCC곡선은 $MnO_2$첨가량이 증가함에 따라 시계방향으로 회전하였으며, 온도안정성을 향상시켰다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
• /
• pp.193-195
• /
• 1994

In this study, the structural, dielectric and piezoelectrical properties of $xPb(Mg_{1/2}W_{1/2})O_3-(1-x)[0.41Pb(Ni_{1/3}Nb_{2/3})O_3-0.36PbTiO_3-0.23P Zr)_3]$ (x=0, 0.01, 0.02, 0.03, 0.04, 0.05) system ceramics were investigated. The dielectric constant ${\varepsilon_{33}}^{\tau}$ at loon temperature increased up to 3mol% PMW and decreased with further PMW content. The specimen with 1mol% $Pb(Mg_{1/2}W_{1/2})O_3$, which has the ${\varepsilon_{33}}^{\tau}=5509$, kp=59[%] and $d_{33}=758{\times}10^{-12}[C/N]$, exhibits good characteristics.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제55권12호
• /
• pp.555-559
• /
• 2006

Using the $Ba_{0.5}Sr_{0.5}TiO_3$(BST) powders prepared by the Sol-Gel method, the BST thick films were fabricated on the $Al_2O_3 $substrates coated with Pt by the screen printing method. Compared with pure BST thick films, the structural and dielectric properties of the BST thick films doped with $1{\sim}10$ wt % MgO were investigated. It was observed that the Mg substitution into BST causes a shift in the cubic-tetragonal BST phase transition peak to a lower temperature. The microstructure of the BST substituted with Mg was homogeneous and dense. Mg substitution into BST had a significant effect on the grain size reduction. Dielectric constant was decreased with increasing the MgO content and temperature. In the case of BST thick films doped with 1 wt% MgO, the relative permittivity and dielectric loss were 1581 and 1.4 % at 1 MHz.