• Title/Summary/Keyword: MgO : $LiNbO_3$

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Microstructure and Piezoelectric Properties of Low Temperature Sintering PMW-PNN-PZT-BF Ceramics According to PNN Substitution (PNN 치환에 따른 PMW-PNN-PZT-BF 세라믹스의 미세구조와 압전 특성)

  • Sin, Sang-Hoon;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.2
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    • pp.90-94
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    • 2016
  • In this work, [$Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_x(Zr_{0.5}Ti_{0.5})_{0.97-x}O_3-BiFeO_3$] (x=0.02 to 0.12) composition ceramics were fabricated by the conventional soild state reaction method and their microstructure and piezoelectric properties were investigated according to PNN substitution. The addition of small amount of $BiFeO_3$, $Li_2CO_3$, and $CaCO_3$ were used in order to decrease the sintering temperature of the ceramics. The XRD (x-ray diffraction patterns) of all ceramics exhibited a perovskite structure. The sinterability of PMW-PNN-PZT-BF ceramics was remarkably improved using liquid phase sintering of $CaCO_3$, $Li_2CO_3$. However, it was identified from of the X-ray diffraction patterns that the secondary phase formed in grain boundaries decreased the piezoelectric properties. According to the substitution of PNN, the crystal structure of ceramics is transformed gradually from a tetragonal to rhombohedral phase. The x=0.10 mol PNN-substituted PMW-PNN-PZT-BF ceramics sintered at $920^{\circ}C$ showed the optimum values of piezoelectric constant($d_{33}$), piezoelectric figure of merit($d_{33{\cdot}}g_{33}$), planar piezoelectric coupling coefficient($k_p$) and density : $d_{33}=566$ [pC/N], $g_{33}=29.28[10^{-3}mV/N]$, $d_{33{\cdot}}g_{33}=16.57[pm^2/N]$, $k_p=0.61$, density=7.82 [$g/cm^3$], suitable for duplex ultrasonic sensor application.

Surface Acoustic Wave Characteristics of Piezoelectric Materials and Protein Immobilization (압전 재료의 탄성표면파 특성과 단백질의 고정화)

  • Chong, Woo-Suk;Hong, Chul-Un;Kim, Gi-Beum
    • Korean Chemical Engineering Research
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    • v.44 no.2
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    • pp.166-171
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    • 2006
  • In this study, in using a piezoelectric material of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ (PMN-PT), which has a high electromechanical coupling coefficient, we have tried to study about this material can be practically available as a new biosensor to detect protein by using surface acoustic wave (SAW). As the results, the filtering of the center frequency of the PMN-PT substrate is a superior result to that of the $LiTaO_3$ (LT) substrate, but the result was not completely satisfactory. Also this study attempts to develop a sensing method to detect mismatched DNA in order to diagnose cancer. We could directly immobilize the MutS to the NTA using the EDC solution. But, we immobilized MutS using nickel and it is judged that is more effective method to detect mismatched DNA.

Mineralogy and Chemical Composition of the Residual Soils (Hwangto) from South Korea (우리 나라 황토(풍화토)의 구성광물 및 화학성분)

  • 황진연;장명익;김준식;조원모;안병석;강수원
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.3
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    • pp.147-163
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    • 2000
  • The mineralogy and chemical composition of reddish to brownish yellow residual soils, so called "Hwangto" have been examined according to representative host rocks. The result of the study indicates that Hwangto consists of 40-80% clay minerals and various minerals such as quartz, feldspar, hornblende, goethite, and gibbsite. Clay minerals include kaolinite, halloysite, illite, hydroxy interlayered vermiculite (HIV), mica/vermiculite interstratifield mineral and chlorite. The mineralogical constituents and contents of Hwangto were different depending on the types of host rocks. Moreover, the Jurassic granitic rocks contain relatively more kaolin minerals, whereas the Cretaceous granitic rocks contain more HIV and illite. In addition, reddish Hwangto contains relatively more kaolinite and HIV, and yellowish Hwangto contains more illite and halloysite. It is suggested that feldspars and micas of host rocks were chemically weathered into illite, halloysite, illite/vermiculite interstratified minerals, and HIV, and finally into kaolinite. Compared with their host rocks, the major chemical compositions of Hwangto tend to contain more $Al_2O_3,\;Fe_2O_3,\;H_2O$ in amount and less Ca, Mg, and Na. Hwangto contains relatively high amount of trace elements, P, S, Zr, Sr, Ba, Rb, and Ce including considerable amount of Li, V, Cr, Zn, Co, Ni, Cu, Y, Nb, La, Nd, Pb, Th in excess of 10 ppm. Relatively high amount of most trace elements were detected in the Hwangto. The major and minor chemical compositions of the Hwangto were different depending on the types of host rocks. However, their difference was in the similar range compared with the compositions of host rocks.

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Double-pass Second Harmonics Generation of Tunable CW Infrared Laser Beam of DOFA System in Periodically Poled LiNbO3 (PPLN 비선형 결정과 이중통과법을 이용한 DOFA 시스템에서 증폭된 연속발진형 파장가변 적외선 레이저광의 제 2고조파 발생)

  • Yoo, Kil-Sang;Jo, Jae-Heung;Ko, Kwang-Hoon;Lim, Gwon;Jeong, Do-Young
    • Korean Journal of Optics and Photonics
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    • v.19 no.3
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    • pp.229-236
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    • 2008
  • The optimum conditions of second harmonic generation (SHG) can be successfully achieved experimentally using single pass and double pass methods of a pumping beam. The beam has a power of several Watts radiated by a DOFA (Diode Laser Oscillator & Fiber Amplifier) system, which is a high power CW wavelength tunable infrared laser system, in a PPLN (Periodically Poled MgO doped Lithium Niobate) nonlinear crystal. In the case of a single pass method, the parameters are the wavelength of 535 nm for SHG and the output power of 245 mW generated from the pumping input beam with wavelength of 1070 nm and the power of 2.45 W at phase matching temperature of $108.9^{\circ}C$. The conversion efficiency of SHG was 10%. In order to enhance the output of SHG, the double pass method of the SHG system of a PPLN using a concave mirror for the retroreflection and a pair of wedged flat windows for phase compensation was also presented. In this double pass system, we obtained the SHG output beam with the wavelength of 535 nm and the maximum power of 383 mW at optimum phase matching temperature of $108.5^{\circ}C$ by using an incident pumping beam with wavelength of 1070 nm and the power of 2.45 W. The maximum conversion efficiency is 15.6%, which is more than that of the single pass method.