• Title/Summary/Keyword: Mg-Al-Zn 합금

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Corrosion behavior of Zn-MgZn2 Eutectic Structure in Zn-Mg-Al alloy coated steel (Zn-Mg-Al 합금도금강판의 Zn-MgZn2 공정조직의 부식거동)

  • Lee, Jae-Won;Son, Hong-Gyun;Min, Jae-Gyu;Yu, Yeong-Ran;Gwak, Yeong-Jin;Kim, Tae-Yeop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.280-280
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    • 2012
  • Mg의 첨가한 Zn-Mg-Al 합금도금강판에 형성된 $Zn-MgZn_2$ 공정조직의 부식거동을 이해하고자 진공 고주파 용해로 $MgZn_2$ 제작한 후 Zn와 galvanic coupling하여 $MgZn_2$합금과 Zn간의 galvanic corrosion 거동을 알아보았다. $MgZn_2-Zn$ galvanic coupling의 SVET 결과에서 $MgZn_2$가 anode, Zn가 cathode가 됨을 확인되었다. $MgZn_2$의 Zn와의 galvanic corrosion 평가에서 galvanic current는 Zn 보다 낮은 potential에서 anodic current density를 나타내었으며, galvanic potential은 $MgZn_2$전위로부터 두 합금의 혼합전위를 향해 증가함을 알 수 있었다. Zn-Mg-Al 합금도금강판의 염수분무 평가에서도 초기 $Zn-MgZn_2$ 공정조직에서 $MgZn_2$가 용출되는 것이 관찰되었다.

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Distribution Behavior of Solute Element in Al-Mg-Zn Alloy Continuous Cast Billet During Homogenization Treatment (Al-Mg-Zn계 알루미늄 합금 연주 빌렛 균질화처리과정 중 용질원소 거동변화)

  • Myoung-Gyun Kim
    • Journal of Korea Foundry Society
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    • v.43 no.6
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    • pp.286-293
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    • 2023
  • In this study, we investigated the microstructural evolution of Al-Mg-Zn aluminum alloy billet during homogenization treatment using OM, SEM, EDS and DSC. There were numerous phases found, such as; AlMgZn, AlMgFe, and AlMgZnSi phases, in the grain of the cast billet. After 6 hours homogenization treatment, Zn was mostly dissolved, whereas, Mg and Si were only partly dissolved. Accordingly, only AlMgFe and AlMgSi remained. After 18 hours, all of the leftover Mg and Si were dissolved, leaving only AlMgFe, which was also found after 24 hours. The results of the alloy design program, JMatPro showed that Mg dissloved more rapidly than Zn. According to the homogenization kinetic equation, Mg and Zn are completely dissolved within 1.9 and 3.5 hours, respectively.

Mechanical Properties and Castabilities of Al-12Mg-5.5Zn-xSi Alloys

  • Kim, Jeong-Min;Sung, Ki-Dug;Jun, Joong-Hwan;Kim, Ki-Tae;Jung, Woon-Jae
    • Journal of Korea Foundry Society
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    • v.24 no.6
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    • pp.340-346
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    • 2004
  • The plan for obtaining a good combination of strength and castability appeared feasible and the following observations were made. 1. In Al-12Mg-6.6Zn-xSi alloys, more primary $Mg_2Si$ phase formed with reduced $Al_3Mg_2$ phase, as Si content is necessary for an effective solution heat treatment because the solidus temperature is very low silicon contents. 2. A high tensile strength could be obtained in the heat-treated Al-12Mg-5.5Zn-5Si alloy attributed in the heat-treated Al-12Mg-5.5Zn-5Si alloy attributes to fine $MgZn_2$ particles that precipitated uniformly in the matrix. 3. Al-12Mg-5.5Zn-Si alloys showed excellent casting capabilities such as hot cracking resistance and fluidity compared to the reference commercial alloys. 4. The wear resistance of Al-12Mg-5.5Zn-5Si alloy was superior to that of A7075 alloy, and even higher resistance is expected if the morphology and size of primary $Mg_2Si$ phase is carefully controlled.

The Effects of Al-Alloying Elements on the Melt Oxidation(II, Oxide Layer Shape and Microstructure) (Al-합금의 원소가 용융산화에 미치는 영향(ll. 산화층 형상과 미세구조))

  • Jo, Chang-Hyeon;Gang, Jeong-Yun;Kim, Il-Su;Kim, Cheol-Su;Kim, Chang-Uk
    • Korean Journal of Materials Research
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    • v.7 no.8
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    • pp.660-667
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    • 1997
  • AI-Mg-합금의 용융산화에 의해 생성되는 AlO$_{2}$O$_{3}$-복합재료의 미세구조에 미치는 합금원소의 영향을 연구하였다. AI-1Mg 합금과 AI-3Mg 합금을 기본으로하여 Si, Zn, Sn, Cu, Ni, Ca, Ce를 1, 3, 5 %를 무게비로 첨가하였다. 각 합금을 1473K에서 20시간 유지하여 산화시킨 후 산화층의 거시적 형상과 미세구조를 광학현미경으로 관찰하였다. 각 미세구조의 상분율을 상분석기로 측정하였다. 산화층의 최첨단면은 SEM과 EDX로 관찰하고 분석하였다. Cu나 Ni를 첨가한 합금으로부터 성장한 산화층의 미세구조가 가장 치밀하였다. Zn이 포함된 합금으로부터 성장한 산화층 최첨단 성장면에는 ZnO가 관찰되었다. Zn이 포함되지 않은 다른 합금의 성장 전면에는 항상 MgAi$_{2}$O$_{4}$상이 관찰되었다.

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A Study on the Die Casting of Mg-9Al-1Zn Alloy for Air Bag Case (Mg-9Al-lZn 합금 자동차 에어백 케이스의 다이캐스팅에 관한 연구)

  • Kim, Sun-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.10
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    • pp.77-83
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    • 2002
  • Magnesium alloys casting are gaining increased acceptance in the automotive and electronic industeries and die casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Mg-9Al-lZn alloy fabricated by die casting process for development of air bag case. The microstructure of die casted specimen were composed of pro-eutectic magnesium solid solution and $\beta$(Mg17Al12) precipitates. The tensile strength of as-fabricated Mg-9Al-lZn alloy revealed 231.4MPa. It was found that Mg-9Al-lZn alloy have good corrosion resistance in electrochemical polarization test.

The Squeeze Casting and Its Structure of Mg-Al-Zn Alloy (Mg-Al-Zn합금에 있어서의 용탕단조와 그 조직)

  • Choi, J.C.;Choi, Y.D.
    • Journal of Korea Foundry Society
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    • v.17 no.5
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    • pp.419-425
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    • 1997
  • 용탕단조방법에 의해 제조된 Mg-6Al-xZn(x=0, 1, 2)합금의 기계적 성질에 미치는 시효열처리의 영향을 조사한결과 아래와 같은 결론을 얻었다. (1) 주조조직을 관찰한 결과 미세한 수지상조직을 나타냈으며 초정${\alpha}$, 과포화 ${\alpha}$, ${\beta}$상 등 세가지 상으로 구성되어 있었다. (2) Mg-6Al-xZn합금은 시효경화성을 나타내었으며 Zn의 첨가량이 증가할수록 전시효구간에서 경도값이 높게 나타났다. (3) 시효조직을 관찰한 결과 $200^{\circ}C$의 시효시에는 불연속 석출물이 대부분 차지했으나 $240^{\circ}C$의 시효온도에서는 수지상 경계에서 시작되는 미세분산된 연속석출물이 대부분 이었다. (4) $240^{\circ}C$에서 시효열처리 한 시편은 연속석출물이 석출됨으로서 $200^{\circ}C$에서의 시효열처리된 시편에 비하여 과시효되는 경향이 작았다. (5) T6열처리 후 인장시험 결과 Zn 첨가량에 따라 강도가 증가하였는데 Mg-6Al-2Zn합금의 경우 인장강도는 248.4 MPa을 나타내었으며 Zn양에 따른 연신율의 감소는 나타나지 않았다.

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Weld Cracking of High Strength Al-Zn-Mg Alloy Weldment (용접구조용 7000 계열 고장력 Al-Zn-Mg 합금의 용접특성과 용접균열에 관한 고찰)

  • 김환태;황선효;남수우
    • Journal of Welding and Joining
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    • v.12 no.1
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    • pp.28-37
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    • 1994
  • 본 소고에서는 Al-Zn-Mg 계통의 고강도 알루미늄합금의 제조과정에서 실시하는 열처리 공정을 통해 얻어지는 시효경화 효과, 합금원소 첨가에 따른 석출물의 생성과 이에 따른 석출경화 효과와 용착금속의 응고균열 발생과의 상호관계를 조사하고 용접열영향부의 용질원자 확산과 입계의 liquid film에 의한 액화(liquation) 균열의 생성을 분석하여 설명하고자 한다.

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Evaluation of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Maximum Load Conditions Using Residual of Random Variable (최대하중조건에 따른 Mg-Al-Zn 합금의 확률변수 잔차를 이용한 확률론적 피로균열전파모델 평가)

  • Choi, Seon Soon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.1
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    • pp.63-69
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    • 2015
  • The primary aim of this paper is to evaluate the probabilistic fatigue crack propagation models using the residual of a random variable and to present the probabilistic model fit for the probabilistic fatigue crack growth behavior in Mg-Al-Zn alloys under maximum load conditions. The models used in this study were prepared by applying a random variable to empirical fatigue crack propagation models such as the Paris-Erdogan model, Walker model, Forman model, and modified Forman model. It was verified that the good models for describing the stochastic variation of the fatigue crack propagation behavior in Mg-Al-Zn alloys under maximum load conditions were the 'probabilistic Paris-Erdogan model' and 'probabilistic Walker model'. The influence of the maximum load conditions on the stochastic variation of fatigue crack growth is also considered.

A Study of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Different Specimen Thickness Conditions by Using the Residual of a Random Variable (확률변수의 잔차를 이용한 Mg-Al-Zn 합금의 시편두께 조건에 따른 확률론적 피로균열전파모델 연구)

  • Choi, Seon-Soon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.4
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    • pp.379-386
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    • 2012
  • The primary aim of this paper was to evaluate several probabilistic fatigue crack propagation models using the residual of a random variable, and to present the model fit for probabilistic fatigue behavior in Mg-Al-Zn alloys. The proposed probabilistic models are the probabilistic Paris-Erdogan model, probabilistic Walker model, probabilistic Forman model, and probabilistic modified Forman models. These models were prepared by applying a random variable to the empirical fatigue crack propagation models with these names. The best models for describing fatigue crack propagation behavior in Mg-Al-Zn alloys were generally the probabilistic Paris-Erdogan and probabilistic Walker models. The probabilistic Forman model was a good model only for a specimen with a thickness of 9.45 mm.

The Influence of Alloying Elements on the Fluidity of Al-Zn-Mg Alloys (Al-Zn-Mg계 알루미늄 합금의 유동성에 미치는 합금원소의 영향)

  • Cho, Jea-Sup;Kim, Jee-Hun;Sim, Woo-Jeong;Im, Hang-Joon
    • Journal of Korea Foundry Society
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    • v.32 no.3
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    • pp.127-132
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    • 2012
  • Al-Zn-Mg alloys, being high strength aluminum alloys, have attracted attention as a material of automobile parts that require higher mechanical properties and lightness. Automobile parts with complex shapes are manufactured by low-priced casting method, but Al-Zn-Mg alloys are difficult to cast because of its poor hot cracking, feeding, and fluidity. Thus fluidity experiments on Al-Zn-Mg alloys were conducted for the castability evaluation. The effects of Mg and Zn, representative elements of Al-Zn-Mg alloys, on fluidity were observed. Spiral mold was used for fluidity experiments and the lengths of solidified specimens were measured after melting and gravity casting. Correlation between microstructures and fluidity length based on the alloy composition was considered. According to the experimental results, as the amount of Mg and Zn increased, fluidity decreased. Also, it was confirmed that fluidity change by the variation of Mg composition was greater than that of Zn.