• Title/Summary/Keyword: Mg-Al alloys

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Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Mechanical Properties of Ultrafine Grained Materials via Equal-Channel Angular Pressing (ECAP가공에 의한 초미세립 소재의 기계적 물성)

  • Ko, Y.G.;Kim, W.G.;Ahn, J.Y.;Park, K.T.;Lee, C.S.;Shin, D.H.
    • Transactions of Materials Processing
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    • v.15 no.2 s.83
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    • pp.105-111
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    • 2006
  • A study was made to investigate the microstructure and the mechanical properties of low-carbon steel, Al-Mg alloy and Ti-6Al-4V alloy each representing bcc, fcc and hcp crystal structures, respectively fabricated by equal-channel angular(ECA) pressing. After a series of ECA pressings was performed, most grains were significantly refined below ${\mu}m$ in diameter with high mis-orientation of grain boundaries irrespective of different crystal structure used. Regarding the strain hardening capability, tensile tests of ultrafine grain (UFG) dual-phase (ferrite/martensite) steel which was different from UFG ferrite-pearlite steel were carried out at ambient temperature, and corresponding mechanical properties were discussed in relation to modified C-J analysis. Low-temperature and/or high strain-rate superplasticity of the UFG Al-Mg alloy and UFG Ti-6Al-4V alloy were also studied. Based on the analysis used in this study, it was concluded that UFG alloys exhibited the enhanced mechanical properties as compared to coarse-grained (CG) counterparts.

Potential Difference of Cyclic Polarization Curve of an Aircraft Al Alloy: ∆E (Esec,corr - Ecorr)

  • Sun, Qingqing;Chen, Kanghua
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.140-147
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    • 2020
  • This paper presents a hypothesis and its experimental validation that ∆E (Esec,corr - Ecorr) of cyclic polarization curve of an Al-Zn-Mg-Cu alloy decreases firstly and then increases with the increasing of corrosion rate or corroded fraction Fcorr of alloy surface. The minimum value of ∆E is obtained when Fcorr ≈ 50%. In addition, a proportional relationship between ∆E and |50% - Fcorr| was found. This non-monotonic relation between ∆E and extent of localized corrosion indicates that additional attention should be paid on using ∆E to assess localized corrosion behaviour of Al-Zn-Mg-Cu alloys.

Tensile Behavior of Cast-Forged Al-Si-Mg Alloy (주/단조 Al-Si-Mg 합금의 인장 거동)

  • Kim K. J.;Kwon Y.-N.;Lee Y. S.;Jeong S. C.;Lee J. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.329-332
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    • 2004
  • Cast-forging process has a lot of advantages in terms of saving materials along with enhancement of mechanical properties. Therefore, this process has been taken as one of candidate process to manufacturing automotive suspension parts. Since most of cast-forging parts are made with using Al-Si alloys of high castability, the mechanical properties largely depends on the primary ${\alpha}$ and eutectic Si particles. During hot forging step these microstructural features evolve with strain increment. In the present study, the mechanical property evolution was investigated in terms of microstructual evolution with strain. Specially, fracture behavior of A356 alloy was studied to find out how to improve the mechanical properties.

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MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AS CAST Al-6.5Mg-1.5Zn-0.5Fe ALLOY FOLLOWED BY COLD ROLLING AND SUBSEQUENT ANNEALING

  • SEONG-HEE LEE
    • Archives of Metallurgy and Materials
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    • v.64 no.3
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    • pp.875-878
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    • 2019
  • Microstructures and mechanical properties of as-cast Al-6.5Mg-1.5Zn-0.5Fe alloys newly alloy-designed for the parts of automobile were investigated in detail. The aluminum (Al) sheets of 4 mm thickness, 30 mm width and 100 mm length were reduced to a thickness of 1mm by multi-pass rolling at ambient temperature and subsequently annealed for 1h at 200~500℃. The as-cast Al sheet was deformed without a formation of so large cracks even at huge rolling reduction of 75%. The recrystallization begun to occur at 250℃, it finished at 350℃. The as-rolled material showed tensile strength of 430 MPa and tensile elongation of 4.7%, however the specimen after annealing at 500℃ showed the strength of 305 MPa and the elongation of 32%. The fraction of high angle grain boundaries above 15 degree increased greatly after annealing at high temperatures. These characteristics of the specimens after annealing were discussed in detail.

Prediction of the Liquidus Temperature Curve for Hypoeutectic Al-Si-Cu-Mg Alloy (아공정 Al-Si-Cu-Mg 합금의 액상선 온도 곡선 예측)

  • Kim, Keunhak;Park, Dongsung;Oh, Seung-Jin;Jeon, Junhyub;Yoon, Sang-Il;Kim, Ki-Sun;Kim, Tae-Young;Lee, Seok-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.6
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    • pp.300-306
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    • 2018
  • In the present study we proposed new equations to predict the liquidus temperature curve for hypoeutectic Al-Si-Cu-Mg alloy. A thermodynamic simulation was carried out to calculate the liquidus temperature, eutectic temperature and eutectic Si concentration with different Si, Cu, and Mg contents in hypoeutectic Al-Si alloys. Regressed equations were derived using the thermodynamic simulation results by multiple regression analysis. The proposed equations were compared with the equations reported previously by other researchers and agreed better with the experimental data. The addition of Cu and Mg lowered the eutectic temperature. The eutectic Si concentration was decreased by adding Cu whereas that was increased by adding Mg. Al-Si binary phase diagram was successfully predicted with a consideration of the effect of Cu and Mg addition by using the proposed equations.

Evaluation on Damage Behavior of Al-4.5%Mg-0.6%Mn Al Alloy with Potentiostatic Experiment Time (Al-4.5%Mg-0.6%Mn 알루미늄 합금의 정전위 시간 변수에 따른 손상거동 평가)

  • Kim, Seong-Jong;Woo, Yong-Bin;Han, Min-Su;Jang, Seok-Ki
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.6
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    • pp.569-576
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    • 2012
  • In general, aluminum alloys forms the passive film($Al_2O_3$, $Al_2O_3{\cdot}3H_2O$) in neutral solution. However, the passive film created on the surface will be destroyed by chloride ions contained in sea water so the corrosion will occur. In this study, in order to solve the problem of corrosion under a seawater environment, potentiostatic protection techniques were applied to Al-4.5%Mg-0.6%Mn aluminum alloy in seawater. At polarization experiments, active state were observed at anodic polarization and concentration polarization by reduction of dissolves oxygen and activation polarization were found at anodic polarization. As a results of potentiostatic experiment, calcareous deposit were created much more as applying time increase from the turning point of the concentration polarization and activation polarization and crevice corrosion was partially observed between calcareous deposit and surface of base metal. Overall potentiostatic anodic polarization experiment was difficult to apply potentiostatic corrosion protection technology by occurrence of active state, whereas potentiostatic cathodic polarization experiment examined optimum corrosion protection condition of -1.1 V~-0.75 V within the range of concentration polarization considered various applying time.

Formation of Bioactive Surface by PEO-treatment after 2nd ATO Technique of Ti-6Al-4V Alloy (Ti-6Al-4V 합금에 2nd ATO 처리 후 플라즈마 전해 산화법에 의한 생체활성표면형성)

  • Lim, Sang-Gyu;Cho, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.74-74
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    • 2018
  • Ti-6Al-4V alloys have been widely used as orthopedic materials because of their excellent corrosion resistance and mechanical properties. However, it does not bind directly to the bone, so it requires a surface modification. This problem can be solved by nanotube and micropore formation. Plasma electrolytic oxidation (PEO) treatment for micropore, which combines high-voltage spark and electrochemical oxidation, is a new way of forming a ceramic coating on light metals such as titanium and its alloys. This method has excellent reproducibility and can easily control the shape and size of the Ti alloy. In this study, formation of bioactive surface by PEO-treatment after $2^{nd}$ ATO technique of Ti-6Al-4V alloy was invesgated by various instrument. Nanotube oxide surface structure was formed on the surface by anodic oxidation treatment in 0.8 wt.% NaF and 1M $H_3PO_4$ electrolytes. After nanotube formation, nanotube layer was removed by ultrasonic cleaning. PEO-treatment was carried out at 280V for 3 minutes in the electrolytic solution containing the bioactive substance (Mg, Zn, Mn, Sr, and Si). The surface of Ti-6Al-4V alloy was observed by field emission scanning electron microscopy (FE-SEM, S-4800 Hitachi, Japan). An energy dispersive X-ray spectrometer (EDS, Inca program, Oxford, UK) was used to analyze the spectra of physiologically active Si, Mn, Mg, Zn, and Sr ions. The PEO film formed on the Ti-6Al-4V alloy surface was characterized using an X-ray diffractometer (TF-XRD, X'pert Philips, Netherlands). It is confirmed that bioactive ions play an essential role in the normal bone growth and metabolism of the human skeletal tissues.

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Application of Explainable Artificial Intelligence for Predicting Hardness of AlSi10Mg Alloy Manufactured by Laser Powder Bed Fusion (레이저 분말 베드 용융법으로 제조된 AlSi10Mg 합금의 경도 예측을 위한 설명 가능한 인공지능 활용)

  • Junhyub Jeon;Namhyuk Seo;Min-Su Kim;Seung Bae Son;Jae-Gil Jung;Seok-Jae Lee
    • Journal of Powder Materials
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    • v.30 no.3
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    • pp.210-216
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    • 2023
  • In this study, machine learning models are proposed to predict the Vickers hardness of AlSi10Mg alloys fabricated by laser powder bed fusion (LPBF). A total of 113 utilizable datasets were collected from the literature. The hyperparameters of the machine-learning models were adjusted to select an accurate predictive model. The random forest regression (RFR) model showed the best performance compared to support vector regression, artificial neural networks, and k-nearest neighbors. The variable importance and prediction mechanisms of the RFR were discussed by Shapley additive explanation (SHAP). Aging time had the greatest influence on the Vickers hardness, followed by solution time, solution temperature, layer thickness, scan speed, power, aging temperature, average particle size, and hatching distance. Detailed prediction mechanisms for RFR are analyzed using SHAP dependence plots.

Evaluation of Joint Properties of Friction Stir Welded AZ31B Mg Alloy (FSW를 이용한 AZ31B Mg합금의 접합성 평가)

  • 노중석;김흥주;장웅성;방국수
    • Journal of Welding and Joining
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    • v.22 no.3
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    • pp.56-61
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    • 2004
  • Friction stir weldability of AZ31B Mg alloy was studied using microstructural observation and mechanical tests. Defect free joints was obtained under the condition of 2000rpm-100mm/min. In TMAZ, a lot of twin deformation were observed due to the mechanical effect of the FSW tool and thus relatively high hardness was obtained. In SZ, the twin deformation was disappeared by recovery and the hardness decreased because the. grain structure was coarsened by dynamic recrystallization and grain growth. The Al-Mn precipitates were observed throughout the joint regions. On the other hand, $$\beta$-Mg_{17}Al_{12}$ intermetallic compounds were not observed in either of the zone. The joint efficiency was about 80% and the impact value of the joint was almost equal to that of base metal.