• Title/Summary/Keyword: Mg electrode

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A Study on Servo DC Resistance Spot Welding of Mg Alloy Sheet(1) (Mg합금판재의 서보가압식 DC점용접에 관한 연구(1))

  • Jung, Sun-Nyeo;Chang, Hee-Seok;Lee, Mok-Young
    • Journal of Welding and Joining
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    • v.27 no.1
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    • pp.102-107
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    • 2009
  • Weldability of Mg alloy was investigated using servo-actuated DC resistance spot welder. Due to its uncommon electrical and mechanical properties, lots of voids and cracks were observed inside nugget with conventional weld schedule. Lobe curve was proposed to clarify proper electrode force and weld current, which guarantee reasonable weld strength and fatigue life. Macro structure of sectioned specimen was examined to count total number of void and crack. Post weld schedule is also proposed to reduce micro victors hardness value of weld zone.

Prevention of Crevice Corrosion of STS 304 Stainless Steel by a Mg-alloy Galvanic Anode

  • Lim, U.J.;Yun, B.D.;Kim, J.J.
    • Corrosion Science and Technology
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    • v.5 no.3
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    • pp.90-93
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    • 2006
  • Prevention of crevice corrosion was studied for STS 304 stainless steel using a Mg-alloy galvanic anode in solutions with various specific resistivity. The crevice corrosion and corrosion protection characteristics of the steel was investigated by the electrochemical polarization and galvanic corrosion tests. Experimental results show that the crevice corrosion of STS 304 stainless steel does not occur in solutions of high specific resistivity, but it occurs in solutions of low specific resistivity like in solutions with resistivities of 30, 60 and $115{\Omega}{\cdot}m$. With decreasing specific resistivity of the solution, the electrode potential of STS 304 stainless steel in the crevice is lowered. The potential of STS 304 stainless steel in the crevice after coupling is cathodically polarized more by decreasing specific resistivity indicating that the crevice corrosion of STS 304 stainless steel is prevented by the Mg-alloy galvanic anode.

Development of a cholesterol biosensor modified with carbon nanotube (탄소나노튜브를 이용하여 개조한 콜레스테롤 바이오 센서 개발)

  • Kim, Haidong
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.425-429
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    • 2015
  • A cholesterol biosensor was developed using a modified carbon electrode with carbon nanotubes. The disposable cholesterol biosensor was modified with carbon nanotubes to enhance electron transfer during the enzymatic reaction of cholesterol. Cholesterol oxidase and peroxidase, with potassium ferrocyanide as a mediator, were immobilized on a screen-printed carbon nanotube electrode. The electrochemical cholesterol biosensor developed using carbon nanotubes showed a rapid and reliable signal for measuring total cholesterol. The cholesterol sensor showed a linear response in 5 seconds with a small volume (0.5 μL) in the range of 100~400 mg/dL, with a coefficient of variation of 4.0%.

An ionic liquid incorporated gel polymer electrolyte for double layer capacitors

  • Perera, Kumudu S.;Prasadini, K.W.;Vidanapathirana, Kamal P.
    • Advances in Energy Research
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    • v.7 no.1
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    • pp.21-34
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    • 2020
  • Energy storage devices have received a keen interest throughout the world due to high power consumption. A large number of research activities are being conducted on electrochemical double layer capacitors (EDLCs) because of their high power density and higher energy density. In the present study, an EDLC was fabricated using natural graphite based electrodes and ionic liquid (IL) based gel polymer electrolyte (GPE). The IL based GPE was prepared using the IL, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (1E3MITF) with the polymer poly(vinyl chloride) (PVC) and the salt magnesium trifluoromethanesulfonate (Mg(CF3SO3)2 - MgTF). GPE was characterized by electrochemical impedance spectroscopy (EIS), DC polarization test, linear sweep voltammetry (LSV) test and cyclic voltammetry (CV) test. The maximum room temperature conductivity of the sample was 1.64 × 10-4 Scm-1. The electrolyte was purely an ionic conductor and the anionic contribution was prominent. Fabricated EDLC was characterized by EIS, CV and galvanostatic charge discharge (GCD) tests. CV test of the EDLC exhibits a single electrode specific capacitance of 1.44 Fg-1 initially and GCD test gives 0.83 Fg-1 as initial single electrode specific discharge capacitance. Moreover, a good stability was observed for prolonged cycling and the device can be used for applications with further modifications.

Effects of Nafion Contents on the Performance of MEAs Prepared by Decal-Transfer Method (Nafion 함량이 데칼전사기법을 통해 제작된 고분자 전해질 연료전지의 MEA 성능에 미치는 영향)

  • Kim, Gyeong-Hee;Cho, Eun-Ae;Han, Jong-Hee;Kim, Sung-Hyun;Eom, Kwang-Sup
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.125-133
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    • 2012
  • Nafion ionomer located in electrode helps to increase the platinum utilization and proton conductivity. To achieve higher performance in PEMFCs, it is important an optimum Nafion content in the electrode. As the platinum loading and fabricated method depend on the optimum Nafion content. In this study, we have examined the interrelationship between platinum loading and Nafion content fabricated by decal transfer method. For electrodes with 0.25 and 0.4 mg/$cm^2$ Pt loading, best performance was obtained at 25 wt.% Nafion ionomer loading. It is also found that MEA with 0.25 mg/$cm^2$ Pt, the optimum Nafion content appears differently at low and high current density.

Improvement of Cathode Reaction of a Mediatorless Microbial Fuel Cell

  • Pham, The-Hai;Jang, Jae-Kyung;Chang, In-Seop;Kim, Byung-Hong
    • Journal of Microbiology and Biotechnology
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    • v.14 no.2
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    • pp.324-329
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    • 2004
  • Oxygen diffuses through the cation-specific membrane, reducing the coulomb yield of the fuel cell. In the present study, attempts were made to enhance current generation from the fuel cell by lowering the oxygen diffusion, including the uses of ferricyanide as a cathode mediator and of a platinum-coated graphite electrode. Ferricyanide did not act as a mediator as expected, but as an oxidant in the cathode compartment of the microbial fuel cell. The microbial fuel cell with platinum-coated graphite cathode generated a maximum current 3-4 times higher than the control fuel cell with graphite cathode, and the critical oxygen concentration of the former was 2.0 mg $1^{-1}$, whilst that of the latter was 6.6 mg $1^{-1}$. Based on these results, it was concluded that inexpensive electrodes are adequate for the construction of an economically feasible microbial fuel cell with better performance as a novel wastewater treatment process.

Removal of Uranium Ions in Lagoon Waste by Electrosorption

  • Jung, Chong-Hun;Won, Hui-Jun;Park, Wang-Kyu;Kim, Gye-Nam;Oh, Won-Zin;Hwang, Sung-Tai;Park, Jin-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.701-706
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    • 2003
  • A study on the electrosorption of U(VI) onto porous activated carbon fibers (ACFs) was performed to treat uranium-containing lagoon sludge. Effective U(Ⅵ) removal is accomplished when a negative potential is applied to the activated carbon fiber(ACF) electrode. For a feed concentration of 100mg/L, the concentration of U(VI) in the cell effluent is reduced to less than 1mg/L. The adsorbed uranium could be deserted from the ACF by passing a 1M NaCl solution through the cell and applying a positive potential onto the electrode. The regeneration of ACF from the cycling experiments was confirmed.

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A study on the electrical switching properties of oxide metal (산화금속의 전기적 스위칭 특성 연구)

  • Choi, Sung-Jai;Lee, Won-Sik
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.9 no.3
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    • pp.173-178
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    • 2009
  • We have investigated the electrical properties of oxide metal thin film device. The device has been fabricated top-top electrode structure and its transport properties are measured in order to study the resistance change. Electrical properties with linear voltage sweep on a electrodes are used to show the variation of resistance of oxide metal thin film device. Fabricated oxide metal thin film device with MIM structure is changed from a low conductive Off-state to a high conductive On-state by the external linear voltage sweep. The $Si/SiO_2/MgO$ device is switched from a high resistance state to a low resistance state by forming. Consequently, we believe oxide metal is a promising material for a next-generation nonvolatile memory and other electrical applications.

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The Potentiometric Performances of Membrane Electrodes Based on Tetracycline Antibiotics (테트라싸이크린 항생제를 담체로 이용한 막전극의 전위차 특성)

  • Baek, Jong-Gyu;Rhee, In-Sook;Paeng, Ki-Jung
    • Journal of the Korean Electrochemical Society
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    • v.9 no.3
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    • pp.132-134
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    • 2006
  • The main component governing selectivity in ion-selective electrodes and optodes is the ionophore. For this reason, a member of natural products that possess selective ion-binding properties have long been sought after. By applying this principle, the performance of tetracycline used as neutral carriers for cation selective polymeric membrane electrode was investigated. The cation ion-selective electrode based on tetracycline gave a good Nernstian response of 26.6 mV per decade for calcium ion in the activity range $1x10^{-6}M$ to $1x10^{-2}M$ with and without lipophilic additives. The optimized cation ion-selective membrane electrodes displayed very comparable potentiometric responses to various mono and di-valent cations of alkali and alkaline earth metal ions except $Mg^{2+}$.

Protective effects of citrus based mixture drinks (CBMDs) on oxidative stress and restraint stress

  • Cho, MyoungLae;Kim, Dan-Bi;Shin, Gi-Hae;Kim, Jae-Min;Seo, Yoonhee;Choe, Soo Young;Cho, Ju Hyun;Kim, Young-Cheul;Lee, Jin-Ha;Lee, Ok-Hwan
    • Food Science and Biotechnology
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    • v.27 no.6
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    • pp.1801-1809
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    • 2018
  • In the current study investigated the protective effects of citrus based mixture drinks (CBMDs) using oxidative stress in human dermal fibroblast (HDF) cells and restraint-stressed rats. The CBMDs contained citrus bioflavonoids including narirutin and hesperidin. The cell viability of HDF cells treated with $H_2O_2$ was observed at 53.9% but treated with CBMD-1 and CBMD-2 ($500{\mu}g/mL$) on $H_2O_2$ exposed HDF cells significantly increased the relative cell viability at 65.0 and 72.2%, respectively. In the treadmill test, the time spent on the electrode plate in the restraint-stressed group was analyzed 24.1 s, but restraint-stressed rats with administered CBMDs (300 mg/kg) had significantly decreased the time at 2.4 (CBMD-1) and 4.7 (CBMD-2) s, respectively. In addition, number of touches the electrode plate in restraint-stressed group was observed at 42.4 ea, but, restraint-stressed rats with administered CBMD-1 and CBMD-2 (300 mg/kg) were significantly decreased at 7.0 and 10.2 ea, respectively.