• Title/Summary/Keyword: Mg Forming

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Study on an Aluminum Modified Alloy and Manufacturing Conditions for Hot Metal Gas Forming (열간가스성형용 알루미늄 개발 합금 공정 조건에 관한 연구)

  • Lee, G.M.;Go, G.Y.;Lee, H.C.;Kim, D.O.;Lee, Y.K.;Kim, J.S.;Song, J.H.
    • Transactions of Materials Processing
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    • v.26 no.4
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    • pp.222-227
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    • 2017
  • In order to respond to environmental regulations and increased demand for fuel economy, the demand for lightweight car bodies has grown. Hydroforming of aluminum is one possible solution as it eliminates the need for additional welding to develop closed cross-sectional parts. However, the low formability of aluminum is a limitation of its application. On the other hand, the ductility of materials can be improved at higher temperatures, and hot metal gas forming has been widely applied in the production of lightweight vehicle parts. In this study, aluminum alloy for pipe extrusion was developed by controlling the Mg:Cr:Mn ratio based on AA5083. Mechanical properties of the developed material were examined by tensile test and were applied to a forming simulation. Cold forming simulation for preforming and non-isothermal hot forming simulation for hot metal gas forming were carried out to validate process conditions. A prototype of the sidemember was manufactured under the given process condition. Finally, thickness distribution was compared with finite element analysis results.

Reaction Processes of the Formation of Mg-Al Spinel by a Thermal Decomposition of a Mixed Sulfate Hydrate (복합 황산염 수화물의 열분해에 의한 Mg-Al 스피넬의 생성반응)

  • 박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.71-75
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    • 1986
  • The forming reaction processes of magnesium aluminate spinel by a thermal decomposition of sulfate hydrate were studied with DTA, TG. SEM and X-ray powder diffraction methods. The hydrous salt composed of the mixture of the two compounds of $MgSO_4$ $6H_2O$ and ${AL_2}({SO_4})_17H_2O_3$ in which both sulfates were crystalline. On heating the hydrous slat the crystalline magnesium and aluminum sulfate anhydride to amorphous alumina magnesium sulfate anhydride decomposed to amorphous magnesia and these amorphous oxides reacted completely each other to form a spinel at $1000^{\circ}C$ The apparent activation energy of forming reaction of spinel was 36.5 kcal/mole($900^{\circ}C$~$1000^{\circ}C$) The crystallite size of spinel obtained at $1000^{\circ}C$ after 1 h was 380$\AA$.

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Effect of Chlorination on Disinfection Byproducts Production and Release of Microcystins from Bloom-forming Algae (녹조현상 원인조류들의 염소처리에 의한 소독부산물 생성 및 microcystins 유출)

  • Park, Hae-Kyung;Seo, Yong-Chan;Cho, Il-Hyung;Park, Byung-Hwang
    • Journal of Korean Society on Water Environment
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    • v.22 no.3
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    • pp.513-520
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    • 2006
  • The effect of chlorination on disinfection byproducts (DBPs) production from bloom-forming freshwater algae including 7 strains of cyanobacteria and 6 strains of diatoms was investigated. The release and degradation of hepatotoxin (microcystins) by the chlorination on Microcystis under differential condition of the chlorination time and dose were also investigated. The disinfection byproducts formation potentials (DBPFP) of cyanobacterial species and diatoms were ranged from 0.017 to $0.070{\mu}mol\;DBPs/mg$ C and from 0.129 to $0.708{\mu}mol\;DBPs/mg$ C respectively. Among three major groups of DBPs, haloacetonitrils (HANs) was major product in most test strains except Aphanizomenon sp. and Oscillatoria sp. Haloacetic acids (HAAs) was less than 5 % of total DBPs. Chloroform and dichloroacetonitril (DCAN) were dominant compounds in trihalomethanes (THMs) and HANs respectively. After 4 hours chlorination of toxic Microcystis aeruginosa under the dose range of 0.5 to $10mg\;Cl_2/L$, the concentration of intracellular microcystins decreased, but dissolved dissolved microcystins concentration increased with the treatment of more than $3mg\;Cl_2/L$. However the total amount of microcystins was almost constant even at $10mg\;Cl_2/L$ of chlorination. To conclude, our results indicate that the chlorination causes algal cell lysis and release of intracellular microcystins in the intact form to surrounding waters.

Effects of Nickel and Iron Oxide Addition by Milling under Hydrogen on the Hydrogen-Storage Characteristics of Mg-Based Alloys

  • Song, Myoung Youp;Baek, Sung Hwan;Park, Hye Ryoung;Mumm, Daniel R.
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.64-70
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    • 2012
  • Samples of pure Mg, 76.5 wt%Mg-23.5 wt%Ni, and 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ were prepared by reactive mechanical grinding and their hydriding and dehydriding properties were then investigated. The reactive mechanical grinding of Mg with Ni is considered to facilitate nucleation and to shorten diffusion distances of hydrogen atoms. After hydriding-dehydriding cycling, the 76.5 wt%Mg-23.5 wt%Ni and 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ samples contained $Mg_2Ni$ phase. In addition to the effects of the creation of defects and the decrease in particle size, the addition of Ni increases the hydriding and dehydriding rates by the formation of $Mg_2Ni$. Expansion and contraction of the hydride-forming materials (Mg and $Mg_2Ni$) with the hydriding and dehydriding reactions are also considered to increase the hydriding and dehydriding rates of the mixture by forming defects and cracks leading to the fragmentation of particles. The reactive mechanical grinding of Mg-Ni alloy with $Fe_2O_3$ is considered to decrease the particle size.

Immunopotentiating Effect of Polysaccharides Extracted from Agrocybe cylindracea (Agrocybe cylindracea로부터 추출한 다당류의 면역증강활성)

  • 김선희;이항우;배만종;이재성
    • Korean Journal of Microbiology
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    • v.36 no.1
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    • pp.64-68
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    • 2000
  • The immunopotentiating effects of the polysaccharides, both intracellular and extracellular, was examined by an animal feeding test. The results are summarized as follows. The oral administration of intracellular and extracellular polysaccharides of Agrocybe cylindracea for 10 days resulted in the enhanced phagocytic activity of peritoneal exudate cells(PEC), spleen cells(SC), and monolymphocytes(ML). In the experiment of PFC(plaque forming cell) and RFC(rosette forming cell), the results showed that all the polysaccharide fractions enhanced the immune related cells. The EAC II group(the extracellular polysaccharide of Agrocybe cylindracea 10 mg/0.2 ml distilled water/day/ mouse) increased the PFC and RFC by 46~50% and 43%, respectively, compared to the control group. On the other hand, the IAC I group(the intracellular polysaccharide of Agrocybe cylindracea 1 mg/0.2 ml distilled water/day/mouse) increased the PFC and RFC by 49~70% and 91%, respectively. In terms of the mitogenic activity, the extracellular polysaccharides of A. cylindracea showed a higher activity than the intracellular polysaccharides.

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Computer Simulation for Die Filling Behavior of Semi-Solid Slurry of Mg Alloy

  • Lee, Dock-Young;Moon, Jung-Hwa;Seok, Hyun-Kwang;Kim, Sung-Bin;Kim, Ki-Bae
    • Journal of Korea Foundry Society
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    • v.27 no.1
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    • pp.31-35
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    • 2007
  • In order to develop the semi-solid forming technology for magnesium alloy the rheological and thixotropic behavior of Mg alloy slurry with varying shear rates and cooling rates was investigated and simulated with considering the viscosity based on microstructures and processing variables. The viscosity of slurry of Mg alloy (AZ91D) in semi-solid region was exponentially increased with a solid fraction, and was decreased with increasing a shear rate. In order to analyze precisely the rheological behavior, the ANYCAST program modified with the Carreau model and the different heat transfer coefficient between the cast and mold was used to simulate the flow behavior of Mg semi-solid slurry during the injection into a casting mold in a high pressure diecasting machine. The simulated rheological behavior of Mg alloy slurry was matched well with the experimental results.

Analysis of Hot Compression Process of Aluminum 6082 Billet using Nonlinear Heat Transfer Coefficient (비선형 열전달 계수를 사용한 알루미늄 6082 빌렛의 열간 압축 공정 해석)

  • Jeon, H.W.;Suh, C.H.;Kwon, T.H.;Park, C.D.;Jeon, J.H.;Choi, H.Y.;Kang, G.P.
    • Transactions of Materials Processing
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    • v.28 no.1
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    • pp.5-14
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    • 2019
  • In order to reduce the weight of automobile parts, automobile parts using aluminum alloy are being developed. Aluminum alloy for automobile parts is mainly made of Al6xxx (Al-Mg-Si) type alloy, which is excellent in hot forming property, and it can increase mechanical properties by the use of heat treatment. In this study, hot forming was performed using Al6082. Before the hot forming, the forming analysis was performed using the DEFORM-3D finite element analysis program in this case. For the forming analysis, the heat transfer coefficient was derived from the experiment, and the forming analysis was performed by applying it. At the forging analysis, the temperature of Al6082 material was set to 813K and that of the mold was set to room temperature. After the forging analysis, the experiment was performed, and the forging analysis and the experimental results were compared.

Fabrication and Characterization of Thermal Battery using Porous MgO Separator Infiltrated with Li based Molten Salts

  • Kim, Kyungho;Lee, Sungmin;Im, Chae-Nam;Kang, Seung-Ho;Cheong, Hae-Won;Han, Yoonsoo
    • Journal of Powder Materials
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    • v.24 no.5
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    • pp.364-369
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    • 2017
  • Ceramic powder, such as MgO, is added as a binder to prepare the green compacts of molten salts of an electrolyte for a thermal battery. Despite the addition of a binder, when the thickness of the electrolyte decreases to improve the battery performance, the problem with the unintentional short circuit between the anode and cathode still remains. To improve the current powder molding method, a new type of electrolyte separator with porous MgO preforms is prepared and characteristics of the thermal battery are evaluated. A Spherical PMMA polymer powder is added as a pore-forming agent in the MgO powder, and an organic binder is used to prepare slurry appropriate for tape casting. A porous MgO preform with $300{\mu}m$ thickness is prepared through a binder burnout and sintering process. The particle size of the starting MgO powder has an effect, not on the porosity of the porous MgO preform, but on the battery characteristics. The porosity of the porous MgO preforms is controlled from 60 to 75% using a pore-forming agent. The batteries prepared using various porosities of preforms show a performance equal to or higher than that of the pellet-shaped battery prepared by the conventional powder molding method.

Effect of the Casting Conditions on the Globulization of Primary Al of $AlSi_7Mg$ Alloy (($AlSi_7Mg$알루미늄 합금의 초정 구형화에 대한 주조조건의 영향)

  • Han, Yo-Sub;Lee, Ho-In;Lee, Jae-Chul
    • Journal of Korea Foundry Society
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    • v.23 no.1
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    • pp.40-46
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    • 2003
  • Semisolid forming requires alloys with non-dendritic microstructure of the thixotropy. Recently, low pouring temperture method without stirring, i.e. liquidus casting has been found out new fabrication method of the semisolid metals. Effects of melt superheat and mold conditions on the globulization of primary Al of $AlSi_7Mg$ alloy were investigated in gravity casting process without stirring. The microstructures of primary Al as function of melt superheat and mold temperature show globular, rosette and dendritic shapes. The conditions for globular microstructure of primary Al were low melt superheat < 35 K and low mold temperature < 500 K. The thermal conditions for globular microstructure of primary Al were undercooled melt at early solidification stages and slow cooling < 0.6 K/s. It was found that the initial microstructure was maintained throughout the solidification and the globules of primary Al can be obtained by high nucleation of fine and spherical nuclei due to enhanced undercooling of melt.

A Study on the Forming of Solid Solution in CaO.MgO.$2SiO_2-Al_2O_3$ System (CaO MgO.$2SiO_2-Al_2O_3$ 계의 고용체 생성에 관한 연구)

  • 안영필;김복희
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.25-30
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    • 1983
  • This experiment was studied in the system of (1-x) CaO MgO $2SiO-Al_2O_3$ to investigate forming of solid solution. The technique empolyed was the well known water-quenching method. Differential thermal analysis of the each glass water quenched indicated that under 30 mole% $Al_2O_3$ was lowered with increasing of the amount of $Al_2O_3$ It was supposed by X-ray diffraction patterns of each specimen sintered at various temperature that only solid solution was formed under the 30mole % $Al_2O_3$ compositions solid solution and anorthite were formed at the 20mole% $Al_2O_3$ composition anorthite solid solution and spinel$(MgAl_2O_4)$ were formed over the 40mole% $Al_2O_3$ compositions. The maximum density and thermal expanison coefficient was 2.89g/cm 7.74x106./C$^{\circ}$ respectively in the composi-tion of 10 mole% $Al_2O_3$ . All the specimens showed linear thermal expansion behavior. Microhardness was as high as 850kg/nm2 in the composition of 5, 10, 20 mole % $Al_2O_3$ and dielectric constant was 7.3-6.9.

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