• Title/Summary/Keyword: Mg2+

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New and Regenerated Production Based on Nitrogen in the southern Part of the Yellow Sea in Late April, 1993. (1993년 4월말 황해 남부 해역의 질소 신생산(新生産)과 재생산(再生産))

  • YANG, SUNG RYULL;SHIN, KYOUNG SOON;YANG, DONG-BEOM
    • 한국해양학회지
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    • v.29 no.3
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    • pp.258-268
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    • 1994
  • Nitrogenous new production and regenerated production were measured in the southern part of the Yellow Sea (Hwanghae) using a stable isotope /SUP 15/N nitrate and ammonia between April 25∼30, 1993. Nitrogen production varied between 155 and 688 mg N m/SUP -2/ d/SUP -1/, which belongs to meso to eutrophic area values. This is equivalent to 881∼3909 mg C m/SUP -2/ d/SUP -1/, assuming the Redfield ratio for C:N of 5.7:1 (by weight). the f0ratio which is the fraction of new production from primary production, varied between 0.12 and 0.26, indicating that 74 to 88% of primary production was supported by the regeneration of nutrients within the euphoric zone. This low f0ratio is the characteristics of the oligo- to mesotrophic area. Contrary to the expected, the ambient nutrient concentration was not an important factor for controlling productivity in this area during the study period. The difference in productivity among stations was mainly due to the variations in phytoplankton biomass in different water masses.

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Persistence Study of Thiamethoxam and Its Metabolite in Kiwifruit for Establishment of Import Tolerance

  • Il Kyu Cho;Gyeong Hwan Lee;Woo Young Cho;Yun-Su Jeong;Danbi Kim;Kil Yong Kim;Gi-Woo Hyoung;Chul Hong Kim
    • Korean Journal of Environmental Agriculture
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    • v.41 no.4
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    • pp.355-364
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    • 2022
  • BACKGROUND: Pre-harvest interval and decline pattern of thiamethoxam were determined in kiwifruit using liquid chromatography-tandem mass spectrometry (LCMS/MS). The study was carried out to propose import tolerance using OECD maximum residue limit (MRL) calculator for the export promotion of kiwifruit to Taiwan. METHODS AND RESULTS: The thiamethoxam residue in kiwifruit was determined by using the LC-TriQ-MS/MS with the analytical process to set up the import tolerance under greenhouse conditions for Taiwan. Excellent linearity was observed for all of the analytes with a determination coefficient (R2)≥0.99. The limit of quantification was determined to be 0.01 mg/kg for both thiamethoxam and clothianidin in kiwifruit. Linearity was determined from the co-efficient of determinants (R2) obtained from the seven-point calibration curve. The standard calibration curve showed as follows; 1) Site 1 (Gimje): y = 944,406X + 1,583 (R2=0.9995), 2) Site 2 (Goheung): y = 1,356,205X + 934 (R2=0.9983), and 3) Site 3 (Jangheung): y = 1,239,937X - 3,090 (R2=0.9908). The residue of thiamethoxam in the kiwifruit for three decline trials showed the range of 0.35 to 0.56 mg/kg in site 1 (Gimje), 0.24 to 0.55 mg/kg in site 2 (Goheung), and 0.28 to 0.42 mg/kg in site 3 (Jangheung), respectively. However, clothianidin was not detected in all of the treatments. The maximum residual amounts (decline) in the samples, sprayed according to the safe-use standard for thiamethoxam 10% WG in kiwifruit (30 days before harvest, 3 sprays every 7 days) were 0.56 mg/kg in site 1, 0.55 mg/kg in site 2, and 0.42 mg/kg in site 3, respectively. CONCLUSION(S): The import tolerance (IT) of thiamethoxam for kiwifruit may be proposed to be 0.9 mg/kg by using the OECD MRL calculator.

Desalinization Effect of Pennisetum Alopecuroides and Characteristics of Leachate Depending on Calcium Chloride (CaCl2) Concentration

  • Yang, Ji;Yoon, Yong-Han;Ju, Jin-Hee
    • Journal of People, Plants, and Environment
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    • v.23 no.4
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    • pp.445-453
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    • 2020
  • Background and objective: Calcium chloride (CaCl2) and sodium chloride (NaCl) are commonly used as a deicing agent in South Korea and penetrate the soil on the roadside, causing damage to plants. This study was conducted to investigate the salinity reduction effect of Pennisetum alopecuroides and the chemical characteristics of soil leachate. Methods: The plants were treated with five different concentrations of CaCl2 (0, 1, 2, 5, and 10g·L-1) and were grouped into the Cont., C1, C2, C5, and C10 groups. CaCl2 of 200 m·L-1 was sprayed to each plant once every two weeks. The growth of P. alopecuroides (plant height, leaf length, leaf width and the number of leaves) was measured. The level of EC and pH, and exchangeable cations (K+, Ca2+, Na+, and Mg2+) in the leachate of soil was monitored. Results: The pH of soil leachate decreased as the CaCl2 concentration increased, and the EC increased significantly. The content of K+ did not change significantly until the concentration of CaCl2 reached 5 g·L-1, but the content of Ca2+, Na+, and Mg2+ significantly increased. The plant height, leaf length, and leaf width of P. alopecuroides showed the highest value in CaCl2 1 g·L-1 followed by CaCl2 2 g·L-1 and the control group. Root fresh weight was the highest in CaCl2 2 g·L-1. On the other hand, there was no change in the shoot fresh weight, dry weight and root dry weight, and P. alopecuroides growth inhibition at the concentration of 5 g·L-1 or higher in the plant height and leaf length. Conclusion: P. alopecuroides is relatively highly salt-tolerant and can improve the salt damaged soil by lowering the content of the salt-based exchangeable K+ ions.

Fermentation Efficiency and Effect on Morphological Change of Nitrogen and Phosphorous with the Litter Types of Cowshed (우사의 깔짚 종류에 따른 발효 효율과 질소와 인의 형태 변화에 미치는 영향)

  • Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.66 no.2
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    • pp.86-91
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    • 2022
  • The manure made of chaff and sawdust as litter was collected separately at a cowshed of a livestock farm in Andondg city. The fermentation efficiency of excreta is greatly influenced by the type and characteristics of litter and a factor to be considered for reducing N and P, the causes of eutrophication. Changes in weight with temperature and constituents of sample were examined using TG-DTA and XRF, respectively. NO2-, NO3-, and PO43- ions and NH4+, T-P and T-N eluted from manure by rain were analyzed using ion chromatograph and UV/Vis spectrometry, respectively. As a result, the fermentation efficiency of excreta in sawdust manure is three times higher as compared with chaff manure. The higher the fermentation efficiency, ammonia nitrogen was highly de-nitrogenated and organic phosphorous were also changed into phosphorous ions. Furthermore, phosphorous ions can be removed by transforming insoluble salts such as calcium phosphate (CaHPO4·3H2O) and struvite (NH4MgPO4·6H2O) with addition of Ca and Mg.

Effects of Nutrient Solution Strength on Growth and Nutrient Element Concentrations of Leaf Lettuce by Hydroponic Culture under Artificial Light (인공광을 이용한 수경재배에서 배양액 농도가 상추의 생장과 배양액 양분 농도에 미치는 영향)

  • Kim, D.E.;Lee, W.Y.;Heo, J.W.;Lee, G.I.;Kang, D.H.;Woo, Y.H.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.19 no.1
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    • pp.5-14
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    • 2017
  • This study was conducted to investigate the effects of nutrient solution strength on growth and nutrient element concentrations in leaf lettuce (Lactuca sativa L. cv. 'Dduksum') by hydroponic culture under fluorescent lamp and LED. Leaf lettuce were grown in closed hydroponic cultivation systems supplied with 1/2, 1 and 2 strength of nutrient solution recommended by horticultural experiment station in Japan. The growth of 'Dduksum' was highest in the 2 strength of standard nutrient solution. The amount of nutrient element in the recycled nutrient solution was higher at 2, 1 and 1/2 strength of nutrient solution. The concentration of NO3-N, Ca2+, Mg2+ in the recycled nutrient solutions increased in 1 and 2 strength of nutrient solution but that of NH4-N decreased gradually in 1/2 and 1 strength of nutrient solution. The concentration of K, Ca, Mg in leaf lettuce was maintained in the normal range, whereas the concentration of phosphorous was 1.3 to 1.6%, which was higher than proper range. As the concentration of NH4-N decreases gradually in all the treatments, it is necessary to raise the rate of NH4-N or add it.

A study on applying random forest and gradient boosting algorithm for Chl-a prediction of Daecheong lake (대청호 Chl-a 예측을 위한 random forest와 gradient boosting 알고리즘 적용 연구)

  • Lee, Sang-Min;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.507-516
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    • 2021
  • In this study, the machine learning which has been widely used in prediction algorithms recently was used. the research point was the CD(chudong) point which was a representative point of Daecheong Lake. Chlorophyll-a(Chl-a) concentration was used as a target variable for algae prediction. to predict the Chl-a concentration, a data set of water quality and quantity factors was consisted. we performed algorithms about random forest and gradient boosting with Python. to perform the algorithms, at first the correlation analysis between Chl-a and water quality and quantity data was studied. we extracted ten factors of high importance for water quality and quantity data. as a result of the algorithm performance index, the gradient boosting showed that RMSE was 2.72 mg/m3 and MSE was 7.40 mg/m3 and R2 was 0.66. as a result of the residual analysis, the analysis result of gradient boosting was excellent. as a result of the algorithm execution, the gradient boosting algorithm was excellent. the gradient boosting algorithm was also excellent with 2.44 mg/m3 of RMSE in the machine learning hyperparameter adjustment result.

Monitoring of Radioactivity and Heavy Metal Contamination of Dried Processed Fishery Products (건조 수산가공식품의 방사능 및 중금속 오염도 조사)

  • Lee, Ji-Yeon;Jeong, Jin-A;Jeon, Jong-Sup;Lee, Seong-Bong;Kwon, Hye-Jung;Kim, Jeong-Eun;Lee, Byoung-Hoon;Mo, A-Ra;Choi, Ok-Kyung
    • Journal of Food Hygiene and Safety
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    • v.36 no.3
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    • pp.248-256
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    • 2021
  • A total of 120 samples corresponding to 12 categories of dried processed fishery products distributed in Gyeonggi-do were examined for radioactivity contamination (131I, 134Cs, 137Cs) and heavy metals (lead, cadmium, arsenic, and mercury). One natural radioactive material, 40K, was detected in all products, while the artificial radioactive materials 131I, 134Cs and 137Cs were not detected at above MDA (minimum detectable activity) values. The detection ranges of heavy metals converted by biological basis were found as follows: Pb (N.D.-0.332 mg/kg), Cd (N.D.-2.941 mg/kg), As (0.371-15.007 mg/kg), Hg (0.0005-0.0621 mg/kg). Heavy metals were detected within standard levels when there was an acceptable standard, but the arsenic content was high in most products, although none of the products had a permitted level of arsenic. In the case of dried processed fishery products, there are products that are consumed by restoring moisture to its original state, but there are also many products that are consumed directly in the dry state, so it will be necessary to set permitted levels for heavy metals considering this situation in the future. In addition, Japan has decided to release contaminated water from the Fukushima nuclear power plant into the ocean, so there is high public concern about radioactivity contamination of food, including fishery products. Therefore, continuous monitoring of various food items will be necessary to ease consumers' anxiety.

Purification and Biochemical Characterization of a Serine Protease with Fibrinolytic Activity from Maggots of Mimela splendems

  • Kwon Heun Young;Kim Tae Un
    • Biomedical Science Letters
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    • v.10 no.4
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    • pp.347-351
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    • 2004
  • Maggot fibrolase (MsMg-1) was purified from the maggots of Mimela splendems using ammonium sulfate fractionation, DEAE Affi-gel affinity chromatography. This protease had a molecular weight of 85 kDa as determined by SDS-polyacrylarnide gel electrophoresis under reducing conditions. It showed strong proteolytic and fibrinolytic activities. The purified enzyme was strongly inhibited by phenylmethanesulfonyl fluoride, Mn/sup 2+/, and Zn/sup 2+/ but it was not by EDTA, EGT, Mg/sup 2+/, Ca/sup 2+/, and Li/sup 2+/ ions. In these experimental results, we have speculated that MsMg-1 is a serine protease with a strong fibrinolytic activity.

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Effect of Napa Cabbage (Brassica campestris var. Pekinensis) Cropping Systems on Soil Physiochemical Properties, Yield and Quality in Alpine Area of South Korea (한국 고랭지 배추 작부체계에 따른 토양, 배추 생산성 및 성분 특성 비교)

  • Bak, Gye Ryeong;Lee, Jeong Tae
    • Korean Journal of Plant Resources
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    • v.34 no.4
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    • pp.249-256
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    • 2021
  • Napa cabbage (Brassica campestris var. Pekinensis) is the main material of Kimchi so that important crop in South Korea. There are two typical napa cabbage cropping systems in the alpine area. One is cultivating napa cabbage annually while another is cultivating napa cabbage and potato biennially. In this research, we evaluated soil physiochemical properties, yield, and mineral contents of napa cabbage depending on two cropping systems. As a result, organic matter, available P2O5, exchangeable K+ was decreased after six-years of cultivation on both cropping systems. However, soil pH was only decreased in a continuous napa cabbage cropping system. Soil porosity is also decreased in both cropping systems on topsoil while is increased in rotation with potato on subsoil. The rotation system showed a significantly higher yield with a higher value of leaf and napa cabbage size than the continuous cropping system. Total nitrogen, Ca2+, and Ma2+ were increased and total carbon and phosphate decreased in both cropping systems after six-years. Especially, total nitrogen and Mg2+ were significantly higher in the continuous system while Ca2+ was higher in the rotation system. In conclusion, the cropping system influences soil physiochemical properties and plant production in an agricultural field.

Optical Properties of MgMoO4:Dy3+,Eu3+ Phosphors Prepared with Different Eu3+ Molar Ratios (Eu3+ 이온의 몰 비 변화에 따른 MgMoO4:Dy3+,Eu3+ 형광체의 광학 특성)

  • Kim, Jung Dae;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.3
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    • pp.186-191
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    • 2016
  • The effects of $Eu^{3+}$ doping on the structural, morphological, and optical properties of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors prepared by solid-state reaction technique were investigated. XRD patterns exhibited that all the synthesized phosphors showed a monoclinic system with a dominant (220) diffraction peak, irrespective of the content of $Eu^{3+}$ ions. The surface morphology of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors was studied using scanning electron microscopy and the grains showed a tendency to agglomerate as the content of $Eu^{3+}$ ions increased. The excitation spectra of the phosphor powders were composed of a strong charge transfer band centered at 294 nm in the range of 230~340 nm and two intense peaks at 354 and 389 nm, respectively, arising from the $^6H_{15/2}{\rightarrow}^6P_{7/2}$ and $^6H_{15/2}{\rightarrow}^4M_{21/2}$ transitions of $Dy^{3+}$ ions. The emission spectra of the $Mg_{0.85}MoO_4$:10 mol% $Dy^{3+}$ phosphors without incorporating $Eu^{3+}$ ions revealed a strong yellow band centered at 573 nm resulting from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$. As the content of $Eu^{3+}$ was increased, the intensity of the yellow emission was gradually decreased, while that of red emission band located at 614 nm began to appear, approached a maximum value at 10 mol%, and then decreased at 15 mol% of $Eu^{3+}$. These results indicated that white light emission could be achieved by controlling the contents of the $Dy^{3+}$ and $Eu^{3+}$ ions incorporated into the $MgMoO_4$ host crystal.