• Title/Summary/Keyword: Methane-air mixture

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Combustion Characteristics Analysis of Methane-Air Homogeneous Mixture in a Constant Volume Combustion Chamber (정적연소기에서의 메탄-공기 균질혼합기의 연소특성 분석)

  • Lee, Suk-Young;Kim, Sang-Jin;Jeon, Chung-Hwan
    • Journal of the Korean Society of Combustion
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    • v.13 no.3
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    • pp.9-16
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    • 2008
  • In this study, a cylindrical constant volume combustion chamber is used to investigate the flow and combustion characteristics of methane-air homogeneous mixture under various initial charge pressure, excess air ratios and ignition times. The flame and burning speed, mean gas speed are calculated by numerical analysis to analyze the combustion characteristics. It is found that the mean gas velocity during combustion has the maximum value around 300 ms and then decreased gradually on the condition of 10000 ms, and that the combustion duration is shorten and flame speed and burning velocity have the highest value under the conditions of an excess air ratio 1.1, an initial charge pressure of 0.2 MPa and an ignition time of 300 ms in the present study. And, the initial pressure and burning speed are in inverse proportion, so that it is in agreement with Strehlow who presented that the initial pressure and burning speed are in inverse proportion when the burning speed is under 50cm/s.

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COMBUSTION CHARACTERISTICS OF HOMOGENEOUS CHARGED METHANE-AIR MIXTURE IN A CONSTANT VOLUME COMBUSTION CHAMBER

  • CHOI S. H.;CHO S. W.;JEONG D. S.;JEON C. H.;CHANG Y. J.
    • International Journal of Automotive Technology
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    • v.6 no.4
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    • pp.323-332
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    • 2005
  • A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of a homogeneous charged methane-air mixture under various overall charge pressures, excess air ratios and ignition times. The flow characteristics, including the mean velocity and turbulence intensity, were analyzed with a hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer, a flame propagation image acquired by ICCD camera and exhaust emissions measured by 2-valve gas chromatography were used to investigate effects of initial pressures, excess air ratios and ignition times on the combustion characteristics. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to a near-zero value after 3000 ms and that the combustion duration was shorten and the flame speed and laminar burning velocity had the highest value under the condition of an excess air ratio of 1.1, an overall charge pressure of 0.15 MPa and an ignition time of 300 ms in the present study. The $CO_2$ concentration was proportional to the ignition time and overall charge pressure, the $CO_2$ concentration was proportional to the excess air ratio, and the UHC concentration was inversely proportional to the ignition time and overall charge pressure.

Characteristics of Combustion Radical in CNG Direct Injection Vessel (CNG 직접분사식 연소기에서의 연소 라디칼 특성)

  • 최승환;조승완;이석영;정동수;전충환;장영준
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.5
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    • pp.58-65
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    • 2004
  • A cylindrical constant volume combustion chamber was used to investigate the combustion characteristics of stratified methane-air mixture under several initial charge conditions in the author's previous reports. The results showed that the improvement of thermal efficiency and reduction of heat loss was realized simultaneously by using 2-stage injection method. This paper deals with the reason why the stratified combustion has showed better combustion rate through the measurement and analysis of chemiluminescence of C $H^{*}$ and $C_{2}$$^{*}$ radicals. An optic fiber bundle is used to measure the local emission of C $H^{*}$ and $C_{2}$$^{*}$ radicals to map the relationship between the excess air ratio and local radical intensity ratio in the combustion vessel at 5 mm apart form the geometric center. The results show that there exist a relationship between the intensity ratio and the air-fuel ratio. It is revealed that the improvement of combustion rate in a lean-stratified mixture is realized through the 2-stage injection method. method.

Numerical Analysis on the Triple Flame Structure with Different Kinds of Fuel (3중화염의 구조에 미치는 연료종류에 관한 수치해석)

  • 최낙정
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.1
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    • pp.88-95
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    • 1999
  • This study investigates the effects of different kind fuels on the flame structure by using the numerical simulation in triple flame made by a co-flowing fuels-air stream based on the elementary chemical reaction mechanism. Methane and Hydrogen were used as fuel for this study. In order to interpret the result of the study on numerical simulation Skeletal chemistry is employe as the elementary chemical reaction mechanism for methane Gutheil's as an offset ele-mentary chemical reaction mechanism for hydrogen. The result of this study is as follows. In com-parison between the apparent burning velocity change of triple flame and the one-dimensional pre-mixed flame hydrogen fuel flame is higher than methane fuel flame. The flame thrusts out for-ward in the down stream of the boundary between air-fuel mixture and air stream and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated.

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Feasibility of a methane reduced chemical kinetics mechanism in laminar flame velocity of hydrogen enriched methane flames simulations

  • Ennetta, Ridha;Yahya, Ali;Said, Rachid
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.213-221
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    • 2016
  • The main purpose of this work is to test the validation of use of a four step reaction mechanism to simulate the laminar speed of hydrogen enriched methane flame. The laminar velocities of hydrogen-methane-air mixtures are very important in designing and predicting the progress of combustion and performance of combustion systems where hydrogen is used as fuel. In this work, laminar flame velocities of different composition of hydrogen-methane-air mixtures (from 0% to 40% hydrogen) have been calculated for variable equivalence ratios (from 0.5 to 1.5) using the flame propagation module (FSC) of the chemical kinetics software Chemkin 4.02. Our results were tested against an extended database of laminar flame speed measurements from the literature and good agreements were obtained especially for fuel lean and stoichiometric mixtures for the whole range of hydrogen blends. However, in the case of fuel rich mixtures, a slight overprediction (about 10%) is observed. Note that this overprediction decreases significantly with increasing hydrogen content. This research demonstrates that reduced chemical kinetics mechanisms can well reproduce the laminar burning velocity of methane-hydrogen-air mixtures at lean and stoichiometric mixture flame for hydrogen content in the fuel up to 40%. The use of such reduced mechanisms in complex combustion device can reduce the available computational resources and cost because the number of species is reduced.

CO, $CO_2$ and NOx Emission Characteristics of Methane-Air Premixed Flame in Constant Volume Combustion Chamber (정적연소실에서 메탄-공기 예혼합화염의 CO, $CO_2$ 및 NOx 배출 특성)

  • 김태권;김성훈;장준영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.19-26
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    • 2000
  • This paper presents the effects of initial pressure of mixture on CO, $CO_2$ and NOx emissions in constant volume combustion chamber. The CO, $CO_2,O_2,N_2$ concentrations in the chamber are determined by thermal conductivity detection (Gas-chromatograph) wile the NOx concentration is measured by chemiluminescent detection (NOx Analyser). Methane-air mixture is used as premixed fuel and the measurements are taken with equivalence ratios($\phi$) varing from 0.6 to 1.3, and initial pressures of methane-air mixture varing from 0.1MPa to 0.8MPa in constant volume combustion chamber. The NOx concentration steadily increases with increasing equivalence ratio, peaks in lean flame ($\phi$=0.85~0.9), and then rapidly decreases. However, as the initial pressure of mixture is increased, the equivalence ratio corresponding to the point of peak [NOx] shifts towards leaner conditions. This is caused by a similar shift in the peak [CH], which is caused by the variation with pressure and equivalence ratio of the rate of CH production from $CH_2$ and OH. The maximum combustion pressure peaks at $\phi$ =1.05 and the $CO_2$ concentration peaks at $\phi$=0.95~1.0 while the CO concentration rises sharply at the condition of fuel-rich mixtures. This is caused by complete combustion at $\phi$=0.95.

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Numerical Study on Methane/Air Turbulent Jet Diffusion Flames Near-Extinction Using Conditional Moment Closure Model (CMC model에 의한 near-extinction methane/air turbulent jet diffusion flame의 수치적 모사)

  • Kang, Seung-Tak;Kim, Seung-Hyun;Huh, Kang-Yul
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.11-17
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    • 2002
  • The first-order conditional moment closure (CMC) model is applied to $CH_4$/Air turbulent jet diffusion flames(Sandia Flame D, E and F). The flow and mixing fields are calculated by fast chemistry assumption and a beta function pdf for mixture fraction. Reacting scalar fields are calculated by elliptic CMC formulation. The results for Flame D show reasonable agreement with the measured conditional mean temperature and mass fractions of major species, although with discrepancy on the fuel rich side. The discrepancy tends to increase as the level of local extinction increases. Second-order CMC may be needed for better prediction of these near-extinction flames.

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Combustion Characteristics of Methane-Air Mixture in a Constant Volume Combustion Chamber(3) : Exhaust Emission (정적연소기에서의 메탄-공기 혼합기의 연소특성(3) : 배기배출물)

  • 최승환;전충환;장영준
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.1-8
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    • 2004
  • A cylindrical constant volume combustion chamber was used to investigate the exhaust emission characteristics of homogeneous charge, stratified pattern and inhomogeneous charge under various conditions using gas chromatography. In the case of homogeneous charge condition, the $CO_2$ concentration is proportional to excess air ratio and overall charge pressure, the $CO_2$ concentration is proportional to excess air ratio and the UHC concentration is inversely proportional to ignition time and overall charge pressure. In the case of stratified pattern, the RI(rich injection) condition shows better exhaust emission characteristics, especially $CO_2$, than that of HI (homogeneous injection) or LI (lean injection) conditions. In inhomogeneous charge conditions, when initial charge pressure is increased, $CO_2$ and UHC concentration is reduced but $O_2$ concentration is increased. And when the excess air ratio of initial charge mixture is 3.0, UHC and $CO_2$concentration show lowest values.

Combustion Characteristics of Methane-Hydrogen-Air Premixture(II) (메탄-수소-공기 예혼합기의 연소특성(II))

  • 김봉석;이영재
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.3
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    • pp.156-167
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    • 1996
  • The present work is a continuation of our previous study to investigate the effects of parameters such as equivalence ratio, hydrogen supplement rate and initial pressure on combustion characteristics in a disk-shaped constant volume combustion chamber. The main results obtained from the study can be summarized as follows. The flames in near stoichiometric mixture of methane-air are propagated with a spherical shape, but in excess rich or lean mixtures are propagated with a elliptical shape. And, they are changed to an unstable elliptical shape flame with very regular cells by increasing the hydrogen supplement rate. Also, flame is sluggishly propagated at increased initial pressure in combustion chamber. Volume fraction of burned gas and flame radius as the combustion characteristics are increased by increasing the hydrogen supplement rate, especially at the combustion middle period, but then are slowly increased by increasing the initial pressure.

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Limit of equivalence ratio on mixing enhancement in rich flames. (과농 예혼합화염의 혼합촉진에 대한 당량비 한계)

  • Kim, Jin-Kook;Shin, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.1 no.1
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    • pp.51-55
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    • 1996
  • An experimental investigation has been made with the objective of studying the limits of equivalence ratio on mixing enhancement in a tone excited jet flame. The jet is pulsed by means of a loudspeaker-driven cavity and rich flames(${\phi}>1.5$) are used. The excitation frequency is chosen for the resonant frequency identified as a pipe resonance due to acoustic excitation. Methane, propane and butane are used to examine the effect of mixture property on the limit of equivalence ratio. Mixing is always enhanced in a methane/air flame as the excitation intensity increases. Constant lower limits of equivalence ratio for mixing enhancement are present in cases of propane/air and butane/air flames irrespective of mean mixture velocities. The equivalence ratio limits are also found to be related to the flame instability ; the lower Le, the higher the limit of equivalence ratio. Under the equivalence ratio limits, cellular flames are generated as the excitation intensity increases. The amplitude of oscillating velocity for generating a cellular flame in the equivalence ratio limit is proportional to a mean mixture velocity irrespective of fuels.

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