• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2145-2149
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• 2018

The formation of methanol directly from methane and steam was observed over Cu ion-exchanged mordenite. Furthermore, the continuous production of methanol was achieved by co-feeding methane and steam over Cumordenite. The methanol production rate was comparable to that reported in the stepwise process in which activation, methane reaction, and extraction of methanol were carried out separately.

• Journal of the Korea Organic Resources Recycling Association
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• v.15 no.3
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• pp.113-120
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• 2007

Anaerobic batch tests were performed to evaluate the characteristics of methane production from piggery manure such as the ultimate methane yield (UMY), the kinetic constant and the maximum methane production rate. The kinetic behavior of anaerobic degradation of piggery manure was assumed as a first order reaction. The UMY, the first order kinetic constant and the maximum methane production rate were 0.27~0.44L $CH_4/gVS$, $0.161{\sim}0.280d^{-1}$ and 0.043~0.120L $CH_4/d$, respectively. Reactor of piggery manure as the self-seed source of anaerobic digestion resulted in longer acclimation time than reactors seeded with anaerobic digested sludge (ADS). But there was no little difference in the UMY between the two seed materials. The anaerobic digestion can be effective for the treatment of piggery manure containing high concentration of solids, the two-stage anaerobic digestion is, however, thought to be more effective than the traditional single one.

• Korean Journal of Environmental Agriculture
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• v.27 no.2
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• pp.145-149
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• 2008

Anaerobic co-digestion of swine manure and food waste for biogas production was performed in serum bottles at various volatile solids(VS) contents and mixing ratios of two substrates(swine manure:food waste=$100:0{\sim}0:100$). Through kinetic mode of surface methodology, the methane production was fitted to a Gompertz equation. The ultimate methane production potential of swine manure alone was lower than that of food waste regardless of VS contents. However, it was appeared that maximum methane production potentials in 80 : 20 of the mixing rate at VS 3% was enhanced at 144.7%, compared to its only swine manure. The potential increased up to 815.71 ml/g VS fed as VS concentration and food composition increased up to 3.0% and 20%, respectively. The ultimate amount of methane produced had significantly a positive relationship with that of methane yield rate. Overall, it would be strongly recommended that feeding stocks use 20% of mixing ratio of food waste based on VS 3% contents when operating the anaerobic reactor on site at $35^{\circ}C$ if not have treatment of its anaerobic waste water.

• Journal of Microbiology and Biotechnology
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• v.22 no.10
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• pp.1452-1456
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• 2012

The anaerobic oxidation of methane (AOM) in anaerobic sewage sludge was characterized. The net methane oxidation was observed in samples amended with methane plus sulfate or with methane alone, whereas methane formation was observed in the samples without methane, indicating that methane oxidation and formation occurred simultaneously. The ratio of the net methane oxidation rate to $H_2S$ formation was 100:1, suggesting that the AOM was not closely associated with sulfate reduction in the anaerobic sludge. The net AOM was positively associated with the methane concentration and sludge dilution ratio. However, the rate of AOM was negatively correlated with organic substrate (acetate) concentration. Therefore, the production and oxidation of methane could be controlled by environmental conditions and dissolved organic compounds in the bulk solution.

• Journal of Korean Society on Water Environment
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• v.25 no.1
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• pp.18-25
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• 2009

Nitrogen removal and methane production from piggery wastewater were investigated in two-phase anaerobic digestion (TPAD) coupled with biological nitrogen removal (BNR) process at $35^{\circ}C$. Methane production rate was about $0.7L/L{\cdot}day$ at organic loading rate (OLR) of $1.2g{\cdot}TCOD/L{\cdot}day$ in methanogenic UASB. Conversion efficiency of the removed TCOD into methane in UASB was as high as 72% and overall TCOD removal efficiency in this system was over 97%. Ammonia nitrogen were stably removed in BNR system and overall efficiency were 98%. With recirculation of the nitrified final effluent to TPAD, nitrogen oxides were completely removed by anaerobic denitrification in the acidogenic reactor, which did not inhibit the acidogenic activities. Overall TN removal efficiency in the TPAD-BNR system was as high as 94%.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.1
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• pp.62-68
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• 2013

The effect of organic substance on its degradation rate in burial site was investigated using batch tests. Substrate were swine and cattle with the initial concentrations of 2, 4, 6, 8, and 10 g VS(volatile solids)/L, respectively. The highest methane production rates of swine and cattle were found at 2 g VS/L as 46.3 and 48.4 ml CH4/g VS.d, respectively. As substrate concentration increased, the methane production rate decreased. The inhibition constants were n and m that were estimated using nonlinear inhibition model. The values of n and m were inhibition constants of methane production rate and ultimate methane yield, respectively. The values of n and m were 4.9 and 0.6 on swine and 1.1 and 0.4 on cattle. The methane production rate was responded sensitively by increase and decrease of substrate concentration, whereas ultimate methane yield do not relatively. From a relation between n and m, inhibitory effect of substrate concentration was confirmed as uncompetitive inhibition.

• Journal of environmental and Sanitary engineering
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• v.15 no.4
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• pp.84-90
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• 2000

5L laboratory-scale anaerobic digester was used to study the effects of food size and washing rate of food waste on the mixed digestion with sewage sludge. Food waste was crushed with particle diameters of 4mm and 2mm and washed two to three times, and seven to eight times before feeding the batch digester. The digester with crushed of washed food waste showed better performance than that with uncrushed of unwashed to produce methane gas of reduce volatile solids. The digester with 2mm food waste showed 17.4% higher VS/TS reduction rate and 18ml higher methane production rate per gram VS input than that with uncrushed food waste, where VS and TS are volatile solid and total solids in the liquid effluent, respectively. Also food waste crushed eight times gave 8% higher VS/TS reduction rate and 11ml higher methane production rate per gram VS input than unwashed food waste.

• Journal of Korean Society on Water Environment
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• v.30 no.5
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• pp.559-567
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• 2014

Since the ocean dumping of organic wastes is prohibited under the London Convention, the need for land treatment of food waste leachate (FWL) has significantly been growing in recent years. This study was conducted to use thermal solubilization to turn FWL into a form that can easily be degraded during the anaerobic digestion process, thereby reducing the percentage of solids and increasing the production of methane. To derive the optimal operating conditions of thermal solubilization, a laboratory-scale reactor was built and operated. The optimal reaction temperature and time turned out to be $190^{\circ}C$ and 90 min, respectively. The BMP test showed a methane production of 465 mL $CH_4/g$ $COD_{Cr}$ and a biodegradation rate of 90.1%. The production of methane rose by about 15%, compared with no the application of thermal solubilization. To reduce the solid content of FWL and improve the methane production, therefore, it may be helpful to apply thermal solubilization to pre-treatment facilities for anaerobic digestion.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.5
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• pp.557-562
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• 2007

The purpose of this paper is to investigate the reforming characteristics and maximum operating condition for the hydrogen production by methane reforming using the compression ignition engine induced partial oxidation. An dedicated compression engine used for methane reforming was decided operating range. The partial oxidation reforming was investigated with oxygen enrichment which can improve hydrogen production, compared to general reforming. Parametric screening studies were achieved as $O_2/CH_4$ ratio, total flow rate, and intake temperature. When the variations of $O_2/CH_4$ ratio, total flow rate, and intake temperature were 1.24, 208.4 L/min, and $400^{\circ}C$, respectively, the maximum operating conditions were produced hydrogen and carbon monoxide. Under the condition mentioned above, synthetic gas were $H_2\;22.77{\sim}29.22%,\;CO\;21.11{\sim}23.59%$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.11
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• pp.942-948
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• 2007

Popular techniques for producing hydrogen by converting methane include steam reforming and catalyst reforming. However, these are high temperature and high pressure processes limited by equipment, cost and difficulty of operation. Low temperature plasma is projected to be a technique that can be used to produce high concentration hydrogen from methane. It is suitable for miniaturization and fur application in other technologies. In this research, the effect of changing each of the following variables was studied using an AC GlidArc system that was conceived by the research team: the gas components ratio, the gas flow rate, the catalyst reactor temperature and voltage. Results were obtained for methane and hydrogen yields and intermediate products. The system used in this research consisted of 3 electrodes and an AC power source. In this study, air was added fur the partial oxidation reaction of methane. The result showed that as the gas flow rate, the catalyst reactor temperature and the electric power increased, the methane conversion rate and the hydrogen concentration also increased. With $O_2/C$ ratio of 0.45, input flow rate of 4.9 l/min and power supply of 1 kW as the reference condition, the methane conversion rate, the high hydrogen selectivity and the reformer energy density were 69.2%, 32.6% and 35.2% respectively.