• 한국토양비료학회지
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• 제28권2호
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• pp.183-190
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• 1995

논포장에서 배출되는 메탄가스를 측정하기 위하여 간이폐쇄정태 chamber법을 이용하여 대표적인 시료를 채취할 수 있도록 chamber내 시료채취 높이, 시료채취시 시간간격, 하루중 시료 채취시간을 검토하였다. 1. 대표적인 시료채취를 위한 chamber내 높이는 65cm이었고 chamber 하반부에서 시료가 균일하게 섞이도록 DC fan을 추가로 설치할 필요성이 인정되었다. 2. 시간경과에 따른 chamber내 메탄농도의 변화 및 기온의 변화에서 보면 시료채취를 개시하여 30분이내에 시료를 채취하는 것이 바람직하였다. DC fan으로 chamber내부의 공기가 섞이도록 하는 것은 대표적인 시료를 얻기 위한 것 뿐 아니라 chamber내열평형을 이루어 시료(試料) 채취기간중(採取期間中) 식물(植物)의 생리적(生理的) 활성(活性)에 최소한(最小限)의 변화를 주는 방법으로 판단되었다. 3. 하루중 대표적인 메탄 배출량을 나타내는 오전 9시~12시에 시료를 채취하여 분석하되 부득이한 경우에는 또 하나의 평균적인 배출량을 나타내는 오후 6시~8시의 시료를 채취하여 분석하여도 가능할 것으로 판단되었다. 4. 수도주간(水稻株間)진 토양(土壤)에서 메탄 배출을 측정하는데 사용하는 소형의 chamber는 토양을 교란할 수 있으므로 설치한 후 최소한 6시간이 경과되어야 chamber내 메탄농도가 주위의 메탄 농도로 회복되었다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2005년도 추계학술대회 논문집
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• pp.1190-1195
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• 2005

Biomass burning is a source of greenhouse gases, carbon dioxide, methane, and nitrous oxide. Under the ideal conditions of complete combustion, the burning of biomass produces carbon dioxide and water vapor. Since complete combustion is not achieved under any conditions of biomass burning, other carbon species, including carbon monoxide, methane, non-methane hydrocarbons and particulate carbon are produced. In this study, we analyze the combustion characteristics of rice-husk, such as heat release rate, smoke production rate, the percentage variation of CO and $CO_2$, oxygen consumption rate, and mass loss under different heat fluxes (20, 50 and 70kW). As a result, at 20kW incomplete combustion is occurred so that the percentage of CO is high in initial burning and total smoke release is higher than the others. At 50kW and 70kW, the combustion behaviors is very similar except the variation of CO percentage.

• 한국지하수토양환경학회지:지하수토양환경
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• 제24권1호
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• pp.24-34
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• 2019

Soil moisture regulates the fate of methane ($CH_4$) in forest soil via biological and chemical processes. The instant effect of variable precipitation on $CH_4$ uptake is, however, unclear in the forest ecosystems. Here, we measured $CH_4$ flux in a temperate forest soil immediately after variable volume of water applications equivalent to 10, 20 40, and $80mm\;m^{-2}day^{-1}$ precipitation. $CH_4$ uptake was significantly higher when the water was not applied. The $CH_4$ uptake decreased significantly with increasing water application. $CH_4$ uptake was linked with air filled porosity and water filled porosity. $CH_4$ uptake response to actual precipitation intensity was in agreement with $CH_4$ uptake results in this study. $CH_4$ uptake decreased 55% at highest precipitation intensity. Since annual $CH_4$ flux is calculated with interpolation of weekly or biweekly field observations, instant effect of precipitation can mislead the interpolated annual results.

• 한국환경농학회지
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• 제13권3호
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• pp.359-372
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• 1994

A simplified closed static chamber method was devised for measurement of methane flux from paddy fields. Compared to automatic methane measuring system(AMMS) this chamber method provides availability with moderate costs of setup and maintenance, while it also provides the time-effectiveness compared to other closed top-type chamber method. It accomodates 30 chambers within 2 hours sampling period with two persons. And it provide a rapid and accurate analysis of methane, 30-40 samples per hour. Modified method for $N_2O$ measurements provides a precise and accurate analysis of nitrous oxide without upgrading additional heating zones for gas sampling(switching) valves.

• 대한기계학회논문집B
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• 제29권9호
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• pp.979-987
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• 2005

Numerical simulations were performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, radical concentrations, $NO_x$ formation, and heat flux in freely propagating $CH_4-Air$ flames. The additives were both carbon dioxide and hydrogen chloride which had a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, hydrogen chloride significantly contributed toward the reduction of flame speed, flame temperature, $NO_x$ formation and heat flux by the chemical effect, whereas carbon dioxide mainly did so by the physical effect. The impact of hydrogen chloride on the decrease of the radical concentration was about $1.4\~3.0$ times as large as that of carbon dioxide. Hydrogen chloride had higher effect on the reduction of $EI_{NO}$ than carbon dioxide because of the chemical effect of hydrogen chloride. The reaction, $OH+HCl{\rightarrow}Cl+H_2O$, played an important role in the heat flux from flames added by hydrogen chloride instead of the reaction, $OH+H_2{\rightarrow}H+H_2O$ which was an important reaction in hydrocarbon flames.

• 한국기후변화학회지
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• 제9권4호
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• pp.377-384
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• 2018

The chamber method is widely used for measuring methane emission from paddy rice fields. The closed static chamber has advantages of easy installation and removal in the field and low manufacturing cost. However, the manual chamber method requires a lot of labor and has a limited sampling time and frequency. To overcome the disadvantages of the manual chamber, the auto-chamber system is used for measuring methane emission. We compared the differences in methane flux between the auto-chamber and manual chamber. To investigate methane emissions by the two methods, a chamber was installed for each of the following treatments : control without rice straw (NA), spring plowing after autumn rice straw application (SPRA) and autumn plowing after autumn rice straw application (APRA). The total methane emission was lowest in the control and highest in APRA with both methods. There was no significant difference in total methane emission between the methods, but dynamic fluctuation in methane with temperature change was accurately measured in the auto-chamber. Measuring methane emission with an auto-chamber system is expected to reduce uncertainty and increase accuracy, accompanied by labor reduction.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2022년도 추계학술대회
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• pp.145-145
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• 2022

South Korea greenhouse gas emissions have increased year by year, resulting in a total emission of 727.6 million tons of CO₂ eq in 2018, a 2.5% increase compared to 2017. Among them, the agricultural sector emitted 21.2 million tons of CO₂ eq., accounting for 2.9% of the total. Among the greenhouse gases emitted from the agricultural sector, a particularly problematic is methane gas emitted from rice paddies. Methane is one of the important greenhouse gases with a global warming potential (GWP) that is about 21 times higher than that of carbon dioxide due to its high infrared absorption capacity despite its relatively short remaining atmospheric period. Since the pattern of methane generation varies depending on the rice variety and ecological type, research related to this is necessary for accurate emission calculation and development of reduction technology. Accordingly, a study was conducted to find out the changes in greenhouse gas emission according to rice varieties and ecology types. As for the rice eco-type cultivar, early maturing cultivar (Haedamssal) and medium-late rice cultivar (Saeilmi) were used. Haedamssal was transplanted on May 25 and June 25, and Saeilmi was transplanted on June 10 and June 25. The amount of methane generated according to the growing day showed a tendency to increase as the planting period was earlier. The difference between varieties was that Haedamssal showed higher methane production than Saeilmi. The total CH₄ flux in the saeilmi was 18.7 kg·h^-1(Jun 10 transplanting), 12.4 kg·h^-1(Jun 25 transplanting) during rice cultivation. Lower methane emission was observed in Saeilmi than in Haedam rice. In addition, the earlier the planting period, the higher the methane emission. This study is the result of the first year of research, and it is planned to investigate the amount of greenhouse gas emission between double cropping and single cropping using wheat cultivation after harvest for each ecological type.

• 한국토양비료학회지
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• 제43권2호
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• pp.242-251
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• 2010

이 논문은 장기간에 걸쳐 논 생태계에서 측정된 이산화탄소와 메탄의 순교환량 과 이와 동시에 모니터링된 다양한 환경요소들과의 상관관계들을 살펴보고, 이들 플럭스와 환경 요소 및 생태계 요소들이 어떻게 교환된 이산화탄소와 메탄의 동위원소비에 영향을 미치는 지를 파악하고자 하였다. 생육기간 동안 관측된 이산화탄소 및 메탄의 순교환량은 는 담수기에는 각각 일사량과 토양온도의 변화에 따라 경시적인 변화를 보였으나, 낙수기를 전후해서는 토양에 저장되어 있던 가스들이 낙수 후 확산장벽이 사라짐으로 인해 급격히 대기 중으로 대량 방출되는 경향을 보였다. 이러한 플럭스의 변화는 토양 중에 저장되어 있는 이산화탄소와 메탄의 저장량 감소와 직접적으로 연결되었고, 이에 상응하는 순교환량 중 토양의 기여분 증가와 대기 중 이산화탄소 및 메탄의 농도 증가 및 동위원소비 변화가 관찰되었다. 이러한 변화는 환원상태에서 진행되는 메탄생성의 결과로, 기질인 이산화탄소는 상대적으로 무거운 $^{13}C$ 동위원소가 축적되는 반면, 생성물인 메탄은 가벼운 $^{12}C$ 동위원소가 축적되기 때문으로 판단된다. 따라서, 토양 유래 이산화탄소는 식물체 호흡 유래 이산화탄소와 구분되는 동위원소 특성을 지내게 된다. Keeling plot 혼합 모델로 추정된 이산화탄소와 메탄의 가스교환 동위원소 지문은 담수기와 낙수기에 걸쳐 매우 뚜렷한 변화를 보였으며, 그 변화 정도는 토양 중 가스 저장량, 교환된 플럭스의 크기 및 방향, 이동 경로, 부분적인 방출 이산화탄소의 재흡수도, 메탄의 산화정도 등에 의해 크게 달랐다. 본 연구의 결과들은 자연상태에서 관측된 플럭스와 결합된동위원소 기술이 생태계 내 다양한 가스 교환 메커니즘을 이해하는데 매우 유용한 도구가 될 수 있음을 보여주였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.143-150
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• 2003

The synthesis gas generated in waste pyrolysis melting process which consists of pyrolysis of waste and melting process of ash is known to be an alternative fuel. Since the compositopn of synthesis gas is much different from other synthesis gases, the fundamental combustion characteristics are analyzed in this study. The radiation heat heat flux is used to estimate the heat flux from flames made by many combinations of fuel and oxidant supply. The results show that the synthesis gas needs much more amount of oxidant for equivalent heat flux to methane flame and the inverse diffusion flame type for synthesis gas burner is suitable for better radiation heat transfer.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집B
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• pp.168-174
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• 2000

This paper illustrates the validity of reciprocating type superadiabatic combustor as a industrial applicable dryer. After the investigations of inner and surface temperature distributions of combustor various with air-fuel(methane) ratio, mixture flow rate and reciprocating time, this combustor can be applied in industrial dryer at certain operating conditions. The results are as follows. 1) Higher equilivalence ratio emits more radiation heat flux at the censer chamber 2) Higher mixture flow rate makes more uniform temperature distribution. however, due to the heat transfer from censer chamber to porous media, the radiation beat flux is worse. 3) Longer reciprocating time emit more radiation heat flux. however, this case also makes temperature distribution wide