• 한국축산시설환경학회지
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• 제16권3호
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• pp.175-180
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• 2010

본 시험은 혐기조건하에서 돈슬러리로부터 발생하는 온실가스 연속측정 기술을 습득하고, 이를 이용해 온실가스의 일종인 메탄 발생량 및 시간대별 배출량 변화를 알아보기 위한 목적으로 수행하였으며, 그 결과는 다음과 같다. 1. TGA의 16 site에서 측정한 값들의 평균값은 2.437 ppm이었으며 표준편차는 0.024 ppm이었다. 각 site에서 평균값과 비교한 표준편차는 10% 이내였다. 따라서 각 site에서 측정된 값은 일정한 농도를 보인다고 할 수 있다. 2. 돈분뇨 액비에서 배출되는 $CH_4$을 측정하기 위해 돈분뇨 액비 저장조에서 액비를 샘플링하여 그것을 들통에 보관하였고, 들통에서 배출되는 $CH_4$ 배출량을 측정하였다. 들통 1, 2, 3의 $CH_4$ 배출량은 각각 413.9, 373.8, 그리고 391.9 ${\mu}g\;m^{-2}\;s{-1}$였고 세 들통의 평균값은 393.2 ${\mu}g\;m^{-2}\;s{-1}$이었다.

• 한국토양비료학회지
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• 제46권6호
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• pp.575-578
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• 2013

Rice cultivation in the paddy field and the burning of crop residues have been identified as the important sources of methane emission in agricultural sector. This study aimed at assessment of the methane emission from croplands in the year of 2011 with the IPCC guideline methodology. Methane from rice cultivation was emitted 6,813 $CO_2$-eq Gg in 2011. According to the water management, methane emission amounts by continuously flooded and intermittently flooded were 1,499 and 5,314 $CO_2$-eq Gg, respectively. Methane emission by crop residues burning was highest in red pepper and followed by rice straw, pulses and barely in 2011. Methane emission by field burning was very little compared with rice cultivation.

• 한국자동차공학회논문집
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• 제6권1호
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• pp.108-121
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• 1998

Using gas chromatography, the light hydrocarbon emissions were analyzed from SI engine fueled with methane and liquified petroleum gas(LPG), and the effects of fuel and engine operating condition were discussed. For this purpose, 14 species of light hydrocarbon including 1, 3-butadiene were separated, calibrated with standard gas, and measured from undiluted emissions. The brake specific hydrocarbon emission(BSHC) and ozone forming potential(BSO)3 were calculated and discussed with the changes of fuel, engine speed, load, fuel/air equivalence ratio, coolant temperature, and spark timing. As a result, exhaust emission was composed of mainly fuel composed of mainly fuel comp- onent and other olefin components of similar carbon number. The olefin components such as ethylene and propylene determine most of the ozone forming potential. The fraction of fuel component in total hydrocarbon emission was bigger with methane fuel than with LPG fuel. Also fuel fraction increased at high speed or high speed or high temperature of exhaust gas, and to lesser extent with high coolant temperature and retarded spark. However, the effect of equivalence ratio had different tendency according to fuels.

• 한국농림기상학회지
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• 제18권4호
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• pp.320-326
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• 2016

기후-스마트 농업의 관점에서 농업 부문의 온실가스 배출량을 감축하기 위해서는 그 양을 정확히 산정하는 것이 갈수록 중요해지고 있다. 농업 부문 배출량의 상당 부분을 차지하는 논에서 발생하는 메탄 배출량의 정확한 산정을 위해 2010년 농림어업총조사의 전수자료와 수정된 물관리보정인자 산정법 및 그 계산 프로그램을 이용하였다. 그 결과를 이해하기 쉽도록 ArcGIS 소프트웨어를 사용하여 지도화하였다. 이와 같은 방식으로 계산된 값을 현장의 실측 자료와 비교하였을 때 큰차이가 없었으며, 이러한 결과는 이 연구를 더욱 확대할 필요성이 충분함을 보여준다. 본 연구에서 제작된 행정구역별 메탄 배출량 지도를 통해 지역적으로 나타나는 차이를 명확히 인식할 수 있으며, 주요 조절 인자에 대한 분석은 실질적인 메탄 저감 대책을 마련하는 데 중요한 과학적 근거를 제공할 것으로 기대된다.

• Asian-Australasian Journal of Animal Sciences
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• 제32권4호
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• pp.548-555
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• 2019

Objective: The main objective of this study was to evaluate the effect of different feeding levels of a total mixed ration silage-based diet on feed intake, total tract digestion, enteric methane emissions, and energy partitioning in two beef cattle genotypes. Methods: Six mature bulls (three Thai natives, and three Thai natives - Charolais crossbreeds) were assigned in a replicated $3{\times}3$ Latin square design, with cattle breed genotype in separate squares, three periods of 21 days, and three energy feeding above maintenance levels (1.1, 1.5, and 2.0 MEm, where MEm is metabolizable energy requirement for maintenance). Bulls were placed in a metabolic cage equipped with a ventilated head box respiration system to evaluate digestibility, record respiration gases, and determine energy balance. Results: Increasing the feeding level had no significant effect on digestibility but drastically reduced the enteric methane emission rate (p<0.05). Increasing the feeding level also significantly increased the energy retention and utilization efficiency (p<0.01). The Thai native cattle had greater enteric methane emission rate, digestibility, and energy utilization efficiency than the Charolais crossbred cattle (p<0.05). The daily metabolizable energy requirement for maintenance in Thai native cattle ($388kJ/kg\;BW^{0.75}$, where $BW^{0.75}$ is metabolic body weight) was 15% less than that in Charolais crossbred cattle ($444kJ/kg\;BW^{0.75}$). Conclusion: Our results suggested that the greater feeding level in zebu beef cattle fed above maintenance levels resulted in improved energy retention and utilization efficiency because of the reduction in enteric methane energy loss. The results also indicated higher efficiency of metabolisable energy utilization for growth and a lower energy requirement for maintenance in Bos indicus than in Bos taurus.

• Journal of Biosystems Engineering
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• 제31권6호
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• pp.457-462
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• 2006

Our environment is faced with serious problems related to the air pollution from automobiles in these days. In particular, the exhaust emissions from diesel engine are recognized main cause which influenced environment strong. In this study, the potential possibility of biodiesel fuel and oxygenates additives (dimethoxy methane) was investigated as an alternative fuel for a naturally aspirated direct injection diesel engine. The smoke emission of blending fuel (biodiesel fuel 90vol-% + DMM 10vol-%) was reduced in comparison with diesel fuel, that is, it was reduced approximately 70% at 2500 rpm, full load. But, power, torque and brake specific energy consumption didn't have no large differences. But, NOx emissions from biodiesel fuel and DMM blended fuel were increased compared with commercial diesel fuel.

• 신재생에너지
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• 제4권3호
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• pp.5-14
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• 2008

The target for the reduction of $CO_2$ emissions, as specified in the Kyoto Protocol, can only be achieved by an extended use of renewable fuels and the increasing of the energy efficiency. The energy generation from waste gases with a reasonable content of methane like biogas can significantly contribute to reach this target. A further reduction of greenhouse gas emissions is possible by increasing the electrical efficiency using progressive technologies. Fuel cells can be highly energy conversion devices. Utilizing biogas as the fuel for fuel cell systems offers an option that is technically feasible, potentially economically attractive and greenhouse gas neutral. High temperature fuel cells that are able to operate with carbon monoxide in the feed are well suited to these applications. Furthermore, because they do not require noble metal catalysts, the cost of high-temperature fuel cells has the greatest potential to become competitive in the near future compared to other types of fuel cells.

• Asian Journal of Atmospheric Environment
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• 제2권2호
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• pp.116-124
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• 2008

In this study, the Tier 2 method recommended by the Intergovernmental Panel on Climate Change (IPCC) was used to predict the methane generation rate at two landfill sites, designated as Y and C for purposes of this study, in South Korea. Factors such as the average annual waste disposal, methane emissions ($L_0$) and methane gas generation rate constant (k) were estimated by analyses of waste and the historical data for the landfills. The value of k was estimated by field experiments and then the changes in the methane generation rate were predicted through the year 2050, based on the value of k. The Y landfill site, which was in operation until the year 2008, will generate a total of 17, 198.7 tons by the end of 2018, according to our estimations. At the C landfill site, which will not be closed until the end of 2011, the amount of methane gas generated in 2011 will be 3,316 tons and the total amount of gas generated by 2029 will be 61,200 tons. The total production rate of methane gas at the C landfill is higher than that of the Y landfill. This indicates that the capacity of a landfill site affects the production rate of methane gas. However, the interrelation between the generation rate of methane and the value of k is weak. In addition, the generation of methane gas does not cease even when the operations at a landfill site come to a close and the methane gas production rate is at its highest at end of the operating life of a landfill site.

• 한국환경과학회지
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• 제21권2호
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• pp.165-179
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• 2012

Indirect $CO_2$ effect due to non-methane volatile organic compound (NMVOC) emissions from solvent and product use and fugitive NMVOC emissions from fuels in the Republic of Korea and 13 Annex I countries under United Nations Framework on Climate Change were estimated and the proportions of them to total greenhouse gas (GHG) emissions ranged from 0.092% to 0.45% in 2006. Indirect greenhouse effect ($CO_2$, $CH_4$, and $O_3$) were estimated at 13 photochemical assessment monitoring sites in the Republic of Korea using concentrations of 8 NMVOCs of which indirect global warming potential (GWP) were available. The contribution of toluene to mixing ratio was highest at 11 sites and however, the contribution of toluene to indirect greenhouse effect was highest at nine sites. In contrast to toluene, the contributions of ethane, butane, and ethylene were enhanced. The indirect greenhouse effects of ethane and propane, of which ozone formation potentials are the lowest and the third lowest respectively among targeted 10 NMVOCs, ranked first and fourth highest respectively. Acetaldehyde has relatively higher maximum incremental reactivity and is classified as probable human carcinogen however, its indirect GWP ranked second lowest.

• Asian-Australasian Journal of Animal Sciences
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• 제18권6호
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• pp.873-878
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• 2005

Emissions of nitrous oxide (N$_2$O) and methane (CH$_4$) from poultry enteric fermentation were investigated using a respiration chamber. Birds were placed in a respiration chamber for certain intervals during their growing period or for the whole life cycle. The accumulated gas inside the chamber was sampled and analyzed for N$_2$O and CH$_4$ production. A curve for gas production during a life cycle was fitted. The calculated area under the curve estimated the emission factor of poultry enteric fermentation on a life cycle basis (mg bird$^{-1}$ life cycle$^{-1}$). This method can be used to estimate CH$_4$ or N$_2$O emissions from different types of avian species taking into account factors such as diet, season or thermal effects. The CH$_4$/N$_2$O emission factors estimated for commercial broiler chickens, Taiwan country chickens and White Roman Geese were 15.87/0.03, 84.8/16.4 and 1,500/49 (mg bird$^{-1}$ life cycle$^{-1}$), respectively, while the calculated CH$_4$/N$_2$O emission from enteric fermentations were 3.03/0.006, 14.73/2.84 and 9.5/0.31 (Mg year$^{-1}$), respectively in Taiwan in the year of 2000. The described method is applicable to most poultry species and the reported emission factors were applicable to meat type poultry only.