• Title/Summary/Keyword: Methane Content

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Study on Thermal and Mechanical Properties of Epoxy Resin Nanocomposites with the Graphene Oxide (산화그래핀 첨가에 따른 에폭시 나노 복합재료의 열적 및 기계적 특성 연구)

  • Sim, Ji-hyun;Yu, Seong-hun;Lee, Jong-hyuk;Kim, Gun-soo;Chon, Jin-sung;Park, Sung-min
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.98-106
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    • 2018
  • In this study, graphene oxide(GO) was synthesized by using Hummer's method. Then, GO was used as a additive for epoxy resin nanocomposites that were prepared by mixing Tetraglycidyl diamino diphenyl methane(TGDDM) and hardner(MDEA+M-MIPA). Thermal and mechanical properties of epoxy resin nanocomposites were confirmed by analytical methods such as TG-DTA, DMA, fracture toughness, tensile strength, and flexural strength. The fracture surfaces of epoxy resin nanocomposites with different content of the GO were observed by a Scanning Electron Microscope(SEM). The mechanism for mechanical properties of epoxy resin nanocomposites was analyzed by modeling of nanocomposites with different GO weight. Due to the GO, both the heat resistance and the glass transition temperature of the epoxy resin nanocomposites were improved. Interestingly, when 0.1wt.% of GO was added to the epoxy resin/hardner mixture, the properties of mechanical increased compared with the neat epoxy resin. This results were caused by an aggregation between the GO.

Continuous Hydrogen Gas production by Immobilized Anaerobic Microorganisms (고정화 혐기성 미생물에 의한 연속적인 수소 생산)

  • 김정옥;김용환;류정용;송봉근;김인호
    • KSBB Journal
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    • v.18 no.2
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    • pp.111-116
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    • 2003
  • Hydrogen producing acidogenic microorganisms were self-immobilized using organic-inorganic hybrid polymer within 5 minutes. During the continuous tratment of synthetic wastewater at a hydraulic retention time of 20 hours, at 37$^{\circ}C$, pH 5.0, the self-immobillized granules were maintained in a stirred tank reactor. The black colored granules gradually became milky. Image analysis showed that the mean diameter of the milky colored granules ranged from 1.5 to 20. mm. The maximum bio-gas procuction rate was 380 ml/L/hy and the concentration of H$_2$was around 50%, while no methane was detected. Granular ECP was extracted and its content was measured to elucidate the role of the organic-inorganic hybrid polymer. Further increases of granule concentration are expected to increase the hydrogen production rate.

Diesel Combustion Strategies Effect on Exhaust Emissions and Hydrocarbon Species (디젤 연소 전략에 따른 배기가스 및 탄화수소 종 분석)

  • Han, Man-Bae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.759-765
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    • 2012
  • This study investigates the effect of diesel combustion strategies on exhaust emissions and hydrocarbon species emissions for a 1.7 L common rail direct injection diesel engine at 1500 rpm and 3.9 bar BMEP. The first strategy is a method to adopt no EGR with a split injection composed of pilot and main injection (split injection). The second is to adopt a moderate EGR rate with main injection only (single-1). The third is to use a high level of EGR and main injection with rail pressure increase, $i.e.$ low-temperature diesel combustion (single-2). Split injection and single-1 showed a renowned phenomenon of a PM-NOx trade-off, whereas single-2 was observed of a PM-NOx trade-off to reduce PM and NOx simultaneously. HC speciation results show that the split injection produced the least amount of HC species, regardless of the carbon number bin, followed by single-1 and single-2. The ratios of methane, acetylene, and CO to THC increased as a combustion A/F ratio is richer due to reduced oxygen content in the vicinity of the combustion zone, thus enhancing pyrolysis.

Analysis of the Impact of Fire and Explosion Accidents due to LNG Leaks in the LNG Re-gasification Process (LNG 재기화 공정에서 LNG 누출에 따른 화재 및 폭발사고의 피해영향 분석)

  • Lee, Yoon-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.6
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    • pp.825-833
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    • 2018
  • In this study, one calculated the range of damage to the combustion characteristics according to the composition of LNG and the size of leaking holes, and analyzed the damage effect in case of leakage accidents caused by pipe damage in the re-gasification process for the LNG supply system. In order to confirm the combustion characteristics according to LNG composition, there was no significant difference in the result of risk analysis by LNG-producing areas. However, the higher the methane content of the components, the lower the risk of flash fire, hazardous areas of overpressure due to explosion, and thermal radiation damage caused by jet fire. In addition, one investigated the effect of leakage, holes, and ruptures on the risk range and explosions according to the size of the pipe-leakage hole. Also, the influence of overpressure and the range of damage from radiant heat could be predicted. One confirmed the effect of LNG composition and pipe-leakage size on fire and explosion.

Development of PCS and an experiment for performance evaluation (PCS(Pressure Core Sampler) 개발 및 성능평가실험)

  • Lee, Ha-jung;Kim, Hae-jin;Lee, Gye-gwang;Jung, Hyo-seok;Son, In-rak
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.9
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    • pp.973-980
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    • 2015
  • With their wide geographical distribution, unconventional resources are continuously compared against conventional resources, but their development is expanding because TRRs (Technical Recoverable Resources) are similar to conventional resources. In particular, there is active development of unconventional gas resources such as shale gas, tight gas, CBM (coalbed methane) and gas hydrate. However, it is difficult to calculate the material properties of unconventional resources, especially the gas content, with current geophysical logging technology. Additionally, some overseas companies have monopolies on related equipment and materials. Therefore, this study developed a reservoir PCS (Pressure Core Sampler). It can collect core samples without gaseous loss by maintaining high pressure from the moment the core is sampled and record pressure and temperature in real time. Successful performance testing was also carried out for official verification of the manufactured PCS. The reservoir PCS will contribute to the acquisition of geophysical well logging data as well as accurate and reliable cores.

Isolation and Characterization of a New Methanobacterium formicicum KOR-1 from an Anaerobic Digester Using Pig Slurry

  • Battumur, Urantulkhuur;Yoon, Young-Man;Kim, Chang-Hyun
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.4
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    • pp.586-593
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    • 2016
  • A new methanogen was isolated from an anaerobic digester using pig slurry in South Korea. Only one strain, designated KOR-1, was characterized in detail. Cells of KOR-1 were straight or crooked rods, non-motile, 5 to $15{\mu}m$ long and $0.7{\mu}m$ wide. They stained Gram-positive and produced methane from $H_2+CO_2$ and formate. Strain KOR-1 grew optimally at $38^{\circ}C$. The optimum pH for growth was 7.0. The strain grew at 0.5% to 3.0% NaCl, with optimum growth at 2.5% NaCl. The G+C content of genomic DNA of strain KOR-1 was 41 mol%. The strain tolerated ampicillin, penicillin G, kanamycin and streptomycin but tetracycline inhibited cell growth. A large fragment of the 16S rRNA gene (~1,350 bp) was obtained from the isolate and sequenced. Comparison of 16S rRNA genes revealed that strain KOR-1 is related to Methanobacterium formicicum (98%, sequence similarity), Methanobacterium bryantii (95%) and Methanobacterium ivanovii (93%). Phylogenetic analysis of the deduced mcrA gene sequences confirmed the closest relative as based on mcrA gene sequence analysis was Methanobacterium formicicum strain (97% nucleic acid sequence identity). On the basis of physiological and phylogenetic characteristics, strain KOR-1 is proposed as a new strain within the genus Methanobacterium, Methanobacterium formicicum KOR-1.

A Study on Improvement of Distribution Facility in Wholesale Agricultural Products Market

  • Gal, Won-Mo;Kwon, Ki-Tae;Lee, Woo-Sik;Choi, Eun-Mee;Kwon, Lee-Seung;Seong, Seung-Hwan;Kwon, Woo-Taeg
    • Journal of Distribution Science
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    • v.16 no.2
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    • pp.53-65
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    • 2018
  • Purpose - The purpose of this study is to investigate the effect of gamma - irradiation on the effluent from food distribution in the large agricultural and marine products market. This study will contribute to the distribution process as well as the agricultural and fishery distribution facilities. Research design, data, and methodology - In order to reduce the odor, the smell was examined in the anaerobic digestion process by irradiating gamma rays to the wastewater of mixed food discharged from a large restaurant. An odor determination panel list was constructed to determine if the odor was present in the air dilution drainage and the odor concentration was analyzed by instrumental analysis. Results - It was confirmed that the sulfur content increased gradually from 3 months. Ammonia decreased from 33.57ppm at the initial measurement to 4.12 ppm at the end of the experiment. Methane production was highest at 100kGy when exposed to gamma rays of 0-200kGy at pH 12. In other words, it is considered that gamma irradiation doses are most effective at 100kGy and are suitable for large capacity wastewater treatment facilities in terms of economic feasibility. Conclusions - In pre-treatment of compound food wastewater, gamma irradiation is most cost effective when examined at 100kGy. The economic efficiency of the pre-treatment method by gamma irradiation is much higher than the wastewater treatment in the large-scale agricultural and marine products distribution market.

Mixture treatment of food waste and sewage sludge using pilot scale anaerobic digester (Pilot scale 2단 혐기성 소화조를 이용한 음식물쓰레기와 하수슬러지의 혼합처리)

  • Park, Nam-bae;Lee, Heon-Mo;Lee, Byung-Heon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.7 no.2
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    • pp.47-55
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    • 1999
  • Recently, the treatment of that wastes according to increase of food waste has been a great problem of modern society for long time. This study was aimed to evaluate possibility for food waste and sewage sludge mixture treatment using pilot scale two-phase anaerobic digester. Pilot scale two-phase anaerobic digestion system was performanced at 1 : 9 mixture ratio of food waste and sewage sludge infield. The detention time of digester was 20days. The average COD and VS removal efficiencies in organic loading rate $3.03kg\;TCOD/m^3-day$ were 57.7 and 47.7%, and the gas production rate and methane content were $0.4m^3/kg$ VS-day and 65.3%, respectively. TS, VS and VS/TS(%) of mixing tank were 4.44%, 2.59% and 58.34%, respectively and TS. VS and VS/TS(%) of digester in steady state were 3.32%, 1.39% and 41.90%, respectively, Through this study. it was possible to accomplish effective mixture treatment of the sewage sludge and food waste.

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Treatment of Distillery Wastewater Using a Thermophilic High-Rate Hybrid Anaerobic Reactor in Industrial Scale

  • Nam, Ki-Du;Chung, In;Young, James C.;Park, Wan
    • Journal of Microbiology and Biotechnology
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    • v.9 no.6
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    • pp.737-743
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    • 1999
  • A conventional thermophilic anaerobic digester was converted into a thermophilic high-rate hybrid anaerobic reactor (THAR) for treating distillery wastewater. The THAR has been operating successfully since May 1995 at a loading rate of 5.45 to $11.52{\;}kg/\textrm{m}^3/d$ (maximum of 15.02). The THAR has demonstrated a soluble Chemical Oxygen Demand (sCOD) removal efficiency of 85 to 91% and a total COD (tCOD) removal efficiency of as much as 72 to 84%. Product gas had a methane content of 59 to 68%. The tCOD removal rates were 4.31 to 5.43, 6.26 to 6.89, and 9.03 to $9.78kg{\;}tCOD/\textrm{m}^3/d$ for tapioca, com, and naked-barley wastewater, respectively. The sCOD removal rates ranged from 3.75 to 4.79,3.28 to 4.89, and 5.57 to 6.21kg $sCOD/\textrm{m}^3/d$ for tapioca, com, and naked-barley wastewater, respectively. There were unknown substances in a naked-barley distillery wastewater that were identified as being toxic for microorganisms. However, the THAR treated naked-barley wastewater continuously for 26 days, operating at an average tCOD loading of $11.08{\;}kg/\textrm{m}^3/d$without any signs of deterioration in either COD removal efficiency or gas production rate. During this period, the average removal efficiencies of tCOD and sCOD were 84% and 91%, respectively, and the gas production rate averaged 6.61 to $7.57{\;}\textrm{m}^3/\textrm{m}^3$ reactor/d which produced 0.57 to $0.69{\;}\textrm{m}^3{\;}biogas/kg{\;}tCOD_{rem}$. From tapioca and com wastewater, the reactor showed an average gas production rate of 3.18 to 3.46 and 4.91 to $5.22{\;}\textrm{m}^3/\textrm{m}^3$ reactor/d which produced 0.53 to 0.69 and 0.62 to $0.71{\;}\textrm{m}^3/kg{\;}tCOD_{rem}$, respectively.

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Properties of Rigid Polyurethane Foams Synthesized from 4,4 (4,4'-Diphenylmethane Diisocyanate와 Polyether Polyol로부터 제조된 경질 폴리우레탄 폼의 물성)

  • 서원진;정현철;김연희;김우년;최건형
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.185-192
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    • 2002
  • Rigid polyurethane foams (PUFs) were prepared from polymeric 4.4'-diphenyl-methane diisocyanate (PMDI), polyether polyol, 1,4-butane diol, silicone surfactant, and distilled water. The density of the PUF was decreased from 173.7 to 41.7 kg/㎥ with an increase in distilled water from 0.5 to 3.0 php (parts per hundred polyol by weight), respectively, at the 0 php butane diol. The cell size of the PUF increased from 115 to 258 $mu extrm{m}$ with an increase in the amount of distilled water from 0.5 to 3.0 php, respectively, at the 10 php butane diol. It was found that the compressive strength of the PUF increased with the content of distilled water, at the same density. Out of the study for the surfactant effect on the properties of the PUF, it was observed that the cell site of the PUF decreased from 360 to 146 $mu extrm{m}$ with an increase in the amount of the surfactant from 0 to 0.33 php, respectively, but the tell size did not change significantly when the amount of the surfactant exceeded 0.33 php.