• 약학회지
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• 제22권3호
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• pp.157-162
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• 1978

Total organic carbon(TOC) can be determined by means of combustion and flame ionization detector. The principle of string method is that a sample acidified to pH2 and transferred into combustion tube by string is oxidized with air. Another combustion tube method is that organic compounds are oxidized in the combustion tube charged with CuO and cobalt asbestos after the acidified sample is injected directly by microsyringe. Carbon dioxide evolved was reduced under specially treated nickel catalyst and hydrogen, the methane produced was detected by flame ionization detector. Linear relationship was found between concentration and the peak height by the string method. The peak area in the case of combustion tube method is in the range of 1-200ppm. The coefficient of variation by string method was 2.3% and that by combustion tube method was 1.8%. The lower detectable limit was about 10mol. Advantages of the latter are simplicity, sensitivity and reproducibility. TOC in contineous stream can also be determined automatically by means of the string method.

• 한국수소및신에너지학회논문집
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• 제17권4호
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• pp.403-408
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• 2006

The plate reformer consisting of combustion chamber and reforming chamber for 25 kW MCFC stack has been operated and computational fluid dynamics was applied to estimate reactions and thermal fluid behavior in the reformer. The methane air 2-stage reaction was assumed in the combustion chamber, and three step steam reforming reactions were included in the calculation. Flow uniformity, reaction rate and species distribution, and temperature distribution were analyzed. In particular, temperature distribution was compared with the measurements to show good agreement in the combustion chamber, however, inappropriate agreement in the reformer chamber.

• 대한기계학회논문집B
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• 제21권2호
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• pp.195-201
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• 1997

Static and non-static flame methods were used to measure the laminar burning velocity of methane, ethane and natural gas. The flame slot angle and velocity of unburned gas mixture were determined by Schlieren method and LDV, respectively, for static flame. The diameter of nozzle was selected as 11 mm. The experimental results containing the stretch effect showed that the maximum burning velocities were 41.5 for natural gas, 40.8 for methane and 43.4 cm/sec for ethane on equivalence ratio of 1.1. Constant volume combustion chamber was also used for non-static flame. The propagation process of flame front was visualized by high speed camera during constant pressure. The maximum burning velocity of natural gas was determined as 42.1 cm/sec on equivalence ratio of 1.15.

• 한국연소학회지
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• 제6권2호
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• pp.1-7
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• 2001

In order to elucidate the turbulent burning velocity of the two-component fuel mixtures, the lean and rich two-component fuel mixtures, where methane, propane and hydrogen were used as fuels, were prepared keeping the laminar burning velocity nearly the same value. Clear difference in the measured turbulent burning velocity at the same turbulence intensity can be seen among the two-component fuel mixtures with different addition rate of fuel, even under nearly the same laminar burning velocity. The burning velocities of lean mixtures change almost monotonously as changing addition rate, those of rich mixtures, however, do not show such a monotony. These phenomena can be explained qualitatively from the local burning velocities, estimated by considering the preferential diffusion effect for each fuel component. In addition, a prediction expression of turbulent burning velocity proposed for the one-component fuel mixtures can be applied to the two-component fuel mixtures by using the estimated local burning velocity of each fuel mixture.

• 한국연소학회지
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• 제4권2호
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• pp.63-74
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• 1999

The effects of EGR and premixedness on NO formation have been numerically investigated. The flame structure is classified into three categories; premixed flame($=1)$, rich/lean premixed flame(${\alpha}=0.6$ and 0.8) and diffusion flame(${\alpha}=0$). NO formation/destruction mechanisms are assorted to thermal, reburn and Fenimore mechanisms. The temperature of unburned gas is arranged to 298 and 500 K to have access to the condition in a real internal combustion engine. The results show that all three NO formation/destruction reaction rates in the fuel rich flame zone could be decreased by EGR for rich/lean premixed flames, while those in the fuel lean flame zone are not significantly changed. Near the stagnation plane, however, only the thermal NO reaction rate is decreased. The contribution of reburn and Fenimore mechanisms for the net NO production becomes less significant as the premixedness of a flame increases. The larger amount of NO reduction with EGR is expected under the higher temperature and/or higher fuel/air premixedness conditions due to the increased contribution of the thermal mechanism. The role of Fenimore and reburn mechanisms could be important for rich premixed and diffusion flames; therefore, the effect of EGR on NO reduction could vary with fuel/air premixedness. The premixedness of a partially premixed flame changes the flame structure and could affect the NO production characteristics.

• 한국연소학회지
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• 제16권2호
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• pp.23-32
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• 2011

To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

• 한국연소학회지
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• 제19권3호
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• pp.44-52
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• 2014

Solid oxide fuel cell(SOFC) makes electric power using hydrogen or reformed from methane and emits high temperature products that contain flammable species like hydrogen, carbon monoxide and methane which varies with operation condition. SOFC/gas turbine integrated system which uses thermal and chemical energy of the discharges is more efficient than SOFC itself. Burning character of the SOFC products will affect the efficiency and stability of the system. Experiments were conducted to know the characteristics of the flame for two typical composition of SOFC products, i.e. start-up and steady state composition. When coflowing air temperature was higher than $600^{\circ}C$, auto-ignitin occurred for both fuels. Though start-up fuel has higher contents of hydrogen, it makes longer flame than steady state composition. It was inferred that the amount of oxidizer necessary to burn makes this phenomenon. Steady state composition fuel was unstable since it contains lots of water. Nozzle that had 6 holes, distance between each hole was 16.7 times of hole diameter, improved the stability of the flame.

• 한국가시화정보학회지
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• 제9권1호
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• pp.42-48
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• 2011

Six different size of torch-ignition device were applied in a constant volume combustion chamber for evaluating the effects of torch-ignition on combustion. The torch-ignition device was designed for six different volumes and same orifice size. The combustion pressures were measured to calculate the mass burn fraction and combustion enhancement rate. In addition, the flame propagations were visualized by shadowgraph method for the qualitative comparison. The result showed that the combustion pressure and mass burn fraction were increased when using the torch ignition device. And the combustion duration were decreased. The combustion enhancement rates of torch-ignition cases were improved in comparison with conventional spark ignition. Finally, the visualization results showed that the torch-ignition induced faster burn than conventional spark ignition due to the earlier transition to turbulent flame and larger flame surface, during the initial stage. Finally, the initial flame propagation was affected by torch-ignition volume.

• 한국가시화정보학회지
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• 제8권1호
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• pp.19-24
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• 2010

Five different size of orifice were applied in a constant volume combustion chamber for evaluating the effects of torch-ignition on combustion. The initial flame development and flame propagation were analyzed by the mass burned fraction and combustion enhancement rate. The combustion pressures were measured to calculate the mass burned fractions and the combustion enhancement rates. In addition, the flame propagations were visualized by the shadowgraph method for the qualitative comparison. The result showed that the combustion pressure and mass burned fraction were increased when using the torch-ignition device. The combustion enhancement rates of torch-ignition cases were improved in comparison with conventional spark ignition. Finally, the visualization results showed that the torch-ignition induced faster burn than conventional spark ignition due to the earlier transition to turbulent flame and larger flame surface, during the initial stage.

• 한국추진공학회지
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• 제26권2호
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• pp.60-71
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• 2022

최근 발사체 시장의 저비용·재사용 발사체 개발 움직임은 여러 방향으로 세분화되고 있으며, 그중 하나는 가변추력 엔진 개발이다. 또한, 우주 선진국들은 그 청정성 때문에 차세대 우주발사체 추진제로 메탄을 선택하여 연구개발을 진행하고 있다. 본 연구에서는 이에 기체메탄과 액체산소를 추진제로 사용하는 가변추력 핀틀 분사기를 개발했고, 고압 수류시험과 고압 연소시험을 통해 분무 및 연소 특성을 분석했다. 개발된 가변추력 핀틀 분사기는 이중 슬리브 구조를 가졌으며, 반복적인 상압수류, 고압수류 및 연소시험에서 기밀성과 작동성 등에 문제없음을 확인할 수 있었다. 그러나 목표했던 추력 조절 범위는 연소시험에서 달성치 못하는 등 설계상의 문제점이 발견되어 보완이 필요하다.