• Title/Summary/Keyword: Metals' ratio

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ENHANCEMENT OF PHOTOVOLTAIC PERFORMANCE IN COPPER PHTHALOCYNINE THICK FILM SOLAR CELLS

  • Ruiono, Yo Tomota;Momose, Yoshihiro;Takeuchi, Manabu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.673-677
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    • 1996
  • Copper phthalocyanine(CuPc) thick film solar cells were fabgricated byspin coating and their photovoltaic behavior was studied. Polyvinylidene fluoride (PVdF) was used for the binder. Aluminum and indium were employed as electrode metals to form Schottky contact to CuPc layer. The cells showed rectifying J-V characteristics in the dark and photovoltaic effect associated with white light irradiation. The photovoltaic performance of the cells strongly depended on contact metals, in which the formation of oxide layer between binder layer and electrode interface affected the solar cell. Influnce of the CuPc layer thickness, CuPc/PVdF ratio on the photovoltaic performance of the cells were also examined.

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Conversion and Aging Characteristics of Oxidation Catalyst for Natural Gas Vehicle with Lean-burn System (린번 천연가스자동차용 산화촉매의 정화 및 열화특성)

  • 최병철;윤성식;정종우
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.2
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    • pp.134-139
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    • 2003
  • This study was carried out to investigate the aging and conversion characteristics of oxidation catalysts for a natural gas vehicle with lean-bum system. The conversion of $CH_4$ was observed over the various composition ratio of PMs(Precious metals) and washcoating methods. On the fresh catalysts, Pd affected on the activity of $CH_4$ at low temperature more than other PMs in Pd-only and Rh/Pd/Pt catalysts. The activity at low temperature increased as a mount of Pd increases. On the aged catalysts, the $CH_4$ conversion efficiency of Pd-only catalyst with mono-layer washcoat decreased more than that of the other catalysts of $CH_4$ conversion. It was observed that the thermal durability of Rh/Pd/Pt catalysts with double-layer washcoat was better than the single washcoat catalyst.

Mechanical properties and formability of asymmetrically rolled aluminum alloy sheet (무윤활 압연한 알루미늄 판재의 기계적 특성과 성형성)

  • Akramov, S.;Kim, In-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.429-431
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    • 2009
  • Drawability and other mechanical properties of sheet metals are strongly dependent on their crystallographic orientations. In this paper the formability of the AA 5052 Al alloy sheets was investigated after asymmetric rolling and subsequent heat treatment. In most cases, after asymmetric rolling specimens showed a fine grain size and subsequent heat treated specimens showed that the ND // <111> texture component were observed. The anisotropy of formability is often described by the plastic strain ratios (r-value) as a function of the angle to the rolling direction in sheet metal. For a good formability, a high r-value is required in sheet metals. In the asymmetry rolled and subsequent heat treated Al alloy sheet, the variation of the plastic strain ratios have been investigated in this study, The plastic strain ratios of the asymmetry rolled and subsequent heat treated AA 5052 Al alloy sheets were higher than those of the original Al sheets. These could be related to the formation of ND // <111> texture components through asymmetric rolling in Al sheet.

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DC and AC Characterization of Metals Conductivity using the van der Pauw Measurement Method (Van der Pauw 측정법을 이용한 금속 도전율의 직류와 교류특성)

  • Kang, Jeon-Hong;Han, Sang-Ok
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.56 no.4
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    • pp.157-160
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    • 2007
  • The van der Pauw technique is one of the popular methods for determining the conductivity of flat metal samples. Traceability of the national standard for the conductivity has been achieved by direct current measurement techniques in national measurement institutes of many countries. But recently, alternative current measurement techniques for determining the conductivity of flat metal samples is also interested. In this study, we measured the conductivity of non-ferrous and ferrous flat metals at alternative current using van der Pauw technique. As measurement results, the conductivities of the samples were decreased according to increasing the test frequency even though the decreasing ratio was different.

The Effect of Chemical Composition of Sintering Atmosphere on the Structure and Mechanical Properties of PM Manganese Steels with Chromium and Molybdenum Additions

  • Sulowski, Maciej;Cias, Andrzej;Stoytchev, Marin;Andreev, Tchavdar
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.561-562
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    • 2006
  • The effect of chemical composition of the sintering atmosphere on density, microstructure and mechanical properties of Fe-3%Mn-(Cr)-(Mo)-0.3%C steels is described. Pre-alloyed Astaloy CrM and CrL, ferromanganese and graphite were used as the starting powders. Following pressing in a rigid die, compacts were sintered at 1120 and $1250^{\circ}C$ in atmospheres having different $H_2/N_2$ ratio and furnace cooled to room temperature. It has been found that the atmosphere composition has negligible effect on the as-sintered properties of the investigated materials.

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Dynamic Characteristics of LIM controlled by constant V/f (V/f일정제어로 제어되는 LIM의 동특성)

  • Jang, S.M.;Jeong, H.G.;Kim, B.S.;Park, Y.T.;Jeong, Y.H.;Lee, H.G.
    • Proceedings of the KIEE Conference
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    • 1995.07a
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    • pp.50-52
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    • 1995
  • This paper deals with the dynamic characteristics of LIM which is controlled by constant V/f ratio and the characteristics of the Inverter acted as interface between the utility power system and LIM. Though open-loop control method is less reliable than closed-loop control method, it's commonly used because it is simple and cheap. This paper shows the consideration for dynamic characteristics of LIM under open-loop control and for Inverter.

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Effect of Strain Slates on the Formation of Shear Textures during Rolling in fcc Metals (FCC 금속에서 압연 전단집합조직의 형성에 미치는 변형상태의 효과)

  • Kang C. K.;Choi W. G.;Huh M. Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.483-486
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    • 2005
  • In order to study the effect of strain states on the formation of shear textures during rolling in fcc metals, the evolution of textures was simulated by the full constrain model using various ideal strain states. Considering rolling as a two-dimensional problem, i.e., $\varepsilon_{22}\;=\;\varepsilon_{12}\;=\;\varepsilon_{23}\;=\;0$, the deviation from the plane-strain state manifest itself as nonzero contribution of $\varepsilon_{13}$. With increasing variations of $\varepsilon_{13}$, shear textures develop. The sign of ell hardly affects the evolution of textures. The texture simulation with various idealized strain states indicates that the ratio $\mid\varepsilon_{13}\mid/\mid\varepsilon_{11}\mid$ in each time interval in a roll gap plays a dominant role in the evolution of textures during rolling.

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Texture of Asymmetric Rolled Aluminum sheets (알루미늄 비대칭압연 집합조직)

  • Akramov, S.;Kim, In-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.477-479
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    • 2008
  • Drawability and other mechanical properties of sheet metals are strongly dependent on their crystallographic orientations. In this paper the formability of the AA 5052 Al alloy sheets was investigated after asymmetric rolling and subsequent heat treatment. In most cases, after asymmetric rolling specimens showed a fine grain size and subsequent heat treated specimens showed that the ND//<111> texture component were observed. The anisotropy of formability is often described by the plastic strain ratios (r-value) as a function of the angle to the rolling direction in sheet metal. For a good formability, a high r-value is required in sheet metals. In the asymmetry rolled and subsequent heat treated Al alloy sheet, the variation of the plastic strain ratios have been investigated in this study. The plastic strain ratios of the asymmetry rolled and subsequent heat treated AA 5052 Al alloy sheets were higher than those of the original Al sheets. These could be related to the formation of ND//<111> texture components through asymmetric rolling in Al sheet.

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The Optimum Condition Analysis of Vanadium Solvent Extraction by Alamine336 from the Synthetic Vanadium Sulfate Solution. (황산바나듐 모의용액으로부터 Alamine336에 의한 바나듐 용매추출의 최적조건 연구)

  • Ahn, Jong-Gwan;Ahn, Jae-Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.823-829
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    • 2008
  • The solvent extraction process for the recovery of vanadium from leaching solution of SCR(selective catalytic reduction) spent catalyst was investigated by using Alamine336 as an extractant. The effects of experimental conditions, such as initial pH and concentration of sulfate ion, and ammonia concentration of stripping solution were studied. The extraction percentage of vanadium were increased with the increase of initial pH of leaching solution and decreased with the increase of sulfate ion. More than 99% of vanadium in leaching solution were extracted and stripped at the A/O ratio of 1.0 in 2 stages. On the basis of these results, an optimum solvent extraction process which vanadium was effectively recovered from SCR spent catalyst was proposed.

Preparation of Ta Powder for Capacitor by SHS Process (자전연소합성법에 의한 콘덴서용 탄탈륨 분말 제조)

  • Lee, Seung Young;Lee, Sang Il;Won, Chang Whan
    • Korean Journal of Metals and Materials
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    • v.47 no.6
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    • pp.338-343
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    • 2009
  • The purpose of this study is to make the tantalum powder for solid electrolyte capacitor with SHS (self-propagating high-temperature synthesis) process. Raw materials for manufacturing Ta powder were used $Ta_{2}O_{5}$, Mg and NaCl. While progressing SHS process, $Ta_{2}O_{5}$ powder was reduced by Mg powder. The combustion temperature and velocity were easily controled by the varying mole ratio of NaCl, Mg and initial reaction pressure. In the case of only using NaCl as an inorganic agent, the shape is unagglomerated and has high surface area. whereas we were given the powder which has good net structure by the addition of excessive Mg as a diluent.