• 제목/요약/키워드: Metals' ratio

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염소를 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학 평형 계산 (An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine)

  • 이정진;황정호
    • 대한기계학회논문집
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    • 제19권12호
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    • pp.3372-3381
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    • 1995
  • An equilibrium analysis was carried out to determine principal species of heavy metals in waste incineration and their behaviors with variation of temperature, chlorine concentration, excess air ratio, and C/H ratio. The waste was assumed as a compound of hydrocarbon fuel, chlorine, and metals. Calculated results showed that the most important parameter to determine the principal species was temperature. Chlorine concentration also affected on mole fractions of the principal species. Generally principal species at high temperature were chlorides while there were some metals of which principal species were oxides. At low temperature mole fractions of the principal species increased, but at high temperature mole fractions of some metal species decreased. C/H ratio of the hydrocarbon fuel and excess air ratio had little effect on mole fractions of the metal species, compared to the temperature and chlorine concentration.

수피조성분에 의한 중금속 흡착 (Adsorption of Heavy Metal Ions by Constituents of Bark)

  • 백기현;최인규;신금
    • Journal of the Korean Wood Science and Technology
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    • 제24권3호
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    • pp.51-56
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    • 1996
  • The Bark lignin(alkali- and acid lignin), bark extractives(hot water-and $Na_2SO_3$ extractives) of Quercus acutissima and Pinus densiflora, and flavonoids were used to detect heavy metal adsorption. The adsorption ratio of heavy metals by lignin was assigned for 40 to 50%, but was not dependent on lignin kinds. However, in case of the addition of light metals such as $Ca^{++}$ and $Mg^{++}$ to lignin the adsorption ratio was increased by 20 to 40%, and $Pb^{++}$ was almost completely adsorbed. On hot water extractives, the adsorption ratio was very low because the substrate was water-soluble, so the substrate should be water-insoluble to adsorb the heavy metals. However, the adsorption ratios of $Cd^{++}$ and $Pb^{++}$ on $Na_2SO_3$ extractives were significantly increased, while those of $Zn^{++}$ and $Cu^{++}$, were similar to lignin. When four kinds of heavy metals were treated to $Na_2SO_3$ extractives together, more than 97% of $Pb^{++}$ and $Cu^{++}$ was adsorbed_ and $Zn^{++}$ was more adsorbed by 40%, and $Cd^{++}$ was not changed, comparing with the case that on kind of heavy metal was treated. There were differences between adsorption ratio of the kinds of flavonoids and heavy metals, and the adsorption ratio of heavy metals was assigned to 20 to 45% per 0.1g flavonoid.

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Cross-sectional Study for Blood Metal Concentration in Patients with Herbal Medicine Intake

  • Park, Yeong-Chul;Lee, Sun-Dong
    • 대한예방한의학회지
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    • 제13권1호
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    • pp.93-103
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    • 2009
  • Evidences from various countries suggest that toxic heavy metals in herbal medicine may constitute a serious health problem. In order to evaluate whether the toxic heavy metals caused by herbal medicine intake, blood samples collected from 222 patients taking herbal medicine were analyzed. In average levels of analyzed metals, $0.4{\sim}33.9%$ of total samples for 8 metals such as Cd, Co, Cu, Hg, Mn, Ni, Pb and Zn except Cr and Fe exceeded the upper limit for WHO reference value. In analysis of regression coefficients indicating the levels of metals increased or decreased after taking herbal medicine for one month, however, there were different aspects by intake types for herbal medicine. For example, the metals increased by taking decoction in blood samples were as follows; Cd and Pb whether Mn, Ni and Pb as increased metals were identified in the group taking pill and decoction(combined intake group). The odds ratio showing values higher than 1 indicating that people who take herbal medicine would have possibility higher for metal accumulation in blood than that from people who do not take herbal medicine. The metals showing the odds ratio higher than 1 were Hg and Ni in decoction group, and Cd and Hg in combined intake group. However, eight of the total, 10 metals showed the odds ratios lower than 1 by taking herbal medicine. Thus, this may explain the possible role of herbal medicine as a chelator for heavy metals in body.

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Comparison of heavy metal concentrations in hairs of a small sample of Korean patients taking traditional herbal medicine

  • Park, Yeong-Chul;Kim, Myung-Dong;Park, Sung-Kyun;Kim, Hyun-Do;Lee, Sun-Dong
    • Advances in Traditional Medicine
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    • 제10권3호
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    • pp.141-149
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    • 2010
  • A concern of safety issue for traditional herbal medicine is the possibility of some herbs containing heavy metals responsible for several cases of metal poisoning. In our previous study, the physiological levels of heavy metals, such as Cd, Cu, Hg and Pb, were examined to evaluate a potential risk in patients taking herbal medicine. In this study, the levels of 12 heavy metals, including non-metallic element, Se, were analyzed in hair and compared to the results from the previous study. In the previous study, the levels of Cd, Cu, Hg and Pb in hair showed a significantly lower odds ratio than 1. In this study, however, all metals did not show any significant odds ratio higher or lower than 1 even if 5 of 12 metals showed lower odds ratio than 1. In addition, the levels of metal concentrations, especially for Cu, Fe, Pb and Zn, exceeding the WHO reference values were observed in hair. However, any evidence for metal accumulation in hair caused by taking herbal medicines for long duration was not observed in analysis of multiple regression and odds ratio from case-control study. This result would show another possibility for a role of herbs as a non-enzymatic chelator inhibiting the gastrointestinal absorption of heavy metals.

단락시간비를 이용한 GMAW의 비드 높이 제어에 관한 연구 (A Study on Bead Height Control of GMAW by Short Circuit Time Ratio)

  • 감병오;조상명;김상봉
    • 한국해양공학회지
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    • 제16권2호
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    • pp.53-59
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    • 2002
  • This paper shows the experimental results controlling the height of surface and back bead in GMAW by analyzing the unexpected gaps between base metals produced in welding and by controlling welding velocity due to the variation of the gap between base metals in thin-plate welding. The back bead behavior and burn-through in I-type butt joint $CO_2$ welding of thin mild steel are analyzed in the views of short circuit time ratio and short circuit frequency. It is shown through experimental consideration that the short circuit time ratio method is more reasonable than the short circuit frequency method in analyzing the formulation of back bead under changing the gap between base metals. Based on the these results, welding manipulator is designed so as to satisfy the bead height control in real time by measuring the short circuit time ratio. To show the effectiveness of the developed bead formulation control system, the experiment is implemented under two welding conditions such as increasing gap from 0mm to 0.8mm and gradually increasing gap from 0mm to 1.2mm. The experimental results show that the bead formulation can be controlled uniformly in spite of the variation of the gap between base metals.

금속판재의 성형성 (Formability of Sheet Metals)

  • 이동녕
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1994년도 박판성형기술의 진보
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    • pp.11-23
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    • 1994
  • Formability of sheet metals can be evaluated using tensile testing. Easily measured tensile properties such as yield strength, tensile strength, elongation, strain hardening exponent, strain rate sensitivity and plastic strain ratio are important parameters to evaluated the sheet formability. This paper briefly explains how these properties are related to deep drawability and stretchability. The plastic anisotropy of sheet metals is usually attributed to the crystallographic texture. However dislocation distribution may influence the anisotropy.

An Exploratory Study Comparing Blood Metal Concentrations between Stroke and Nonstroke Patients in Koreans

  • Park Yeong-Chul;Park Hae-Mo;Ko Seong-Gyu;Lee Sun-Dong;Park Hong-Duok
    • 한국환경보건학회지
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    • 제32권3호
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    • pp.199-206
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    • 2006
  • Various heavy metals have been known for causing ischemic stroke. In order to describe the causative relationship between the blood levels of various heavy metals and stroke patients, 116 patients with stroke and 111 patients without stroke were selected from one Oriental medical hospital in Wonju, Korea. Total of 9 kinds of metals such as As, Cd, Co, Cu, Hg, Mn, Ni, Pb, and Zn were analyzed in blood from patients with and without stroke. There were no significant differences in the means of metal concentrations between the stroke and nonstroke patients except for the mean of Co concentration. In the case of Co, the means for stroke and non-stroke patients were 0.44 ug/l and 0.40 ug/l showing a significant difference at the level of p-value=0.05. The odds ratios for each metal ranged from 0.96 to 2.86. Most odds ratios were not significant but the odds ratio for Co, $2.86{\pm}1.49$ was significant, indicating that Co increases the risk of stroke by 2.86 times. In order to identify the specific risk level of stroke increased by a multiple interaction of metals, regression coefficients and odds ratio for a pair or multiple pair of metals were reanalyzed. However, all of regression coefficients and odds ratios were not significant. In conclusion, Co showed the significant level in blood from patients with stroke. In addition, the odds ratio of stroke was significantly different from other metals. Thus, it is considered that Co among various metals analyzed in this study is the important metal for increasing the risk of stroke.

열처리조건에 의한 자동차용 EGR쿨러의 브레이징부 접합강도에 관한 연구 (A Study on the Strength of Brazed Joint for Automotive EGR Cooler by Heat Treatment Conditions)

  • 이준;한창석
    • 열처리공학회지
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    • 제22권4호
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    • pp.210-216
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    • 2009
  • Stainless steel EGR cooler of diesel engine is widely used to prevent the corrosion due to the content of sulfur in diesel fuel. The strength of brazed joint between stainless steel materials is very important. It is essential to observe the spreading ratio of the filler metals under the condition of deoxidation or vacuum during heating process. In this experiment, spreading ratio was tested to find the optimum brazing condition for stainless steel using brazing filler metals of FP-613, BNi-2 and BNi-5 on sus304 and sus410. Anti-corrosion tests were also performed on the above filler metals with solution of 5% $H_2SO_4$, 65% $HNO_3$ and 5% $NH_4OH$. Consequently FP-613 has good ability for anti-corrosion with 30% of chromium content compared with other filler metals. The optimum brazing conditions are occurred at $960^{\circ}C$ for 90 min. and at $1090^{\circ}C$ for 50 min. at the same degree of vacuum, $2{\sim}3{\times}10^{-3}$ Torr.

국내 범용 비철금속 스크랩의 리싸이클링 현황 (Current Status on the Recycling of Domestic Major Non-ferrous Metal Scraps)

  • 박형규;손호상
    • 자원리싸이클링
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    • 제24권5호
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    • pp.72-79
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    • 2015
  • 비철금속은 종류가 많아서 비철금속 전반에 걸친 리싸이클링 현황을 파악하기에는 분량이 너무 방대하기 때문에 개별 금속에 대해서는 리싸이클링 현황이 조사 보고되었지만 비철금속 스크랩 전반에 대해서는 통계자료가 아직 공식적으로 발표되지 않고 있다. 본 고에서는 상용 비철금속인 동, 알루미늄, 아연, 연, 니켈 및 마그네슘에 대하여 최근 몇년(2010 - 2014년) 간의 국내 수요, 생산량과 스크랩에 대한 리싸이클링 현황을 조사하고 이를 토대로 리싸이클링율을 추정하였다.

와전류 시험에 의한 금속의 변태율 측정에 관한 연구 (The Eddy Current Method to Measure the Transformation Ratio in Metals)

  • Wee, Sang-Bong;Han, Min-Koo;Paek, KI-Nam
    • 대한전기학회논문지
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    • 제38권5호
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    • pp.348-354
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    • 1989
  • The metallurgical transformation ratios of metals have been evaluated by the eddy current method. Eddy current probes have been designed and applied to various standard samples. The equivalent impedance estimated from the eddy current measurement is closely related to the variation of transformation ratios in metals. It has been found that the variation of the impedance is relatively large in the samples where the transformation ratios of the samples are small. Both reactance and resistance increase when the transformation ratio is large. Sensitivities of eddy current test is increased with increasing frequencies and by inserting ferrite core the solenoid eddy probe. Our results have shown the implementation of eddy current measurement to the one-line nondestructive testing of metals.

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