• Title/Summary/Keyword: Metallic powders

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HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Synthesis of Ultrafine Titanium Carbide Powder by Novel Thermo-Reduction Process (신 열환원 공정에 의한 초미립 티타늄 카바이드 분말 합성)

  • ;S.V. Alexandrovskii
    • Journal of Powder Materials
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    • v.10 no.6
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    • pp.390-394
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    • 2003
  • Ultra fine titanium carbide particles were synthesized by novel metallic thermo-reduction process. The vaporized TiC1$_4$+$CCl_4$ gases were reacted with liquid magnesium and the fine titanium carbide particles were then produced by combining the released titanium and carbon atoms. The vacuum treatment was followed to remove the residual phases of MgC1$_2$ and excess Mg. The stoichiometry, microstructure, fixed and carbon contents and lattice parameter were investigated in titanium carbide powders produced in various reaction parameters.

Effect of Chamber Pressure on the Microstructure of Fe Nano Powders Synthesized by Plasma Arc Discharge Process (플라즈마 아크 방전법으로 제조된 Fe 나노분말의 미세조직에 미치는 챔버압력 영향)

  • 박우영;윤철수;김성덕;유지훈;오영우;최철진
    • Journal of Powder Materials
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    • v.11 no.4
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    • pp.328-332
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    • 2004
  • Fe nanopowders were successfully synthesized by plasma arc discharge (PAD) process using Fe rod. The influence of chamber pressure on the microstructure was investigated by means of X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FE-SEM), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared particles had nearly spherical shapes and consisted of metallic cores (a-Fe) and oxide shells (Fe$_{3}$O$_{4}$), The powder size increased with increasing chamber pressure due to the higher dissolution and ejection rate of H$_2$ and gas density in the molten metal.

Changes of Getter properties by Crystallization of Amorphous Zr-V-Ti alloy Powders (비정질 Zr-V-Ti 합금분말의 결정화에 따른 게터 특성 변화)

  • Park, Je-Shin;Kim, Won-Baek;Baek, Jin-Sun
    • Journal of Powder Materials
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    • v.14 no.1 s.60
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    • pp.50-55
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    • 2007
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Ti_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature. $Zr_{57}V_{36}Ti_7$ amorphous alloy was prepared by ball milling. The hydrogen sorption rate of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption rate of partially crystallized alloy was explained in terms of grain refinement that has been known to promote the diffusion into metallic bulk of the gases. The grain refinement could be obtained by crystallization of amorphous phase resulting in the observed increase in sorption property.

A Study on the Arsenic Removal Characteristics of TiO2 Powders in Ground Water (상용 TiO2의 지하수 비소제거 특성에 관한 연구)

  • Lee, Dong Ho;Kim, Sung Su
    • Journal of Korean Society on Water Environment
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    • v.31 no.6
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    • pp.632-636
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    • 2015
  • This study aims to evaluate arsenic adsorption efficiencies over various metal oxides (CeO2, TiO2, Fe3O4, ZrO2, AlOOH, SiO2, α-Al2O3, and γ-Al2O3) and investigate the correlation between physico-chemical characteristics of metal oxides and their efficiencies. From XPS, XRD BET analysis and isotherm adsorption test, TiO2 powder showed that the best adsorption efficiency, and it's mechanism was highly depended on the chemical adsorption.

Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Mechanism and Characteristics of Nano-dispersed Powder by Pulsed Discharge Method

  • Kwon, Young-Soon;Ilyin, Alexander P.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2003.10a
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    • pp.27-32
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    • 2003
  • The phenomenon of electrical explosion of conductors is considered in the context of the changes in the energy and structural states of the metal at the stages of energy delivery and relaxation of the primary products of EEC. It is shown that these changes are related to the forced interaction of an intense energy flux with matter and to the subsequent spontaneous relaxation processes. The characteristics of nano-sized metal powders are also discussed.

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Effect of Relative Density on the Tensile Properties of Powder Injection Molded PH 17-4 Stainless Steel (분말사출성형된 17-4 PH STS 소결체의 밀도에 따른 인장 특성)

  • 성환진;하태권;안상호;장영원
    • Journal of Powder Materials
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    • v.9 no.4
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    • pp.211-217
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    • 2002
  • It is well known that the powder injection molding(PIM) process can overcome the shape limitations of traditional powder compaction, the costs of machining, the productivity limits of isostatic pressing and slip casting, and the defect and tolerance limitations of conventional casting. Increasing demands from industry for not only the dimensional accuracy nut mechanical strength in PIMed parts have had much effort focused on the investigation of mechanical properties of mechanical strength in PIMed parts have had much effort focused on the investigation of mechanical properties of sintered parts formed with high-strength metallic powders. The 17_4 PH $10\mu{m}$ were injection-molded into flat tensile specimens. Sintering of the compacts was carried out at the various temperatures ranging from 900 to $1350^{\circ}C$. Sintering behavior of the compacts and tensile properties of sintered specimens were investigated.

Fabrication of Bulk Metallic Glass Alloys by Warm Processing of Amorphous Powders (비정질 분말의 열간 성형법에 의한 벌크 비정질합금의 제조)

  • 이민하;김도향
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.193-201
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    • 2004
  • 1960년 Au-Si계 합금에서 처음으로 비정질상이 급속 응고법에 의해 보고된 이래/sup 1)/ 지난 40년 간 많은 합금계에서 비정질상이 보고되어졌다. 대표적으로 Fe-, Ni-, Co기 합금 등 많은 합금계에서 비정질상이 보고되었으나, 비정질상의 형성을 위해서는 약 105 K/s이상의 높은 냉각속도를 필요로 하였다. 1980년대 수백 K/s의 낮은 냉각속도 하에서도 비정질상이 형성될 수 있는 다원계 합금(multi-component alloy)이 Mg-Ln-(Ni, Cu, Zn), Ln-Al-TM 합금에서 보고되어 졌으나 많은 관심을 받지 못하다가 1993년 Zr-Ti-Ni-Cu-Be 합금에서 수 ㎝ 크기의 비정질합금 제조가 보고되면서 전 세계적으로 많은 관심을 받게 되었다. Zr-Ti-Ni-Cu-Be계 벌크 비정질 합금이 보고된 후 Zr-(Nb,Pd)-Al-TM, Pd-Cu-Ni-P, Fe-Co-Zr-Mo-W-B, Ti-Zr-Ni-Cu-Sn등 여러 합금계에서 벌크 비정질 합금이 보고되었다. (중략)