• Korean Chemical Engineering Research
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• 제51권4호
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• pp.443-454
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• 2013

콜로이드 실리카와 가용성 실리카를 이용하여 나트륨이 첨가되지 않은 다양한 금속이온 첨가 MCM-41 촉매를 제조하였다. 전이금속 이온인 $V^{5+}$, $Co^{2+}$ 및 $Ni^{2+}$이 MCM-41에 첨가되었을 경우 기공벽 내의 실리콘 이온과 등방치환을 하여 실리카 기공벽 내에서 독립된 단일 활성점을 형성하여 우수한 환원 및 활성 내구성을 보였다. 수소 승온 환원법을 이용하여 Co-MCM-41 촉매의 기공 곡률 반경효과에 대해 검토해 본 결과, 적절한 환원 처리와 기공 크기 및 pH 조절에 따라 코발트 금속입자의 크기를 1nm 이하의 범위에서 조절할 수 있었으며, 이 미세 금속 입자들은 표면 금속이온들과의 결합으로 인해 상당한 고온 안정성이 있음을 발견하였다. 완전 환원 후에도 비정형 실리카의 부분 덮힘으로 인해 금속 입자들의 표면 이동 및 뭉침 현상이 현저히 저하되는 것을 볼 수 있었다. 이들 촉매의 반응 예로 금속 입자 크기에 민감한 단일층 탄소 나노튜브의 합성을 Co-MCM-41을 이용하여 실시하였고, 금속 입자의 안정성 시험반응으로 Co 및 Ni-MCM-41을 이용한 CO 메탄화 반응, V-MCM-41을 이용한 메탄올 및 메탄의 부분 산화반응 및 기공곡률 반경이 촉매활성에 미치는 영향 등을 살펴보았다.

• 한국세라믹학회지
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• 제22권5호
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• pp.47-53
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• 1985

In view of innovated utilization of Korean clay resources conventional techniques for pulverization are reviewed in comparison with fluid energy milling processes of fluidized-bed type. Throughout experiment indigenous halloysite ores (white grade) after usual pretreatment are employed as typical sample. It is evidenced that grinding by means of porcelain ball mills has limitation in reducing clay particles to less than 10${\mu}{\textrm}{m}$ in diameter regardless of whether it is processed in dry or wet. Upon use of tungsten carbide bull mill particulation to submicron sizes could be effected with relative ease but severe coloration in grey is attended indicating metallic contamination possibly from friction of the grinding apparatus itself. In contrast the modified fluid en ergy milling enables particulation to $\leq$10${\mu}{\textrm}{m}$ in diameter with simultaneous classification int olimited ranges of particle size distributions. Since this technique is in principle based on the interparticle collisions rather than on the frictions between particles and mill surfaces minimum impurity attendance would be an additional advantage. Evidence leads to the conclusion that the fluidized-bed type milling is regarded as highly effective in puverization as well as fractionation of the clay minerals under examination. This is especially so in contemplating high-value and/or high-purity clay products.

• Advances in nano research
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• 제2권2호
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• 대한기계학회논문집B
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• 제25권12호
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• pp.1802-1812
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• 2001

The purpose of this study is to analyze numerically the movement of particles included in turbulent fluid flow characteristics of metallic surfaces. To describe fluid flew, the incompressible Navier-Stokes equation discretized by the finite volume method were solved on the non-orthogonal coordinates with non-staggered variable arrangement, and the k-$\xi$ turbulence model was adapted. After fluid flow was calculated, particle movement was predicted from the Lagrangian approaches. Non-essential complexities were avoided by assuming that the particles had spherical shapes and the Stoke's drag formula only consisted of external farces acting upon them. In order to validate the numerical calculations, the results were compared with the experimental data reported in literature and agreed well with them. The drag force coefficient equation showed better agreement with the experimental data in the prediction of particle movement than the correction factor equation. Impact velocity and impact angle increased as inlet turbulence intensity decreased, relative jet height was lower. or the Reynolds number was larger.

• 한국재료학회지
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• 제17권8호
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• pp.397-401
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• 2007

Fe based SOFC(Solid Oxide Fuel Cell) interconnector was fabricated by using the spark plasma sintering process and its microstructure and mechanical properties were investigated in this study. To fabricate the interconnector, the Fe-26Cr powder was mixed with the Ag (5, 10, 20wt.%) particles. In the Fe-26Cr-Ag sintered bodies, the Ag particles were almost dispersed at the grain boundary of the Fe-26Cr. The sintered bodies have the density of 87.2-97.5%, the density increases with increasing Ag content at sintering temperature of $850^{\circ}C$. Also, the compressive yield strength increases with increasing Ag content at the same sintering temperature.

• 한국분무공학회지
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• 제19권2호
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• pp.88-93
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• 2014

Nanofluids is that metallic or nonmetallic nanometer-sized particles are dispersed in liquid and they can be used in various fields to increase the heat transfer rate. This study conducted experiments to evaluate whether the cooling efficiency of nanofluids is better than that of water in spray cooling. A heated surface was designed and fabricated to make the temperature distribution be linear, which was confirmed by three thermocouple measurements under the heated surface. Spray cooling experiments were conducted using water, 0.2% wt. (weight), and 0.5% wt. $Al_2O_3$ nanofluids at the pressure of 0.2 MPa and 0.3 MPa. Based on the results, it is shown that the cooling efficiency of nanofluids is higher than that of water especially in the region of single phase heat transfer. As a result, we can expect that nanofluids can be used as efficient coolants in the cooling of electronic packages where the temperature of the heated surface is not high enough for boiling incipience.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2008년도 추계학술대회 초록집
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• pp.153-154
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• 2008

High velocity oxy-fuel (HVOF) thermal spraying coating has been used widely throughout the last 60 years mainly in defense, aerospace, and power plants. Recently this coating technique is considered as a promising candidate for the replacement of the traditional electrolytic hard chrome plating (EHC) which pollutes the environment and causes lung cancer by toxic hexa-valent $Cr^{6+}$. In this study, two kinds of cermet coatings, WC-CoCr and WC-CrC-Ni, are formed by HVOF spraying. The wear properties of coatings are evaluated comparatively by reciprocating sliding wear tests at $25^{\circ}C$, $250^{\circ}C$ and $450^{\circ}C$ respectively. Wear rates show that WC-CoCr coatings have better sliding wear resistance than WC-CrC-Ni coatings regardless of temperature due to more, compact and homogeneously distributed WC particles, less metal content, Co, Cr rich metallic bindermatrix with higher fracture strength and better adhesive strength with WC particles.

• 대한기계학회논문집B
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• 제29권4호
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• pp.504-511
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• 2005

The generation of fine relics of inorganic and metallic materials from precursor suspensions is of significant current interest as it holds the key to the fabrication of display and printed circuit board. Some novel printing methods depositing ceramic particles have been suggested in recent years. When a conducting liquid is supplied to a capillary nozzle at a low flow rate and when the interface between air and the liquid is charged to a sufficiently high electrical potential, the liquid meniscus takes the form of a stable cone, whose apex emits a microscopic jet. This is called as a cone-jet mode. In our experiments, an alumina particles flowing through a nozzle were subjected to electro-hydrodynamic printing in the cone-jet mode. The pattern of 'YONSEI' characters was tested at $10 {\mu}l/min$ of alumina ink flow rate and different applied voltages. At an applied voltage of 6 kV, feature size was in the range of $250 {\mu}m.$

• Composites Research
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• 제37권2호
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• pp.94-100
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• 2024

In order to evade the premature failure of super duplex stainless steels (SDSSs) in some harsh environments, the increase of their mechanical properties is a promising approach. In this study, based on the laser powder bed fusion (LPBF) technique, SDSS matrix composites without post heat treatment were fabricated by using the powder mixture of SDSSs, super austenitic stainless steels (SASSs) and micron-sized TiC particles. Many in-situ TiC_xN_y nanoparticles were found to be formed by using micron-sized TiC particles in as-built composites, and both fine ferrite and austenite grains were generated. The as-built composites exhibited an excellent combination of high ultimate tensile strength (UTS) (~1066 MPa) and good uniform elongation (UE) (~15.6%), showing a better mechanical property compared with other reported LPBF-fabricated SDSSs, which was mainly attributed to the fine grain, Orowan and dislocation strengthening mechanisms. In particular, the successful fabrication of SDSS matrix composites can set the stage for producing high-performance metallic parts via LPBF technique.

• Corrosion Science and Technology
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• 제23권4호
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• pp.324-333
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• 2024

Atmospheric corrosion poses a significant threat to durability of metallic materials and safety of structures, making precise prediction of corrosion rates crucial in industrial and engineering settings. Understanding the exact rate of corrosion is essential. However, accurate inclusion of various environmental factors that can influence atmospheric corrosion in the calculation of corrosion rate is a complex challenge. This study introduces a physics-based model that incorporates electrochemical methods and considers active surface area affected by surface contaminants to estimate atmospheric corrosion rate of carbon steel. The model can evaluate corrosion levels using key factors such as chloride deposition rate, relative humidity, and the presence of surface particles. By integrating these considerations, this model moves beyond empirical estimations, providing a more stable prediction of corrosion rate that is less susceptible to environmental variations. This model provides a robust tool for defense applications, offering precise insights into the dynamics of atmospheric corrosion that could enhance the maintenance and safety of weapon systems.