• 제목/요약/키워드: Metallic particle

검색결과 205건 처리시간 0.022초

MAGNETIC PROPERTIES OF NANOCRYSTALLIZED METALLIC GLASSES AT ELEVATED TEMPERATURES

  • Lachowicz, Henryk K.
    • 한국자기학회지
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    • 제5권5호
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    • pp.589-596
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    • 1995
  • In the present paper some of the magnetic properties of the nanocrystalline Fe-based magnets produced by an appropriate annealing of their metallic glass precursors are reviewed. These properties are discussed on the grounds of their characteristics measured at the elevated temperatures. It is shown that the effective magnetostriction these magnets display, results from the competition among two contributions of the opposite sign originating from the individual magnetic phases, crystalline phase and the residual glassy matrix in which the nanocrystallites are embedded. It is also shown that at certain conditions the magnets considered expose superparamagnetic behavior and that their isothermal magnetization characteristics can successfully be used to calculate the distribution of the particle volumes. Application of the recently invented new genetic algorithm method, a powerful tool to calculate these distributions is, finally, presented.

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Chemical Properties of the Individual Asian Dust Particles Clarified by Micro-PIXE Analytical System

  • Ma, Chang-Jin;Kang, Gong-Unn;Kasahara, Mikio;Tohno, Susumu
    • Asian Journal of Atmospheric Environment
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    • 제8권3호
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    • pp.154-161
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    • 2014
  • The present study was undertaken to evaluate the chemical characteristics of Asian dust (hereafter called "AD") particles with the aid of the most advanced micro-PIXE (Particle-induced X-ray emission) analytical technique. To this end, size-selected particles were sampled on a rural peninsula of Korea (Byunsan, 35.37N; 126.27E) during AD and non-AD periods in 2004. The coarse particle (> $2{\mu}m$) number density during an AD event were 170 times higher than those of the non-AD counterpart. The average net-count of silica in individual particles collected on AD event was roughly 11 times higher than that of non-AD counterpart. The X-ray net-counts of trace elements (Zn, Co, Mn, and V) were also considerably high in AD relative to the non-AD day. Particle classification based on the inter ratio analysis of elemental net-count suggests that a large portion of the coarse particles collected during AD event underwent chemical transformation to a certain degree. The visual interpretation of micro-PIXE elemental maps and elemental localization data in and/or on individual AD particles clarified the internal mixture of AD particles with sea-salt and artificial metallic particles.

진공 열 플라즈마 용사공정을 통한 NiTiZrSiSn 벌크 비정질 코팅 형성 (Vacuum Plasma Sprayed NiTiZrSiSn Coating)

  • 윤상훈;김준섭;김수기;이창희
    • Journal of Welding and Joining
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    • 제25권4호
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    • pp.42-48
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    • 2007
  • An inert gas atomized NiTiZrSiSn bulk metallic glass feedstock was sprayed onto the copper plate using vacuum plasma spraying process. In order to change the in-flight particle energy, that is, thermal energy, the hydrogen gas flow rate in plasma gas mixture was increased at the constant flow rate of argon gas. Coating and single pass spraying bead were produced with the least feeding rate. Regardless of the plasma gas composition, fully melted through unmelted particle could be observed on the overlay coating. However, the frequency of the unmelted particle number density was increased with the decrease of the hydrogen gas flow rate. The amorphous phase fraction within coating was also affected by the number density of the unmelted particle.

Geometry Optimization of Dispersed U-Mo Fuel for Light Water Reactors

  • Ondrej Novak;Pavel Suk;Dusan Kobylka;Martin Sevecek
    • Nuclear Engineering and Technology
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    • 제55권9호
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    • pp.3464-3471
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    • 2023
  • The Uranium/Molybdenum metallic fuel has been proposed as promising advanced fuel concept especially in the dispersed fuel geometry. The fuel is manufactured in the form of small fuel droplets (particles) placed in a fuel pin covered by a matrix. In addition to fuel particles, the pin contains voids necessary to compensate material swelling and release of fission gases from the fuel particles. When investigating this advanced fuel design, two important questions were raised. Can the dispersed fuel performance be analyzed using homogenization without significant inaccuracy and what size of fuel drops should be used for the fuel design to achieve optimal utilization? To answer, 2D burnup calculations of fuel assemblies with different fuel particle sizes were performed. The analysis was supported by an additional 3D fuel pin calculation with the dispersed fuel particle size variations. The results show a significant difference in the multiplication factor between the homogenized calculation and the detailed calculation with precise fuel particle geometry. The recommended fuel particle size depends on the final burnup to be achieved. As shown in the results, for lower burnup levels, larger fuel drops offer better multiplication factor. However, when higher burnup levels are required, then smaller fuel drops perform better.

반응소결 SiC/Graphite 복합체에서 Graphite 입자의 크기에 따른 마찰마모특성 (Tribological Properties of Reaction-Bonded SiC/Graphite Composite According to Particle Size of Graphite)

  • 백용혁;서영현;최웅;이종호
    • 한국세라믹학회지
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    • 제34권8호
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    • pp.854-860
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    • 1997
  • The tribological property of ceramics is very important for use in seal rings, pump parts, thread guides and mechanical seal, etc. In the present study, which RBSC/graphite composites were manufactured by adding graphite powders with different particle sizes to mixtures of SiC powder, metallic silicon, carbon black and alumina, effects on the tribological property of each RBSC/graphite composite was investigated in accordance with the particle size of the added graphite powder. The water absorption, the bending strength and the resistance for the friction and wear were measured, and the crystalline phase and the microstructure were respectively examined by using XRD and SEM. In case that the particle size of the graphite powder was fine(2${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was accelerated, thereby making the increase of the bending strength and the decrease of the water absorption, but no improvement for the tribological properties. Furthermore, in case that the particle size of the graphite powder was some large(88~149${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was not accelerated, to thereby make the decrease of the bending strength and the increase of the water absorption, but the improvement for the tribological property of only the composite having the graphite powder of 20 vol%. In addition, in case that the particle size distribution of the graphite powder was large (under 53 ${\mu}{\textrm}{m}$), there was no improvement for every properties. However, the composites, which the graphite powder with the particle size of 53~88 ${\mu}{\textrm}{m}$ was added in 10~15 vol%, had the most increased resistance for the friction and wear which show the worn out amount of 0.4~0.6$\times$10-3 $\textrm{cm}^2$, and the value of the bending strength is 380~520 kg/$\textrm{cm}^2$.

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2001년 봄철 서울시 북동부지점에서 관측한 중금속성분의 농도분포 (The Metallic Composition of PM2.5 and PM10 in a Northeast Region of Seoul During the Spring 2001)

  • 최규훈;강창희;김기현
    • 한국지구과학회지
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    • 제23권6호
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    • pp.514-525
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    • 2002
  • 본 연구는 서울시 북동지역의 군자동에 위치한 세종대학교를 중심으로 2001년 봄철 3월에서 4월까지 PM2.5와 PM10을 채취하여, 이들과 결합된 중금속 성분들에 대한 농도분포의 특성을 살펴보았다. 전체 관측기간 동안 산출된 PM2.5, PM10, 조대입자 영역(PM10-PM2.5)의 평균농도는 49.3${\pm}$29.2, 95.5${\pm}$46.1, 50.5${\pm}$35.0 ${\mu}g$/m$^3$으로 나타났다. 연구대상지역의 중금속 오염도를 살펴보기 위해 부화계수(enrichment factor: EF)를 비교한 결과, 미세 및 조대입자 모두에서 Zn, V, Cr, Pb, Cu, Ni, Co, Mo 등의 중금속 성분들의 EF값이 수십, 수백의 범위에 달할 정도로 오염의 수준이 심각하다는 것을 확인할 수 있었다. 미세/조대입자 영역간에 형성되는 농도비를 비교한 결과, Zn, Cr, Pb, Ni 등이 미세입자 영역에서 뚜렷하게 더 높은 농도를 보이는 것으로 확인되었다. 중금속 농도에 대해 보다 세부적인 분석을 실시한 결과, 중금속 성분들의 농도는 상당 수준 증가하는데, 이와 같은 증가는 황사의 영향을 상당 수준 받는 것으로 나타났다.

내부식성과 경량성 향상을 위한 비금속 재질 집진판의 2단 전기집진기 집진효율 연구 (The study on collection efficiency of two-stage electrostatic precipitator using non-metallic electrode for improve corrosion resistance and light weight)

  • 안소희;이예완;김예슬;김용진;한방우;김학준
    • 한국입자에어로졸학회지
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    • 제17권2호
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    • pp.21-27
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    • 2021
  • We developed non-metallic electrodes that can replace metallic electrodes of the electrostatic precipitator(ESP) for the purpose of light weight, corrosion resistance, cost reduction. We manufactured three types of collection electrodes made of stainless steel (M), Carbon ink coating layer-Plastic sheet-Carbon ink coating layer (CPC), and Plastic sheet-Carbon ink coating layer-Plastic sheet (PCP). We studied the collection efficiency of a two-stage ESP using oil mist particles with and without collection stage by changing the flow rate, the material of collection electrode, and the applied voltage of the pre-charger module and the collection module. Here we measured concentrations of particles at diameters of 0.45 ㎛ (CMD; count median diameter) and 3.0 ㎛ (MMD : mass median diameter), as well as PM2.5 and PM10. As a result of the experiment, two-stage ESP had 22~25% higher collection efficiency in PM2.5 than one-stage ESP at the same applied voltage. The difference in collection efficiency by varying the materials of collection electrodes was less than 5%. The weight of the non-metallic electrode was only one eighth the weight of the metal electrode. CPC electrode had a thickness of 0.27 mm, which was 1.5 times thinner than a thickness of PCP electrode, so when the flow rate increased, the CPC electrodes couldn't be kept at equal intervals due to the fluttering unlike PCP electrodes. In addition, the PCP-CPC collection module of the present experiment followed the theoretical efficiency based on Deutsch equation and Cochet's charging theory.

충청남도 태안 교외대기 PM10, PM2.5의 중금속 농도 특성과 기원 추적연구 (A study of origins and characteristics of metallic elements in PM10 and PM2.5 at a suburban site in Taean, Chungchengnam-do)

  • 오상민;윤숙희;박재선;허유정;이수형;유은진;김민섭
    • 한국입자에어로졸학회지
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    • 제19권4호
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    • pp.111-128
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    • 2023
  • Chungcheongnam-do has various emission sources, including large-scale facilities such as power plants, steel and petrochemical industry complexes, which can lead to the severe PM pollution. Here, we measured concentrations of PM10, PM2.5, and its metallic elements at a suburban site in Taean, Chungcheongnam-do from September 2017 to June 2022. During the measurement period, the average concentrations of PM10 and PM2.5 were 58.6 ㎍/m3 (9.6~379.0 ㎍/m3) and 35.0 ㎍/m3 (6.1~132.2 ㎍/m3), respectively. The concentration of PM10 and PM2.5 showed typical seasonal variation, with higher concentration in winter and lower concentration in summer. When high concentrations of PM2.5 occurred, particulary in winter, the fraction of Zn and Pb components considerably increased, indicating a significant contribution of Zn and Pb to high-PM2.5 concentration. In addition, Zn and Pb exhibited the highest correlation coefficient among all other metallic elements of PM2.5. A backward trajectory cluster analysis and CPF model were performed to examine the origin of PM2.5. The high concentration of PM2.5 was primarily influenced by emissions from industrial complexes located in the northeast and northwest areas.

부산지역 $PM_{2.5}$의 이온 및 미량 금속성분의 화학적 특성 (Chemical characteristics of ions and trace metallic element of PM2.5 in Busan metropolitan area)

  • 전보경;서정민;최금찬
    • 한국환경보건학회지
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    • 제27권4호
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    • pp.63-71
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    • 2001
  • PM 2.5/ samples were measured at two sites, Hadan(suburban site) and Anrak (roadside site) in Busan area. PM 2.5/ sampling was performed for 24-hour intervals by the FH9.5 particulate sampler. Aerosol samples were collected on PTFE filter. A total of 60 particulate samples were collected, dad samples were measured for Particulate mass concentration, metallic elements (Cr, Mn, Ni. Cu. Se, Fe, Pb, and Zn) and waer-soluble elements (C $l^{[-10]}$ , N $O_{3}$$^{[-10]}$ ,S $O_{4}$$^{2-}$, N $H_{4}$$^{+}$, $Ca_{2}$$^{+}$, $Mg_{2}$$^{+}$ and $^{+}$.Mass concentration in Hadan ranged 24.23~57.12 $\mu\textrm{g}$/㎥ and 60.22~72.12 $\mu\textrm{g}$/㎥m Yellow Sand Events. Major cations in Hadan and Anrak site is N $H_{4}$$^{+}$and N $a^{+}$ respectively. SO42$^{[-10]}$ was the abundant specie in the PM 2.5 fraction for Hadan site an dAnrak site. Hadan site showed igher concentration in S $O_{4}$$^{2.1}$ and N $H_{4}$ $^{+}$ In Anrak site the concentration of S $O_{4}$/sip 2-/and N $a^{+}$ was higher than other ions Prominent metallic elements were Fe and Pb in two sites. Principal component analysis showed that main source of PM 2.5 aerosol particles was non-metal related source which was resulted in relating elements as Cr, Ni, and Pb at Hadan site, Anrak site also has resulted PM2.5 aerosol paricles source, which was related its element like Zn, and Ni,. The SAS package analysis also showed that long-range transport effect at Hadan area due to Yellow Sand Event by the prevailing weaterlies.ling weaterlies.

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혼합 전도체 $\beta-LiAl$의 전자구조, 결합과 Li 이온 이동에 따른 영향 (Electronic Structure, Bonding and Kithium Migration Effects of the Mixed Conductor $\beta-LiAl$)

  • Jang, Gun-Eik;I.M Curelaru
    • 한국진공학회지
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    • 제5권3호
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    • pp.194-198
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    • 1996
  • Detailed expermental studies of theelectronic structure of the valence and conduction bands of the mixed conductor $\beta$-LiAlindicate that a quasi-gap opens at the Fermi level, and the conduction states are highlylocalized, as opposed to the theoretical band structure calculations that predict predominant metallic behavior. Evidence for complex lithium migration effects involving the surface of Lial , induced by particle (electron or ion) bombardment and mechanical treatment , has been obtained as a byproduct of these experiments.

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