• 제목/요약/키워드: Metallic element

검색결과 273건 처리시간 0.024초

한국 서해남부 조간대 표층 퇴적물의 지화학적 특성 (Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea)

  • 황동운;류상옥;김성길;최옥인;김성수;고병설
    • 한국수산과학회지
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    • 제43권2호
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    • pp.146-158
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    • 2010
  • In order to evaluate the characteristics of sediments and pollution by organic matter and metallic elements in intertidal sediments along the southwestern coast of Korea, we measured various geochemical parameters, including the mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and metallic elements (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, As), in intertidal surface sediments. The Mz of the surface sediments ranged from 2.1 to 8.3$\phi$, indicating that the surface sediments consist of various sedimentary facies, such as sand, slightly gravelly mud, sandy mud, and silt. The IL and COD in surface sediment ranged from 0.8 to 5.5% (mean $2.9\pm1.2%$) and from 3.9 to $13.8\;mgO_2/g{\cdot}dry$ (mean $8.5\pm2.6\;mgO_2/g{\cdot}dry$), respectively, which were lower than the values for surface sediment in areas near fish and shellfish farms or industrial complexes. No AVS was detected at any sampling station, despite various sedimentary facies. Most of metallic elements in surface sediments showed relatively good positive correlations with Mz and IL, which imply that the concentrations of metallic elements are mainly controlled by grain size and the organic matter content. The concentrations of metallic elements, except As, at some stations were considerably lower than those in the Sediment Quality Guideline (Effect Range Low, ERL) proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Similarly, the geoaccumulation index (Igeo) class indicated that pollution by metallic elements in intertidal surface sediment, except As, was moderate or non-existent. Our results imply that the intertidal surface sediments along the southwestern coast of Korea are not polluted by organic matter and metallic elements and are healthy for benthic organisms.

등가형상을 이용한 딤플형 금속 샌드위치 판재의 효율적 굽힘 거동 예측 (Efficient Methods of Prediction Incorporating Equivalent Models for Elasto-Plastic Bending Behavior of Metallic Sandwich Plates with Inner Dimpled Shell Structure)

  • 성대용;정창균;윤석준;양동열
    • 소성∙가공
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    • 제14권8호통권80호
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    • pp.718-724
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    • 2005
  • An efficient finite element method has been introduced for analysis of metallic sandwich plates subject to bending moment. A full model 3-point bending FE-analysis shows that the plastic behavior of inner structures appears only at the load point. The unit structures of sandwich plates are defined to numerically calculate the bending stiffness and strength utilizing the recurrent boundary condition for pure bending analysis. The equivalent models with the same bending stiffness and strength of full models are then designed analytically. It is demonstrated that the results of both models are almost the same and the FE-analysis method incorporating the equivalent models can reduce the computation time effectively. The dominant collapse modes are face buckling and face yielding. Since the inner dimpled structures prevent face buckling, sandwich plates with inner dimpled shell structure can absorb more energy than other types of sandwich plates during the bending behavior.

OenNen-Styrene DVB 합성수지에 의한 U(VI), Fe(II), Sm(III) 이온들의 흡착 (Adsorption of U(VI), Fe(II), Sm(III) Ions on OenNen-Styrene DVB Synthetic Resin)

  • 이치영;김준태
    • 환경위생공학
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    • 제22권3호
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    • pp.77-87
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    • 2007
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 3%, and 5%-crosslinking and macro cyclic ligand of OenNen-$H_4$ by copolymerization method and the adsorption characteristics of uranium(VI), iron(II) and samarium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium ${UO_2}^{2+}>Fe^{2+}>Sm^{3+}$ ion. The adsorption was in order of 1%, 3%, and 5% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvent.

OenNdien수지에 의한 금속 이온의 흡착 (Adsorption of Metal Ions on OenNdien Resin)

  • 강영식;노기환;김준태
    • 환경위생공학
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    • 제20권3호
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    • pp.27-35
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    • 2005
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

질소-주게 합성수지를 이용한 U(VI), Cu(II), Dy(III) 이온들의 흡착특성 (Adsorption Characteristic of U(VI), Cu(II), Dy(III) Ions Utilizing Nitrogen-Donator Synthetic Resin)

  • 노기환;김준태;김희정
    • 환경위생공학
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    • 제21권3호
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    • pp.52-60
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    • 2006
  • The ion exchange resins have been synthesized from chlormethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, and 20%-crosslinking and macrocyclic ligand of cryptand 21 by copolymerization method and the adsorption characteristics of uranium(VI), copper(II) and dysprosium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, equilibrium time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium$(UO^{2+}_2)\;>\;copper(Cu^{2+})\;>\;dysprosium(Dy^{3+})$ ion. The adsorption was in order of 1%, 2%, and 20% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Study on Chemical Characterization of $PM^{10}$ Observed in Korean Peninsula, 1998 ~ 2001

  • Bang, So-Young;Oh, S.N.;Choi, J.C.;Choi, B.C
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.61-64
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    • 2003
  • This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

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금속분리판을 이용한 무인기항공기(UAV)용 경량화 DMFC 스택 개발 (Development of Lightweight Direct Methanol Fuel Cell (DMFC) Stack Using Metallic Bipolar Plates for Unmanned Aerial Vehicles (UAVs))

  • 이수원;김도환;노정호;조영래;김도연;주현철
    • 한국수소및신에너지학회논문집
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    • 제28권5호
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    • pp.492-501
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    • 2017
  • A 900 W scale direct methanol fuel cell (DMFC) stack is designed and fabricated for unmanned aerial vehicle (UAV) applications. To meet the volume and weight requirements, metallic bipolar plates are applied to the DMFC stack for the first time wherein POS470FC was chosen as bipolar plate material. To ensure good robustness of the metallic bipolar plate based DMFC stack, finite element method based simulations are conducted using a commercial ANSYS Fluent software. The stress buildup and deformation characteristics on bipolar plates and end plates are analyzed in details. The present DMFC stack exhibits the performance of 1,130 W at 32 V and 35.3 A, clearly demonstrating that it could successfully operate for UAVs requiring around 1,000 W of power.

Cyclic Behavior of Timber Column Concealed Base Joint

  • Humbert, Jerome;Lee, Sang-Joon;Park, Joo-Saeng;Park, Moon-Jae
    • Journal of the Korean Wood Science and Technology
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    • 제41권2호
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    • pp.123-133
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    • 2013
  • This paper presents experimental and numerical tests on a recently developed timber column concealed base joint. This joint was designed to replace the wood-wood connection found in the post-and-beam structure of Hanok, the traditional Korean timber house. The use of metallic connectors provides an increased ductility and energy dissipation for a better performance under reversed loading, especially seismic. In this study, we investigate the performance of the joint under pseudo-static reversed cyclic moment loading through the study of its ductility and energy dissipation. We first perform experimental tests. Results show that the failure occurs in the metallic connector itself because of stress concentrations, while no brittle fracture of wood occur. Subsequent numerical simulations using a refined finite element model confirm these conclusions. Then, using a practical modification of the joint configuration with limited visual impact, we improve the ductility and energy dissipation of the joint while retaining a same level of rotational strength as the originally designed configuration. We conclude that the joint has a satisfying behavior under reversed moment loading for use in earthquake resistant timber structure in low to moderate seismicity areas like Korea.

Development of Structural Analysis Modeling for KALIMER Fuel Rod

  • Kang, Hee-Young;Cheol Nam;Woan Hwang
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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    • pp.175-180
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    • 1998
  • The U-Zr metallic alloy with low swelling HT9 cladding is the candidate for the KALIMER fuel rod. The fuel rod should be able to maintain the structural integrity during its lifetime in the reactor. In a typical metallic fuel rod, load is mainly applied by internal gas pressure, and the deformation is primarily caused by creep of the cladding. The three-dimensional FEM modelling of a fuel rod is important to predict the structural behavior in concept design stage. Using the ANSYS code, the 3-D structure analyses were performed for various configuration, element and loads. It has been shown that the present analysis model properly evaluate the structural integrity of fuel rod. The present analysis results show that the fuel rod is expected to maintain its structural integrity during normal operation.

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알루미늄 합금의 성분원소가 절삭 특성에 미치는 영향 (Effect of Machining Characteristics Aluminium Alloy added Composition Elements)

  • 채왕석;김경우;최현민;김동현
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 추계학술대회 논문집
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    • pp.857-860
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    • 1997
  • The purpose of this research was to study the influence of machining characteristics for aluminum alloys. The effect of metallic microstructural variables on the measures of machinability of aluminum alloys has no been adequately investigated. Machining Characteristics are influenced significantly by mechanical characteristics, composition and structure of material etcs. For improvement of machining characteristics, various studies are reported. In this paper, composition elements add to aluminum alloys within the limit of sustaining mechanical characteristics of metallic material. We have analyzed dynamic characteristics of cutting resistance, tensile strength value, hardness value etcs.

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