• 제목/요약/키워드: Metallic Glasses

검색결과 52건 처리시간 0.019초

Ge-Se-Te계 칼코지나이드 유리의 결정 생성 현상 및 특성 (Properties and Crystallization Characteristics of Ge-Se-Te Glasses)

  • 이용우;허종
    • 한국세라믹학회지
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    • 제32권2호
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    • pp.239-247
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    • 1995
  • Chalcogenide glasses with compositions of Ge10Se90-xTex(X=0~50 at.%) were prepared in order to investigate the effects of Te substitution on the transmission characteristics of Ge-Se glasses in the 8~12 ${\mu}{\textrm}{m}$ wavelength region. Absorption coefficients were observed to decrease with Te addition, indicating the improved transmission capabilities of Ge-Se-Te glasses as compared to binary Ge-Se glasses. XRD analysis of crystallized glasses suggested the formation of weaker Se-Te and/or Te-Te bonds with addition of Te substituting for Se in stronger Se-Se bonds. Incorporation of Te in excess of 20at% resulted in the formation of hexagonal Te phases when crystallized. It is speculated that the presence of Te-Te bonds with highly metallic bond character resulted in the enhanced crystallization tendencies of glasses. Fromation of Te-rich chains through gradual replacement of Se-Se with Se-Te and/or Te-Te bonds was further supported by decreases in glass transition and crystallization temperatures.

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대기 플라즈마 용사공정을 이용한 Fe계 벌크 비정질 금속 코팅의 초기 분말의 화학조성과 크기에 대한 미세 조직 및 마모 특성 (Microstructure and Tribological Properties along with Chemical Composition and Size of Initial Powder in Fe-based BMG Coating through APS)

  • 김정환;윤상훈;나현택;이창희
    • 한국표면공학회지
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    • 제41권5호
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    • pp.220-225
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    • 2008
  • In this study, two kinds of Fe-based bulk metallic glasses (BMG) powder were built-up through atmospheric plasma spray (APS) technique. The microstructure of two coatings was analyzed through X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Crystallization and oxidation in coatings were affected by chemical composition and initial powder size. Then, both of them influenced the tribological property.

Magnetically Soft Nanomaterials Obtained by Devitrification of Metallic Glasses

  • Kulik, Tadeusz;Ferenc, Jaroslaw;Kowalczyk, Maciej;Xiubing, Liang;Nedelko, Natalya
    • Journal of Magnetics
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    • 제9권2호
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    • pp.65-68
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    • 2004
  • Magnetically soft nanomaterials obtained by controlled crystallisation of metallic glasses are the newest group of materials for inductive components. In particular, research is carried out in the field of alloys for high temperature applications. This kind of materials must meet two basic requirements: good magnetic properties and stability of properties and structure. In the present work the magnetic properties and structure of Fe-Co-Hf-Zr-Cu-B (HIDTPERM-type) alloys were investigated, as well as their stability. Differential thermal analysis, (DTA), X-ray diffractometry (XRD), transmission electron microscopy (TEM), magnetometry (VSM) and quasistatic hysteresis loop recording were used to characterise structure and properties of the alloys investigated. Optimisation against properties and their stability was performed, resulting in formulation of chemical composition of the optimum alloy, as well as its heat treatment.

비정질 재료 변형 해석을 위한 가중보로노이법 (Weighted Voronoi Analysis for Deformation of Metallic Glasses)

  • 박준영
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2011년도 정기 학술대회
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    • pp.292-293
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    • 2011
  • 보로노이 다면체 기법은 금속비정질재료에서의 20면체 Short-Range order와 같은 원자 구조를 분석하는 가장 유용한 도구 중에 하나이다. 기존의 보로노이 다면체 기법에서는 다면체의 평면은 다른 크기를 가진 원자간 거리의 중간에 위차하였다. 하지만, 이러한 방법은 필연적으로 분석 오차를 발생시킨다. 대안적인 방법으로서 근평면법이라고 불리우는 가중 보로노이법을 사용하면, 원자의 크기의 차이를 고려하여 해석할 수 있다. 본논문에서는 이러한 근평면법을 여러 가지의 성분비를 가진 비정질 재료에 적용하여 기존의 보로노이법과 비교 분석하였다. 결과적으로 보로노이 인덱스, 원자체적 분포, 보로노이 다면체 분포, 20면체의 공간 분포등등에서 기존의 보로노이법은 완전히 잘못된 결과를 보여줄 수도 있다는 것이 발견되었다.

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저온 분사 코팅 공정에서 충돌속도에 따른 CuNiTiZr 벌크 비정질 소재의 활성화 에너지와 결정화 거동 분석 (Effects of Impact Velocity on Crystallization and Activation Energy of Cu-based Bulk Metallic Glasses in Kinetic Spray Coating)

  • 윤상훈;배규열;김정환;이창희
    • 한국표면공학회지
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    • 제41권6호
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    • pp.301-307
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    • 2008
  • In this paper, nanocrystallization of CuNiTiZr bulk metallic glass (BMG) subjecting to a kinetic spraying, dependent on impact velocity, was investigated by numerical and experimental approaches. The crystallization fraction and nucleation activation energy of initial feedstock and as-deposited coating were estimated by DSC and Kissinger method, respectively. The results of numerical modeling and experiment showed that the crystalline fraction and nucleation activation energy in BMG coatings were depended on kinetic energy of incident particle. Upon impact, the conversion of particle kinetic energy leads to not only decreasing free energy barrier but also increasing the driving force for an amorphous to crystalline phase transformation. The nanocrystallization of BMGs is associated with the strain energy delivered by a plastic deformation with a high strain rate.

Soft Magnetic Properties of Ring-Shaped Fe-Co-B-Si-Nb Bulk Metallic Glasses

  • Ishikawa, Takayuki;Tsubota, Takahiro;Bitoh, Teruo
    • Journal of Magnetics
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    • 제16권4호
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    • pp.431-434
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    • 2011
  • The reduction of the Nb content in the $(Fe_{0.75}B_{0.20}Si_{0.05})_{96}Nb_4$ bulk metallic glass (BMG) has been studied. The glass-forming ability (GFA) is reduced by decreasing the Nb content, but it can be enhanced by replacing partially Fe by Co. Furthermore, the saturation magnetization of the $(Fe_{0.8}Co_{0.2})_{76}B_{18}Si_3Nb_3$ BMG is 1.35 T, being with 13% larger than that of the base alloy $(Fe_{0.75}B_{0.20}Si_{0.05})_{96}Nb_4$. $(Fe_{0.8}Co_{0.2})_{76}B_{18}Si_3Nb_3$ BMG exhibits slightly larger $B_{800}$ (the magnetic flux density at 800 A/m) and smaller core losses (20%-30%) compared with the commercial Fe-6.5 mass% Si steel.

인공신경망을 이용한 벌크 비정질 합금 소재의 포화자속밀도 예측 성능평가 (Artificial Neural Network Supported Prediction of Magnetic Properties of Bulk Metallic Glasses)

  • 남충희
    • 한국재료학회지
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    • 제33권7호
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    • pp.273-278
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    • 2023
  • In this study, based on the saturation magnetic flux density experimental values (Bs) of 622 Fe-based bulk metallic glasses (BMGs), regression models were applied to predict Bs using artificial neural networks (ANN), and prediction performance was evaluated. Model performance evaluation was investigated by using the F1 score together with the coefficient of determination (R2 score), which is mainly used in regression models. The coefficient of determination can be used as a performance indicator, since it shows the predicted results of the saturation magnetic flux density of full material datasets in a balanced way. However, the BMG alloy contains iron and requires a high saturation magnetic flux density to have excellent applicability as a soft magnetic material, and in this study F1 score was used as a performance indicator to better predict Bs above the threshold value of Bs (1.4 T). After obtaining two ANN models optimized for the R2 and F1 score conditions, respectively, their prediction performance was compared for the test data. As a case study to evaluate the prediction performance, new Fe-based BMG datasets that were not included in the training and test datasets were predicted using the two ANN models. The results showed that the model with an excellent F1 score achieved a more accurate prediction for a material with a high saturation magnetic flux density.