• Title/Summary/Keyword: Metal-Loading

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Platinum-Catalyzed and Ion-Selective Polystyrene Fibrous Membrane by Electrospinning and In-Situ Metallization Techniques

  • Hong, Seung-Hee;Lee, Sun-Ae;Nam, Jae-Do;Lee, Young-Kwan;Kim, Tae-Sung;Won, Sung-Ho
    • Macromolecular Research
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    • v.16 no.3
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    • pp.204-211
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    • 2008
  • A platinum-catalyzed polyelectrolyte porous membrane was prepared by solid-state compression of electrospun polystyrene (PS) fibers and in-situ metallization of counter-balanced ionic metal sources on the polymer surface. Using this ion-exchange metal-polymer composite system, fiber entangled pores were formed in the interstitial space of the fibers, which were surrounded by sulfonic acid sites ($SO_3^-$) to give a cation-selective polyelectrolyte porous bed with an ion exchange capacity ($I_{EC}$) of 3.0 meq/g and an ionic conductivity of 0.09 S/cm. The Pt loading was estimated to be 16.32 wt% from the $SO_3^-$ ions on the surface of the sulfonated PS fibers, which interact with the cationic platinum complex, $Pt(NH_3)_4^{2+}$, at a ratio of 3:1 based on steric hindrance and the arrangement of interacting ions. This is in good agreement with the Pt loading of 15.82 wt% measured by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The Pt-loaded sulfonated PS media showed an ionic conductivity of 0.32 S/cm. The in-situ metallized platinum provided a nano-sized and strongly-bound catalyst in robust porous media, which highlights its potential use in various electrochemical and catalytic systems.

Evaluation of two interforaminal implants and implant-assisted removable dentures on stress distribution: an in vitro study

  • Bilhan, Selda Arat;Geckili, Onur;Cilingir, Altug;Bozdag, Ergun;Bilhan, Hakan
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.45 no.4
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    • pp.199-206
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    • 2019
  • Objectives: In mandibular edentulism, the treatment option with a two-interforaminal implant-retained bridge and a removable partial denture is rarely evaluated in literature. The aim of this in vitro study was to evaluate the stress distribution of this treatment option by comparing it with traditional treatment options with interforaminal implants in the edentulous mandible. Materials and Methods: Two interforaminal implants were placed in a formalin-fixed cadaver mandible, and overdentures with three different types of attachments were fabricated: (1) two ball attachments and an overdenture, (2) a Dolder bar and an overdenture, and (3) screw-retained two-implant inter-canine porcelain fused to a metal bridge and an implant-assisted removable denture (IARD) with precision attachments. Three biting conditions were generated for each denture type, and the strains were documented under vertical loading of 100 N. Results: The calculated strain values from measured strains in all measurement sites and loading conditions for the screw-retained two-implant intercanine porcelain fused to a metal bridge and a cast framework partial denture with precision attachments situation were lower than in the other scenarios (P<0.05). Conclusion: Within the limitations of the present study, it can be concluded that an IARD may be a reasonable and valuable alternative to ball attachments or a bar in two interforaminal implants, especially when the patients prefer to be able to show their teeth even when they take out their removable dentures.

Analysis of Mechanical Properties of Wood Flours Composites to Improve the Strength of Truck Deck Floor Boards (트럭 Deck Floor Board의 강도향상을 위한 목분복합재의 기계적특성 분석)

  • Yun, Sung-Woo;Go, Sun-Ho;Kim, Hong-Gun;Kwac, Lee-Ku
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.1
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    • pp.24-30
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    • 2019
  • The deck floor of a the cargo truck becomesis damaged and aged due to the continuous loading of the loading cargo and external environmental factors. Floor boards made of wood and metal are often used. In the case of wood, the cost is high due to the use of imported wood, and the strength is easily deterioratesd due to environmental factors. In the case of metal materials, the durability is higher than that of wood, but problems are raised due to the effect of major factors that hinder the weight reduction, and the effects of corrosion. In order to replace this stucturestructural design, this study proposed a wood fiber composite using natural raw materials. Woody composites are being used as environmentally and friendly exterior materials with the combined advantages of plastic, and wood,; low cost and low density. However, due to the nature of the woody composites, the properties are differentdiffer depending on the contents of the matrix, reinforcing agent, additives, compatibilizer, etc. In this study, we investigate these problems through analysis of the microstructure and mechanical properties according to proper content and injection molding conditions. As a result, it is considered that the wood deck composite can replaced the current Deck Floor Boardreplace current deck floor boards through continuous continued research and results of this study.

Enhancing the performance of a long-life modified CANDLE fast reactor by using an enriched 208Pb as coolant

  • Widiawati, Nina;Su'ud, Zaki;Irwanto, Dwi;Permana, Sidik;Takaki, Naoyuki;Sekimoto, Hiroshi
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.423-429
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    • 2021
  • The investigation of the utilization of enriched 208Pb as a coolant to enhance the performance of a long-life fast reactor with a Modified CANDLE (Constant Axial shape of Neutron flux, nuclide densities, and power shape During Life of Energy production) burnup scheme has performed. The analyzes were performed on a reactor with thermal power of 800 MegaWatt Thermal (MWTh) with a refueling process every 15 years. Uranium Nitride (enriched 15N), 208Pb, and High-Cr martensitic steel HT-9 were employed as fuel, coolant, and cladding materials, respectively. One of the Pb-nat isotopes, 208Pb, has the smallest neutron capture cross-section (0.23 mb) among other liquid metal coolants. Furthermore, the neutron-producing cross-section (n, 2n) of 208Pb is larger than sodium (Na). On the other hand, the inelastic scattering energy threshold of 208Pb is the highest among Na, natPb, and Bi. The small inelastic scattering cross-section of 208Pb can harden the neutron energy spectrum. Therefore, 208Pb is a better neutron multiplier than any other liquid metal coolant. The excess neutrons cause more production than consumption of 239Pu. Hence, it can reduce the initial fuel loading of the reactor. The selective photoreaction process was developing to obtain enriched 208Pb. The neutronic was calculated using SRAC and JENDL 4.0 as a nuclear data library. We obtained that the modified CANDLE reactor with enriched 208Pb as coolant and reflector has the highest k-eff among all reactors. Meanwhile, the natPb cooled reactor has the lowest k-eff. Thus, the utilization of the enriched 208Pb as the coolant can reduce reactor initial fuel loading. Moreover, the enriched 208Pb-cooled reactor has the smallest power peaking factor among all reactors. Therefore, the enriched 208Pb can enhance the performance of a long-life Modified CANDLE fast reactor.

Wind resistance performance of a continuous welding stainless steel roof under static ultimate wind loading with testing and simulation methods

  • Wang, Dayang;Zhao, Zhendong;Ou, Tong;Xin, Zhiyong;Wang, Mingming;Zhang, Yongshan
    • Wind and Structures
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    • v.32 no.1
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    • pp.55-69
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    • 2021
  • Ultrapure ferritic stainless steel provides a new generation of long-span metal roof systems with continuous welding technology, which exhibits many unknown behaviors during wind excitation. This study focuses on the wind-resistant capacity of a new continuous welding stainless steel roof (CWSSR) system. Full-scale testing on the welding joints and the CWSSR system is performed under uniaxial tension and static ultimate wind uplift loadings, respectively. A finite element model is developed with mesh refinement optimization and is further validated with the testing results, which provides a reliable way of investigating the parameter effect on the wind-induced structural responses, namely, the width and thickness of the roof sheeting and welding height. Research results show that the CWSSR system has predominant wind-resistant performance and can bear an ultimate wind uplift loading of 10.4 kPa without observable failures. The welding joints achieve equivalent mechanical behaviors as those of base material is produced with the current of 65 A. Independent structural responses can be found for the roof sheeting of the CWSSR system, and the maximum displacement appears at the middle of the roof sheeting, while the maximum stress appears at the connection supports between the roof sheeting with a significant stress concentration effect. The responses of the CWSSR system are greatly influenced by the width and thickness of the roof sheeting but are less influenced by the welding height.

Effect of various abutment systems on the removal torque and the abutment settling in the conical connection implant systems (원추형 연결 임플란트에서 지대주 종류에 따른 나사풀림과 침하현상에 관한 연구)

  • Lee, Jin-Seon;Lee, Joon-Seok
    • The Journal of Korean Academy of Prosthodontics
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    • v.50 no.2
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    • pp.92-98
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    • 2012
  • Purpose: The aim of this study was to evaluate the effects of different abutment materials on abutment screw loosening and settling-down effect in conical connection type implant system. Materials and methods: Three types of abutment, cementation, gold UCLA, and metal UCLA abutment were used. Two UCLA groups were fabricated in a similar pattern to cementation abutment. Type III gold alloy and Nickel-Chromium alloy was used for casting gold UCLA abutment and metal UCLA abutment, respectively. Fixture and abutment were tightened to 30 Ncm by using digital torque controller and re-tightening was conducted with same force after 10 minutes. Digital torque gauge was used to measure loosening torque and fixture/abutment length was measured by digital micrometer. Dynamic loads between 25 N and 250 N were applied with $0^{\circ}$ angle to the abutment axis. After loading, fixture/abutment length was re-measured and amount of settlement was calculated. Loosening torque value was also measured for comparison Results: All three groups showed significant differences of length when comparing before and after loading, but there was no significant difference of settling amount in all groups. Loosening torque values were significantly decreased when comparing before and after loading in all groups($P$<.05). However, there was no significant difference in loss of loosening torque values when compared to groups. Conclusion: In internal conical connection type implants, dynamic load affected on settlement and loosening torque of implant, but there was no differences between abutments materials. Likewise gold UCLA abutment, metal UCLA abutment might be able to withstand functional load.

Elastic-Plastic Stress Distributions Behavior in the Interface of SiC/Ti-15-3 MMC under Transverse Loading(II) (횡하중을 받는 SiC/Ti-15-3 MMC 복합재 계면영역에서의 탄소성 응력장분포거동(II))

  • Kang Ji-Woong;Kwon Oh-Heon
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.26-31
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    • 2005
  • The strong continuous fiber reinforced metal matrix composites (MMCs) are recently used in aerospace and transportation applications as an advanced material due to its high strength and light weight. Unidirectional fiber-metal matrix composites have superior mechanical properties along the longitudinal direction. However, the applicability of continuous fiber reinforced MMCs is somewhat limited due to their relatively poor transverse properties. Therefore, the transverse properties of MMCs are significantly influenced by the properties of the fiber/matrix interface. In order to be able to utilize these MMCs effectively and with safety, it must be determined their elastic plastic behaviors at the interface. In this study, the interfacial stress states of transversely loaded unidirectional fiber reinforced metal matrix composites investigated by using elastic-plastic finite element analysis. Different fiber volume fractions $(5-60\%)$ were studied numerically. The interlace was treated as three thin layer (with different properties) with a finite thickness between the fiber and the matrix. The fiber is modeled as transversely isotropic linear-elastic, and the matrix as isotropic elastic-plastic material. Using proposed model, the effects of the interface region and fiber arrangement in MMCs on the distributions of stress and strain are evaluated. The stress distributions of a thin multi layer interface have much less changes compared with conventional perfect interface. The analyses were based on a two-dimensional generalized plane strain model of a cross-section of an unidirectional composite by the ANSYS finite element analysis code.

Studies of Valve Lifter for Automotive Heavy Duty Diesel Engine by Ceramic Materials I. Developmet of Ceramic-Metal Joint by Brazing Method (Ceramic 재질을 이용한 자동차용 대형 디젤 엔진 Valve Lifter 연구 I. Brazing Process에 의한 Ceramic-Metal 접합체 개발)

  • 윤호욱;한인섭;임연수;정윤중
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.163-171
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    • 1998
  • Continuously contacting with camshaft the face of Valve Lifter made of cast iron brings about abnormal wear such as unfairwear or earlywear because it is heavily loaded in the valve train systems as the engine gets more powered. This abnormal wear becomes a defet namely over-clearance when the valve is lifting so that the fuel gas imperfectly combusted by unsuitable open or close aaction of the engine valve in the combustion chamber. The imperfect combustion in the end results in the major cause of air pollution and combustion chamber. The imperfectly combusted by unsuitable open or close action of the engine valve in the combustion chamber. The imperfect combustion in the end results in the major causes of air pollution and decrease of the engine output. Consequently to prevent this wear this study was to develop the valve lifter which is joined by brazing process with SCM435H and a tip by manufacturing the face as a superhardened which is joined by brazing process with SCM435H and a tip by manufacturing the face as a superhardened ceramics alloy which has high wear resistance. Having the excellent surface hardness with Hv1100-1200 the sintered body developed with superhardened alloy(WC) can endure the severe face loading in the valve train system. We experienced with various brazing alloys and obtained the excellent joining strength to the joint had 150MPa shear strength. Interface analysis and microstructure in a joint were examined through SEM & EDS Optical microscope. Also 2,500 hours high speed(3,000-4,000 rpm) and continuous (1step 12hr) engine dynamo testing was carried out to casting valve liter and ceramics-metal joint valve lifter so that the abnormal wears were compared and evaluated.

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A Study on the Behavior of Class 900 Flange Joints with Metal Ring Gaskets (금속 링 개스킷이 삽입된 Class 900 플랜지 조인트의 거동에 관한 연구)

  • Lee, Min-Young;Jeong, Doo-Hyung;Kim, Byung-Tak
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.1
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    • pp.34-41
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    • 2018
  • A flange joint is a pipe connection used to prevent the leakage of high-pressure fluids by inserting a gasket and tightening the bolts. Among several kinds of gaskets available, metal ring type joint gaskets are most widely used in conditions that require high-temperature and high-pressure fluid flow, such as oil pipelines, gas pipes, pumps, valve joints, etc. The purpose of this study is to investigate the contact pressure and stress characteristics closely related to the sealing performance of Class 900 flange joints used in high temperature and high pressure environments. The dimensions of flange joints with five different nominal pipe sizes were determined with reference to those specified in ASME 16.5. The metal ring gaskets inserted in the joints were octagonal and oval gaskets. The bolt tensile forces calculated from the tightening torques were input as the bolt pretension loads in order to determine the contact pressure and stress levels after fastening. Loading was composed of three steps, including the fastening step, and different amounts of applied pressures were used in each analysis to investigate the effect of fluid pressure on the contact force of the joints. A general-purpose software, ANSYS 17.2, was used for the analysis.

Adsorption of Ni(II), Co(II), and Mg(II) from Sulfuric Acid Solution by Diphonix Resin for the Utilization of Laterite Ore (라테라이트광 활용을 위한 황산용액에서 Diphonix 수지의 니켈, 코발트, 마그네슘 흡착)

  • Lee, Man-Seung;Kim, Sang-Bae;Chae, Jong-Gwee
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.3
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    • pp.183-189
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    • 2010
  • It is of importance to separate Ni(II) and Co(II) from Mg(II) in solution which was leached from nickel laterite ore. In order to investigate the possibility of separating Ni(II) and Co(II) from Mg(II), adsorption behavior of the three metals from individual and mixed sulfate solutions was investigated by using Diphonix resin. The concentration of each metal in solution was fixed at 100 ppm and the pH of the sulfuric acid solution was changed from 5 to 7. At ambient temperature, the adsorption behavior of the three metal ions followed Langmuir adsorption isotherm. The loading capacity of Diphonix resin for the three metal ions was obtained from the Langmuir isotherm. Since adsorption behavior of the three metal ions from the mixed solution was similar to each other, it was found to be difficult to separate Ni(II) and Co(II) from Mg(II) by using Diphonix resin.