• Journal of the Korean Applied Science and Technology
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• v.22 no.3
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• pp.219-227
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• 2005

Competitive solvent extraction of the mixure of alkali metal and alkaline earth cation from water into organic solvent containing the crown ether carboxylic acid and anlogous crown ether phosphonic acid was investigated as follows. The lipophilic group is found to strongly influence to the selective extraction in the mixed systems from only alkali metal cation for sym-(n-decyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ to mostly alkaline earth metal cation for sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxyacetic acid $\underline{3}$. Monoethyl sym-(n-decyldibenzo)-16-crown-5-oxymethylphosphonic acid $\underline{2}$. and monoethyl-sym- bis]4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{4}$ showed good selectivity for $Na^+$ over $Mg^{2+}$, the second extracted ion. Structural variation in the crown ether phosphonic acid somewhat was influenced to the extraction selectivity in the mixed systems. when variation of the ionized group is influenced in the mixed systems, the selectivity of $Na^+$ as the second extracted ion was much better crown ether carboxylic acid $\underline{1}$ than crown ether phosphonic acid $\underline{2}$, while the efficiency of $Na^+$ extraction was better $\underline{2}$ (83% total loading) than $\underline{1}$ (32%).

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.421-430
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• 2023

Fe-Ni-Pt nanocatalysts were loaded on carbon black powders which were synthesized by a spontaneous reduction reaction of iron (II) acetylacetonate, nickel (II) acetylacetonate and platinum (II) acetylacetonate. The morphology and the loading weight of Fe-Ni-Pt nanoparticles were characterized by transmission electron microscopy and thermogravimetric analyzer. The amount of Fe-Ni-Pt catalyst supported on the carbon black surface was about 6.42-9.28 wt%, and the higher the Fe content and the lower the Pt content, the higher the total amount of the metal catalyst supported. The Brunauer-Emmett-Teller Analysis (BET) specific surface area of carbon black itself without metal nanoparticles supported was 233.9 m²/g, and when metal nanoparticles were introduced, the specific surface area value was greatly reduced. This is because the metal nanocatalyst particles block the pore entrance of the carbon black, and thereby the catalytic activity of the metal catalysts generated inside the pores is reduced. From the I-V curves, as the content of the Pt nanocatalyst increased, the electrolytic properties of water increased, and the activity of the metal nanocatalyst was in the order of Pt > Ni > Fe.

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2711-2716
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• 2014

The high content of potassium in molasses limits its usage as a raw material for stock feed. Moreover, its high viscosity makes it difficult to develop an efficient removal process. In this study, ion exchange and solvent extraction experiments have been performed to investigate the removal of potassium from a mixture of molasses with water. Cationic exchange resins (AG50W-X8 and Diphonix) showed a high loading percentage of potassium but the occurrence of breakthrough in few bed volumes was a drawback to the industrial application. Among the cationic extractants (D2EHPA, PC 88A, Cyanex 272) tested in this study, saponified PC 88A was found to be the best extractant for the removal of potassium. Batch simulation studies on a three stage counter current extraction confirmed that 85% of potassium was removed from 50 wt % molasses solution in water by using saponifed PC 88A.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.144-148
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• 2001

A proper estimation of the mechanical properties for composites has been required for better design/selection of constituents for composite materials. Present investigation shows the simulation results for ceramic reinforced metal matrix composite under uniaxial transverse tensile loading. The resulting transverse mean stress with the transverse mean strain was described for composites as a function of the volume fraction with two different types of interfacial bonding: (1)strongly bonded interface, and (2)no bonded interface. A two-dimensional finite element modeling and analysis were conducted based on the unit-cell concept with an assumption of a regular square arrangement of the reinforcement within the composite. The mean stress was generally increased with the ceramic volume fraction for composite with strong interface bonding. The micromechanics concept combined with finite element modeling for composite can be used in order to predict the transverse properties of composites with a priori known properties of constituents.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2004.04a
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• pp.504-507
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• 2004

Previous studies on the liquid Gallium ion sources used an electro-chemically etched tungsten wire with a coil-type heater. Such a structure requires excessive power consumption in the course of heating the liquid metal. In this work, a new structure is proposed that replaces the coil-type heater. It uses a Gallium reservoir made of six pre-etched 250 $\mu\textrm{m}$ tungsten wires that surround the needle electrode. Gallium loading at the reservoir is observed to be much more stable, resulting in an improved beam stability.

• Transactions of Materials Processing
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• v.12 no.1
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• pp.49-59
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• 2003

To reduce the cost of finite element analyses for sheet forming, a 3D hybrid membrane/shell method has been developed to study the springback of anisotropic sheet metals. In the hybrid method, the bending strains and stresses were analytically calculated as post-processing, using incremental shapes of the sheet obtained previously from the membrane finite element analysis. To calculate springback, a shell finite element model was used to unload the final shape of the sheet obtained from the membrane code and the stresses and strains that were calculated analytically. For verification, the hybrid method was applied to predict the springback of a 2036-T4 aluminum square blank formed into a cylindrical cup. The springback predictions obtained with the hybrid method was in good agreement with results obtained using a full shell model to simulate both loading and unloading and the experimentally measured data. The CPU time saving with the hybrid method, over the full shell model, was 75% for the punch stretching problem.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.479-482
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• 2004

The behavior of fatigue delamination in a GLARE(Glass Fiber Reinforced Metal Laminates) under fatigue loading conditions investigated. The behavior of fatigue delamination was examined basing on investigation of the crack and delamination using a SAM (Scanning Acoustic Microscope). The crack and delamination behavior on the relationship among a-N, SAM images and crack length-delamination length were considered. The test results indicated the features of different fatigue delamination and crack growth according to each fiber orientation angle and also obtained to more increase delamination than crack through the relationship between crack length and delamination length in GLARE.

• Journal of the Korean Society for Precision Engineering
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• v.10 no.3
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• pp.152-160
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• 1993

This paper presents experimental study of the static and dynamic fracture toughness behavior of a A1-6061 aluminum alloy reinforced alumina( .delta. -A1$_{2}$0$_{3}$) whiskers with 5%, 10%, 15% volume fraction. The static fracture tests using three-point bending specimen were performed by UTM25T. And drop weight impact tester performing dynamic fracture tests was used to measure dynamic locads applied to a fatigue-precracked specimes. The oneset of crack initiation was detected uwing a strain gage bonded near a crack tip. The value of static fracture toughness $K_{IC}$ and dynamic fracture toughness $K_{ID}$ were decided on the basis of linear elastic fracture mechanics. The effects of fiber volume fraction and loading on fracture toughness were investigated. The distribution of whiskers, bonding state and fracture interfaces involved in void, fiber pull-out state were investigated by optical microscopy(OM) and scanning electron microscopy(SEM)

• Journal of Electrical Engineering and Technology
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• v.6 no.6
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• pp.849-852
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• 2011

This paper investigates a method to tackle the resonance problems of the rectangular power-bus structure(PBS) using thin sheets loaded with periodic metal strips. The equivalent surface impedance of the proposed loading is calculated and involved in the expression of the impedance that accounts for in the PBS, in order to improve the resonance behavior of the original structure. The effects of the strips and the immediate surroundings are illustrated by a number of numerical experiments. Also the restrictions of the technique are addressed.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2001.10a
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• pp.271-274
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• 2001

Experiments on the yield strength of pipe connectors made of metal wire, joint pins, pole pipes, multi span insertion joints, and T-clamp joints used in pipe houses were conducted. The strength of connections of a pipe connector made of metal wire was adequate but it had a big difference according to loading direction. The collapse load of pipes connected with a joint pin was lower than that of single pipes. Also experimental results showed that pole pipes for use in a part of frame buried under the ground were safe, and the strength of multi span insertion joints should be increased. The resistant moment of T-clamp was about 13.7% of a single pipe.