• Carbon letters
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• 제10권3호
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• pp.213-216
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• 2009

The electrochemical deposition of Pt nanoparticles on carbon nanotubes (CNTs) supports and their catalytic activities for methanol electro-oxidation were investigated. Pt catalysts of 4~12 nm average crystalline size were grown on supports by potential cycling methods. Electro-plating of 12 min time by potential cycling method was sufficient to obtain small crystalline size 4.5 nm particles, showing a good electrochemical activity. The catalysts' loading contents were enhanced by increasing the deposition time. The crystalline sizes and morphology of the Pt/support catalysts were evaluated using X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The electrochemical behaviors of the Pt/support catalysts were investigated according to their characteristic current-potential curves in a methanol solution. In the result, the electrochemical activity increased with increased plating time, reaching the maximum at 12 min, and then decreased. The enhanced electroactivity for catalysts was correlated to the crystalline size and dispersion state of the catalysts.

• 한국대기환경학회지
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• 제16권2호
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• pp.199-208
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• 2000

In this study we investigated on the possibility of platinum and silver catalysts as de-NOx catalyst for activity test of supported metal oxide catalysts. the study was performed with the change of amount of metal and support types. The catalyst was prepared the activity of alumina supported silver catalyst produced by dry and wet impregnation method respectively and the resistance of sulfur for optimum supported silver catalyst,. As a result the activity of alumina supported platinum catalyst was showed at low temperature region but the case of silver catalyst activated at high temperature region. So we finally chose alumina supported silver catalyst as de-NOx target catalyst because alumina supported catalyst showed higher activity than alumina supported platinum catalyst.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1999년도 춘계학술대회논문집
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• pp.18-21
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• 1999

In this study in order to make doubly-curved sheet metal effectively a sheet metal forming process has been developed by adopting the flexibility of the incremental forming process and the principle of bending deformation which causes slight deformation to thickness The developed process is an unconstrained forming process with no holder. For this study the experimental equipment is set up with the punch-set which consists of two pairs of lower support-punches and one upper center-punch. In the experiments using aluminum sheet it is found that the curvature of the formed sheet metal is determined by controlling the distance between supporting punches in pairs and the forming depth of the center-punch. and the edge-forming method is proposed for forming the sheet metal into the balanced shape. The equation using process variables such as the distance between supporting punches in pairs and the forming depth of the center-punch is proposed for the prediction of the radii of curvatures of the formed shape and it is corrected by the experimental results and the FEM simulation results about whether springback takes place. It is found that according o the simulation there is a certain set of the distance between a pair of supporting punches and the forming depth of the center-punch which causes a little springback. It is thus shown that the radii of curvatures of the formed sheet metal can be predicated by the corrected equation unless significant springback occurs.

• 대한치과보철학회지
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• 제25권1호
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• pp.161-179
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• 1987

To study the mechanical behaviors of the margins of porcelain-fused-to-metal crown on the posterior teeth, 5 types of margins on the lower first molar were chosen, and then the finite element models were constructed. 50kg forces were applied to the porcelain on the axial wall supported by the metal vertically. The displacements and stresses of the porcelain-fused-to-metal crown were analyzed to investigate the influence of the type of margins. The results were as follows; 1. High tensile stresses were exhibited on the porcelain of the portion of the coronal line angle insufficient metallic support. 2. In case metal coping had a good supporting form to vertical force, uniform compressive stresses were exhibited on their supporting form. 3. Tensile stresses in the inframetallic margin on the series of the shoulder with a bevel margins were decreased in the bevel portion. 4. Principal stresses on the metal of the chamfer marginal portion were decreased comparing with the series of the shoulder margins. 5. The noticeable compressive stress gradients were exhibited between axial cement layer and metal on the series of the shoulder margins. 6. The principal stresses on the marginal cement layer were higher than that of the occlusal surface and axial wall.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.61-61
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• 2010

In the present work, we present the optimized the hybrid structures of carbon nanotubes (CNTs) and metal nanocomposites including Cu, Al, Co and Ni using the first principle calculations based on the density functional theory. Introduction of CNTs into a metal matrix has been considered to improve the mechanical properties of the metal matrix. However, the binding energy between metals and pristine CNTs wall is known to be so small that the interfacial slip between CNTs and the matrix occurs at a relatively low external stress. The application of defective or functionalized CNTs has thus attracted great attention to enhance the interfacial strength of CNT/metal nanocomposites. Herein, we design the various hybrid structures of the single wall CNT/metal complexes and characterize the interaction between single wall CNTs and various metals such as Cu, Al, Co or Ni. First, differences in the binding energies or electronic structures of the CNT/metal complexes with the topological defects, such as the Stone-Wales and vacancy, are compared. Second, the characteristics of functionalized CNTs with various surface functional groups, such as -O, -COOH, -OH interacting with metals are investigated.We found that the binding energy can be enhanced by the surface functional group including oxygen since the oxygen atom can mediate and reinforce the interaction between carbon and metal. The binding energy is also greatly increased when it is absorbed on the defects of CNTs. These results strongly support the recent experimental work which suggested the oxygen on the interface playing an important role in the excellent mechanical properties of the CNT-Cu composite[1].

• Journal of Microbiology and Biotechnology
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• 제9권6호
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• pp.757-763
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• 1999

The metal specificity of D-xylose isomerase from Streptomyces rubiginosus was examined by site-directed mutagenesis. The activation constants for metal ion ($Mg^{2+},{\;}Mn^{2+},{\;}or{\;}Co^{2+}$) of wild-type and mutant enzymes were determined by titrating the metal ion-free enzyme with $Mg^{2+},{\;}Mn^{2+},{\;}and{\;}Co^{2+}$, respectively. Substitutions of amino acids either on coordinated or around the M2 site (His-22O, Asn-185, Glu-186, and Glu-221) dramatically affected the activation constants as well as activity. A decrease of metal binding affinity was most significant in the presence of $Mg^{2+}$. When compared with the wild-type enzymes, the binding affinity of H220S and Nl85K for Mg^{2+} was decreased by 10-15-fold, while the affinity for $Mn^{2+}{\;}or{\;}Co^{2+}$ only decreased by 3-5-fold. All the mutations close to the M2 site changed their metal preference from $Mg^{2+}{\;}to{\;}Mn^{2+}{\;}or{\;}Co^{2+}$. These altered metal preferences may be caused by a relatively weak binding affinity of $Mg^{2+}$ to the enzyme. Thermal inactivation studies of mutants at the M2 site also support the importance of the M2 site geometry for metal specificity as well as the thermostability of the enzyme. Mutations of other important groups hardly affected the metal preference, although pronounced effects on the kinetic parameters were sometimes observed. This study proposes that the metal specificity of D-xylose isomerase can be altered by the perturbation of the M2 site geometry, and that the different metal preference of Group I and GroupII D-xylose isomerases may be caused by nonconserved amino acid residues around the M2 site.

• 한국표면공학회지
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• 제23권2호
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• pp.30-38
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• 1990

For the purpose of suggesting the thermal resistant catalyst for automobile emission control, various catalysts, Pd-WO3 and PD-La2O3 systems, were charactrized before and after thermal aging. It was found that La2O3 formed amorphous surface compound on the support by strong metal-support interaction(SMSI). And by Temperature Programmed Desorption (TPD) expeiment, it was found that the distribution of acid site which is strong acid sites by adding the promoters. After thermal aging, it was observed that the acidity of Pd-WO3 system was decreased largely because of losing acid site by metal vaporization. On the other hand, there was pretty small change in the properties of matter of Pd-La2O3 system. Therefore, it could be considered that La2O3 formed heat resisting amorphous surface compound on the support by SMSI.

• 한국컴퓨터정보학회논문지
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• 제20권1호
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• pp.11-20
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• 2015

기존 벨로우즈의 용접 불량은 현미경을 이용한 작업자의 수작업과 육안확인으로 진행되고 있어 효율과 능률면에서 많은 부작용이 있다. 본 논문에서 이러한 문제점을 해결하고자 서포트 벡터 머신을 이용한다. 제안된 시스템은 서포트 벡터 머신을 이용하여 작업자의 경험적인 방법을 대체하고, 이미지 처리 과정에서 작업자로부터 발생하는 불규칙성을 극복할 수 있다. 또한 현미경과 3D 디스플레이 시스템을 통하여 제품불량을 쉽게 확인할 수 있다. 자동화 측정 장치로부터 얻어진 실험결과를 통하여 용접불량은 허용되는 에러 범위 아래로 개선됐음을 알 수 있다.

• Journal of Electrochemical Science and Technology
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• 제13권4호
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• pp.417-423
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• 2022

With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-supported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH₄ in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm^-2. Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.

• Transactions on Electrical and Electronic Materials
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• 제16권6호
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• pp.312-316
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• 2015

Through silicon via (TSV) technology holds the promise of chip-to-chip or chip-to-package interconnections for higher performance with reduced signal delay and power consumption. It includes high aspect ratio silicon etching, insulation liner deposition, and seamless metal filling. The desired etch profile should be straightforward, but high aspect ratio silicon etching is still a challenge. In this paper, we investigate the use of etch hard mask for finer TSVs etching to have clear definition of etched via pattern. Conventionally employed photoresist methods were initially evaluated as reference processes, and oxide and metal hard mask were investigated. We admit that pure metal mask is rarely employed in industry, but the etch result of metal mask support why hard mask are more realistic for finer TSV etching than conventional photoresist and oxide mask.