• Title/Summary/Keyword: Metal support

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Lead Tolerance of Noble Metal Catalysts for CO Oxidation

  • Chang, Tu-Won;Sohn, Youn-Soo
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.12-15
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    • 1986
  • Lead tolerance of $Pt/Al_2O_3$ catalysts was evaluated for CO oxidation depending on the properties of the alumina supports and base metals added as promoter. Among the four different alumina supports, the support with a large macropore volume (0.45 cc/g) and 5% Ce has shown the best resistence to lead poisoning. Most of the base metals added to the Pt-catalysts were found to be ineffective for improving lead resistence, but boron has shown an excellent lead tolerence, although it decreases the initial catalytic activity.

Electron Paramagnetic Resonance Study of Bis(N-methyl-2-amino-1-cyclopentenedithiocarboxylato)Copper (II)

  • Woo-Seong Kim;Young-Inn Kim;Sung-Nak Choi
    • Bulletin of the Korean Chemical Society
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    • v.11 no.2
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    • pp.85-88
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    • 1990
  • The electron paramagnetic resonance (EPR) spectrum of the copper (II) complex with the 2-methylamino-1-cyclo-pentene-1-dithiocarboxylate (acdc) anion, $Cu(N-CH_3acdc)_2$ has been studied in the diamagnetic host lattices afforded by the corresponding divalent nickel, zinc, cadmium and mercury complexes. EPR parameters of the complex support the exclusive use of sulfur atoms by the ligand in metal binding. A combination of host lattice structure and covalency effects can be account for the observed spin-Hamiltonian parameters.

Use of Photocatalyst in Civil & Environmental Engineering (건설환경공학분야에서 광촉매 활용)

  • An, Sang-Woo;Jang, Jun-Won;Park, Jae-Woo
    • Prospectives of Industrial Chemistry
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    • v.19 no.5
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    • pp.25-32
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    • 2016
  • 건설환경공학분야에서 사용되고 있는 광촉매의 기술동향을 살펴보았으며, 환경분야는 수처리분야에서 적용되는 광촉매공정의 기술현황을 살펴보았으며, 토목분야에서는 기반시설인 도로용 콘크리트에서의 광촉매 적용 동향을 TiO2 적용을 위주로 기술하였다.

A Study on the Preference of Old Women for the Higher Usability of u-Health Life Support Appliances (재가노인 유헬스 생활지원기기의 실용화를 위한 여성노인의 선호)

  • Kim, Sun-Joong;Park, Kyoung-Ok
    • Journal of the Korean housing association
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    • v.20 no.1
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    • pp.101-112
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    • 2009
  • The purpose of this study is to find out the preference and the needs of old womens on the life support appliances i.e. medication dispenser, video phone, activity monitor and sleep monitor. The appliances may be improved reflecting the result of the questionnaire asking about the preferred functions and designs. The respondents were 141 female seniors of 65 years and older, living in Ulsan city or Cheongju city, Korea. Following is the list of results. (1) The medication dispenser, responded as highly preferred, met some worries over the troubles by power stoppage especially while one is out, letting her forget the medication time. (2) The video phone was worried over the cases of hearing failure by small sound, and watching failure by weakening sight. (3) The activity monitor, like the medication dispenser, was worried about the troubles while one is out or out of the monitoring scope, its expense, and the privacy, (4) The sleep monitor met the worries over the inadequacy for the sleeping mat on the floor and the emission of electromagnetic waves. (5) The preferred designs were (1) white or red standing medication dispenser, (2) wall-mounted video phone working by voice, (3) metal activity monitor sensor with white or yellow bracelet.

Restoration of Mandibular Edentulous Patient By Dental Implant: Case Report

  • Kwon, Ji-Yung;Kim, Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.3
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    • pp.360-365
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    • 2000
  • The completely edentulous patient has few treatment options in conventional dentistry. When implants are considered, treatment plans range from a 2-implant overdenture to a completely implant-supported prosthesis. Fixed prosthesis is often the preferred selection of the edentulous patient. fixed full-arch cert amo-metal restorations can be a predictable implant treatment modality for the edentulous patient. Implant-supported fixed prosthesis has several advantages: predictability, fixedness, retrievability, improved function, lower maintenance of prosthesis, long-term published success. Edentulous patients with a severely resorbed mandible often experience problems with their dentures. Treatment concepts involving two to four implants for the support of an overdenture have been proposed. There seems to be no need to insert more than two endosteal implants to support an overdenture, however, long-term prospective studies are needed to support this notion. Using short endosseous implants and an overdenture in the extremely resorbed mandible is a justified treatment option because of the relative simplicity and low morbidity of this treatment strategy. Implant-supported overdenture has several advantages: Cost, retrievability, hygiene access, profile and contour control, increased retention and stability, implant installed in a predicted region(ant. mandible).

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The Effect of Cu Reflow on the Pd-Cu Alloy Membrane Formation for Hydrogen Separation (수소분리용 Pd-Cu 합금 분리막의 Cu Reflow 영향)

  • Mun, Jin-Uk;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.39 no.6
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    • pp.255-262
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    • 2006
  • Pd-Cu alloy membrane for hydrogen separation was fabricated by sputtering and Cu reflow process. At first, the Pd and Cu was continuously deposited by sputtering method on oxidized Si support, the Cu reflow process was followed. Microstructure of the surface and permeability of the membrane was investigated depending on various reflow temperature, time, Pd/cu composition and supports. With respect to our result, Pd-Cu thin film (90 wt.% Pd/10 wt.% Cu) deposited by sputtering process with thickness of $2{\mu}m$ was heat-treated for Cu reflow The voids of the membrane surface were completely filled and the dense crystal surface was formed by Cu reflow behavior at $700^{\circ}C$ for 1 hour. Cu reflow process, which is adopted for our work, could be applied to fabrication of dense Pd-alloy membrane for hydrogen separation regardless of supports. Ceramic or metal support could be easily used for the membrane fabricated by reflow process. The Cu reflow process must result in void-free surface and dense crystalline of Pd-alloy membrane, which is responsible for improved selectivity oi the membrane.

Estimation of residual stress in welding of dissimilar metals at nuclear power plants using cascaded support vector regression

  • Koo, Young Do;Yoo, Kwae Hwan;Na, Man Gyun
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.817-824
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    • 2017
  • Residual stress is a critical element in determining the integrity of parts and the lifetime of welded structures. It is necessary to estimate the residual stress of a welding zone because residual stress is a major reason for the generation of primary water stress corrosion cracking in nuclear power plants. That is, it is necessary to estimate the distribution of the residual stress in welding of dissimilar metals under manifold welding conditions. In this study, a cascaded support vector regression (CSVR) model was presented to estimate the residual stress of a welding zone. The CSVR model was serially and consecutively structured in terms of SVR modules. Using numerical data obtained from finite element analysis by a subtractive clustering method, learning data that explained the characteristic behavior of the residual stress of a welding zone were selected to optimize the proposed model. The results suggest that the CSVR model yielded a better estimation performance when compared with a classic SVR model.

Effect of La in Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3 (M = La, Ce, Y) Catalysts (M(1)-Ni(5)/AlCeO3 (M = La, Ce, Y) 촉매상에서 수소 제조를 위한 메탄의 부분산화반응에서 La의 효과)

  • Seo, Ho Joon
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.757-761
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    • 2019
  • The catalytic yields of POM to hydrogen over M(1)-Ni(5)/AlCeO3 (M = La, Ce, Y) were investigated using a fixed bed flow reactor under atmosphere. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO3 catalysts before and after the reaction were studied via XRD analysis. FESEM and EDS analyses were further performed to show the uniformed distribution of La, Ni, and Ce metal particles on the catalyst surface. XPS results showed O2-, O22- species and metal ions such as Ce3+, Ce4+, La3+ and Ni2+ etc. were on the catalyst surface. When 1 wt% of La was added to Ni(5)/AlCeO3 catalyst, Ni2p3/2 and Ce3d5/2 increased 52.7 and 6.3%, respectively. The yield of hydrogen on the La(1)-Ni(5)/AlCeO3 catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/AlCeO3 (M = Ce, Y). As Ce4+ ions of CeO2 produced by the reaction of AlCeO3 with oxygen were substitute to La3+, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal-support interaction (SMSI) effect.

Complete denture making in a patient of partial glossectomy using polished surface impression taking and direct metal laser sintering method: A case report (부분 설절제술을 받은 환자에서의 연마면 인상 및 Direct Metal Laser Sintering 을 이용한 총의치 제작 증례)

  • Jung, Yeon-Wook;Lee, Gyeong-Je;Kim, Hee-Jung
    • The Journal of Korean Academy of Prosthodontics
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    • v.57 no.4
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    • pp.350-355
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    • 2019
  • For the success of complete denture, three essential requirements such as retention, stability and support are needed. Moreover, due to the absorption of residual ridge and scarring due to the surgery, when making a complete denture, which is difficult to form the mandibular lingual margins, various considerations such as the arrangement of the Non-anatomical dl non-anatomical teeth, the polished surface impression, the internally weighted metal framework and the use of the denture adhesive cream are necessary. In this case report, the patient has a severely resorbed edentulous ridge from severe periodontitis and has some soft tissue problems after the glossectomy due to tongue cancer. To obtain additional retention and stability, some trials such as polished surface impression taking, internally weighted metal insertion and minimal pressure impression were done for the better result. Moreover To make a metal framework that precisely shapes the desired three-dimensional shape and reduces the complicated process, minimal pressure impression method and direct metal laser sintering technique were used.

Three Dimensional Layering Algorithm for 3-D Metal Printing Using 5-axis (3 차원 금속 프린팅을 위한 다중 3 차원 적층 알고리듬(3DL))

  • Ryu, Sua;Jee, Haeseong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.8
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    • pp.881-886
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    • 2014
  • The purpose of three-dimensional (3-D) metal printing using 5-axis is to deposit metal powder by changing the orientation of the deposited structure to be built for the overhang or undercut feature on part geometry. This requires a complicated preprocess functionality of providing three dimensionally sliced layers to cover the required part geometry. This study addresses the overhang/undercut problem in 3-D metal printing and discusses a possible solution of providing 3-D layers to be built using the DMT(R) machine.