• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.89.2-89.2
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• 2010

The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of $TiO_2$ are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

• Explosives and Blasting
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• v.35 no.1
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• pp.27-33
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• 2017

In this study, two fracture toughness test procedures are modelled for selected metal and rock on LS-DYNA, which is a commercial finite element code. The tests are conducted by using the 3-point bend test procedure for rectangular bar specimen. Because it takes a relatively long time to conduct the test, the implicit solver based on the Newmark method is adopted for the analyses. The values of stress intensity factor obtained from the analyses are 73 and $0.3MPa.m^{0.5}$ for the metal and rock material, respectively. It can be thought that the resulting small value of the fracture toughness of the rock material model well represents the brittleness of rock material.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.3
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• pp.1-10
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• 1998

In this paper, we investigated the improvement of characteristics of knock, emission and fuel consumption rate by optimizing the location and size of water transfer holes in cylinder head gasket without change of engine water jacket design itself. The cooling system was modified in the direction of reducing the metal temperature in the head and increasing the metal temperature in the block. The optimization of water transfer holes in cylinder head gasket was obtained by "flow visualization test". The water transfer holes were concentrated in front side of the engine in order to reduce thermal boundary layer in the water jacket of No. 2 and No. 3 combustion changer in the cylinder head, which would have a large knock intensity, and increase thermal boundary layer in the water jacket of the cylinder block. When the modified coolant flow pattern was applied as proposed in this paper, the knock characteristic was improved. The spark timing was advanced up to 2$^{\circ}$ in low and middle speed range at a full load. In addition, HC emission at MBT was reduced by 5.2%, and the fuel consumption rate was decreased up to 1% in the driving condition of 2400 rpm and 250 KPa. However, since this coolant flow pattern mentioned in this paper might deteriorate the performance of vehicle cooling system due to the coolant flow rate reduction, a properly optimized point should be obtained. obtained.

• Journal of Welding and Joining
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• v.11 no.4
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• pp.44-56
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• 1993

The arc welding processes are substantially nonlinear, in addition to being highly coupled multivariable systems, Frequently, not all the variables affecting the welding quality are known, nor may they be easily quantified. From this point of view, decoupling between the welding parameters from the welding quality is very difficult, which makes it also difficult to control the welding parameters for obtaining the desired welding quality. In this study, a neural network based on the backpropagation algorithm was implemented and adopted for the selection of gas metal arc welding parameters of the fillet joint, that is, welding current, arc voltage and welding speed. The performance of the neural network for modeling the relationship between the welding quality and welding parameters was presented and evaluated by using the actual welding data. To obtain the optimal neural network structure, various types of the neural network structures were tested with the experimental data. It was revealed that the neural network can be effectively adopted to select the appropriate gas metal arc welding parameter of fillet joints for a given weld quality.

• Journal of the Korean Ceramic Society
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• v.35 no.3
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• pp.219-230
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• 1998

Various interlayer materials have been tested for active metal(Cusil ABA) brazing of Si3N4/S. S316 joint. In general multilayer joint had higher strength(80-150 MPa) and better reliability than monolayered one. The joint with Cu(0.2)/Mo(0.3)/Cu(0.2mm) interlayer showed the highest bending strength of abou 490 MPa and the joint with Cu(0.2)/Mo(0.3mm) interlayer the best reliability (14.6 Weibull modulus). The stresses distributed in joint materials during 4-point bending test were estimated by CAE von Mises analysis; the estimated stresses were In good agreement with the measured data. In multilayer joint Cu was though to reduce the residual stresses induced by the difference in thermal expansion coefficient between the ceramic Mo and metal It apperared that a Cu/Mo was optimum interlayer material for Si3N4/S. S316 joint with high bending strength (420 MPa) and reliability. In addition the various shapes and types of compound were examined by EPMA in joining interface.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.118.1-118.1
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• 2011

The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of TiO2 are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

• Journal of Korea Foundry Society
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• v.29 no.1
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• pp.45-51
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• 2009

Conventionally, Al-Sn bearing manufacturing involves casting the Al-Sn alloy and roll-bonding to a steel backing strip. This article will describe the microstructural control of Al-Sn metal bearing alloy following heat treatment. When the pure aluminum rod dipped in the melt of tin maintained below the melting point of aluminum, the melting of aluminum was accelerated with penetration of tin along the grain boundary of aluminum. The length of plate-shaped eutectic tin was decreased with heat treatment time. With even longer heat treatment time over 1 hour the length of eutectic tin didn't decrease any more, while resulting in coarsening of aluminum matrix. Exuded liquid of eutectic tin was formed at the surface of Al-Sn alloy after heat treatment even at below eutectic temperature.

• Progress in Superconductivity
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• v.12 no.2
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• pp.114-117
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• 2011

We report our efforts on the development of Nb-based non-hysteretic Josephson junction fabrication process for quantu device applications. By adopting and modifying the existing Nb-aluminum oxide tunnel junction process, we develop a process for non-hysteretic Josephson junction circuits using metal-silicide as metallic barrier material. We use sputter deposition of Nb and $MoSi_2$, PECVD deposition of silicon oxide as insulator material, and ICP-RIE for metal and oxide etch. The advantage of the metal-silicide barrier in the Nb junction process is that it can be etched in $SF_6$ RIE together with Nb electrode. In order to define a junction area precisely and uniformly, end-point detection for the RIE process is critical. In this paper, we employed thin Al layer for the etch stop, and optimized the etch condition. We have successfully demonstrated that the etch stop properties of the inserted Al layer give a uniform etch profile and a precise thickness control of the base electrode in Nb trilayer junctions.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.18 no.7
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• pp.594-599
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• 2005

In this paper, we report the properties of Mo metal employed as PMOS gate electrode. Mo on $SiO_2$ was observed to be stable up to $900^{\circ}C$ by analyzing the Interface with XRD. C-V measurement was performed on the fabricated MOS capacitor with Mo Bate on $SiO_2$. The stability of EOT and work-function was verified by comparing the C-V curves measured before and after annealing at 600, 700, 800, and $900^{\circ}C$. C-V hysteresis curve was performed to identify the effect of fired charge. Gate-injection and substrate-injection of carrier were performed to study the characteristics of $Mo-SiO_2$ and $SiO_2-Si$ interface. Sheet resistance of Mo metal gate obtained from 4-point probe was less than $10\;\Omega\Box$ that was much lower than that of polysilicon.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.3
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• pp.440-449
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• 2003

Residual strength of fiber metal laminates after impact was studied. 3/4 lay up FML was fabricated using 4 ply prepreg, 2 ply aluminum sheets, and 1 ply steel sheet. Quasi isotropic ([0/45/90/-45]s) and orthotropic ([0/90/0/90]s) FRP were also fabricated to compare with FML. Impact test were conducted by using instrumented drop weight impact machine (Dynatup, Model 8250). Penetration load and absorbed energy of FML were superior to those of FRPs. Tensile tests were conducted to evaluate the residual strength after impact. Strength degradation of FML was less than that of FRP. This means that the damage tolerance of FML is excellent than that of FRP. Residual strength of each specimen was predicted by using Whitney and Nuismer(WN) Model. Impact damage area is assumed as a circular notch in WN model. Damage width is defined as the average of back face and top face damage width of each specimen. Average stress and point stress criterions were used to calculate the characteristic length. It is supposing that a characteristic length is a constant. The distribution of characteristic length shows that the assumption is reasonable. Prediction was well matched with experiment under both stress criterions.