• Title/Summary/Keyword: Metal point

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Microstructure and Electrical Resistivity of Ink-Jet Printed Nanoparticle Silver Films under Isothermal Annealing (잉크젯 프린팅된 은(Ag) 박막의 등온 열처리에 따른 미세조직과 전기 비저항 특성 평가)

  • Choi, Soo-Hong;Jung, Jung-Kyu;Kim, In-Young;Jung, Hyun-Chul;Joung, Jae-Woo;Joo, Young-Chang
    • Korean Journal of Materials Research
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    • v.17 no.9
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    • pp.453-457
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    • 2007
  • Interest in use of ink-jet printing for pattern-on-demand fabrication of metal interconnects without complicated and wasteful etching process has been on rapid increase. However, ink-jet printing is a wet process and needs an additional thermal treatment such as an annealing process. Since a metal ink is a suspension containing metal nanoparticles and organic capping molecules to prevent aggregation of them, the microstructure of an ink-jet printed metal interconnect 'as dried' can be characterized as a stack of loosely packed nanoparticles. Therefore, during being treated thermally, an inkjet-printed interconnect is likely to evolve a characteristic microstructure, different from that of the conventionally vacuum-deposited metal films. Microstructure characteristics can significantly affect the corresponding electrical and mechanical properties. The characteristics of change in microstructure and electrical resistivity of inkjet-printed silver (Ag) films when annealed isothermally at a temperature between 170 and $240^{\circ}C$ were analyzed. The change in electrical resistivity was described using the first-order exponential decay kinetics. The corresponding activation energy of 0.44 eV was explained in terms of a thermally-activated mechanism, i.e., migration of point defects such as vacancy-oxygen pairs, rather than microstructure evolution such as grain growth or change in porosity.

Effects of Brazing Current on Mechanical Properties of Gas Metal Arc Brazed Joint of 1000MPa Grade DP Steels (1000MPa급 DP강 MIG 아크 브레이징 접합부의 기계적 성질에 미치는 브레이징 전류의 영향)

  • Cho, Wook-Je;Yoon, Tae-Jin;Kwak, Sung-Yun;Lee, Jae-Hyeong;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.35 no.2
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    • pp.23-29
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    • 2017
  • Mechanical properties and hardness distributions in arc brazed joints of Dual phase steel using Cu-Al insert metal were investigated. The maximum tensile shear load was 10.4kN at the highest brazing current. It was about 54% compared to tensile load of base metal. This joint efficiency is higher than that of joint of DP steel using Cu-based filler metals which are Cu-Si, Cu-Sn. Fracture positions can be divided into two types. Crack initiation commonly occurred at three point junction among upper sheet, lower sheet and the fusion zone. However crack propagations were different with increasing the brazing current. In case of the lower current, it instantaneously propagated along with the interface between fusion zone and upper base material. On the other hand, in case of higher current, a crack propagation occurred through fusion zone. When the brazing current is low (60, 70A), the interface shape is flat type. However the interface shape is rough type, when the brazing current is high (80A). It is thought that the interface shapes were the reason why the crack propagations were different with brazing current. The interface was the intermetallic compounds which consisted of $(Fe,Al)_{0.85}Cu_{0.15}$ IMC formed by crystallization at $1200^{\circ}C$during cooling. Therefore the maximum tensile shear load and the fracture behavior were determined by a interface shape and effective sheet thickness of the fracture position.

Networks of the Machinery and Metal Industries in Busan Region and the Strategies for Raising the industrial Competitiveness (부산지역 기계.금속산업의 네트워크분석과 경쟁력 제고방안)

  • Kwon, O-Hyeok;Yun, Yeong-Sam;Choi, Hong-Bong
    • Journal of the Korean association of regional geographers
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    • v.11 no.6
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    • pp.543-558
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    • 2005
  • This paper is to research the present conditions and characteristics of the machinery and metal industries in Busan region from industrial cluster and network point of view. The result of this study is as follows. First, a independent machinery and metal industrial cluster has been shaped in Busan region although it is not so large. Second, the technological level and the competitiveness of the machinery and metal industries in Busan region is still low. The companies in Busan area are interacted by local network with low-tech and low competitiveness. Third, we need to invite the technological leading companies to Busan region for this industrial cluster's technological competitiveness is raised.

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A Numerical Study of the Residual Hydrogen Concentration in the Weld Metal (용접금속 잔류수소농도의 수치해석 연구)

  • Yoo, Jinsun;Ha, Yunsok;S.R., Rajesh
    • Journal of Welding and Joining
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    • v.34 no.6
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    • pp.42-46
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    • 2016
  • Hydrogen assisted cracking (HAC) is one of the most complicated problem in welding. Huge amount of studies have been done for decades. Based on them, various standards have been established to avoid HAC. But it is still a chronic problem in industrial field. It is well known that the main causes of the hydrogen crack are residual stress, crack susceptible micro structures and a certain critical level of hydrogen concentration. Even though the exact generating mechanism is unclear till today, it has been reported that the hydrogen level in the weld metal should be managed less than a certain amount to prevent it. Matsuda studied that the residual hydrogen level in the weld metal can be varied even if the initial hydrogen content is same. It is also insisted in this report that the residual hydrogen concentration is in stronger correlation with hydrogen crack than the initial hydrogen content. But, in practical point of view, the residual hydrogen is still hard to consider because measuring hydrogen level is time and cost consuming process. In this regard, numerical analysis is the only solution for considering the residual hydrogen content. Meanwhile, Takahashi showed the possibility of predicting the residual hydrogen by a rigorous FE analysis. But, few commercial software suitable for solving the weld metal hydrogen has been reported yet. In this study, two dimensional thermal - hydrogen coupled analysis was developed by using the commercial FE software MARC. Since the governing equation of the hydrogen diffusion is similar to the heat transfer, it is shown that the heat transfer FE analysis in association with hydrogen diffusion property can be used for hydrogen diffusion analysis. A series of simulation was performed to verify the accuracy of the model. For BOP (Bead-On-Plate) and the multi-pass butt welding simulations, remaining hydrogen contents in the weld metal is well matched with measurements which are referred from Kim and Masamitsu.

Biodegradable PLGA Polymer Coating on Biomedical Metal Implants Using Electrospraying (전기분사를 이용한 의료용 금속 임플란트의 생분해성 PLGA 고분자 코팅)

  • Cho, Seong-Bae;Park, Chul-Ho;Park, Kwi-Deok;Chung, Dong-Jun;Han, Dong-Keun
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.620-624
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    • 2009
  • Biomedical metal implants have been used clinically for replacement, restoration, or improvement of injury bodies based on high mechanical properties, but it has some risks such as the inflammatory, late thrombosis, or restenosis due to the low biocompatibility and toxicity. In various techniques of surface treatment developed to preserve these drawbacks, this study examined the electrospray coating technology with biodegradable poly (lactic-co-glycoic acid) (PLGA) on metal surface. Based on fundamental examination of electrospraying and solution parameters, the surface morphology of coated film was closely related to the boiling point of solvent, in-flight distance, and droplet size. The thickness of polymer film was linearly proportional to the emerged volume. This result exhibits that the polymeric droplets were continuously deposited on the polymer film. Therefore, the electrospray coating technology might be applied into the fabrication of single/multi-layered polymer film in nano-/micro-thickness and the control of the topology for biomedical metal implants including stents.

Analysis of the Formation of Rear Contact for Monocrystalline Silicon Solar Cells (단결정 실리콘 태양전지의 후면 전극형성에 관한 비교분석)

  • Kwon, Hyuk-Yong;Lee, Jae-Doo;Kim, Min-Jeong;Lee, Soo-Hong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.7
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    • pp.571-574
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    • 2010
  • Surface recombination loss should be reduced for high efficiency of solar cells. To reduce this loss, the BSF (back surface field) is used. The BSF on the back of the p-type wafer forms a p+layer, which prevents the activity of electrons of the p-area for the rear recombination. As a result, the leakage current is reduced and the rear-contact has a good Ohmic contact. Therefore, the open-circuit-voltage (Voc) and fill factor (FF) of solar cells are increased. This paper investigates the formation of the rear contact process by comparing aluminum-paste (Al-paste) with pure aluminum-metal(99.9%). Under the vacuum evaporation process, pure aluminum-metal(99.9%) provides high conductivity and low contact resistance of $4.2\;m{\Omega}cm$, but It is difficult to apply the standard industrial process to it because high vacuum is needed, and it's more expensive than the commercial equipment. On the other hand, using the Al-paste process by screen printing is simple for the formation of metal contact, and it is possible to produce the standard industrial process. However, Al-paste used in screen printing is lower than the conductivity of pure aluminum-metal(99.9) because of its mass glass frit. In this study, contact resistances were measured by a 4-point probe. The contact resistance of pure aluminum-metal was $4.2\;m{\Omega}cm$ and that of Al-paste was $35.69\;m{\Omega}cm$. Then the rear contact was analyzed by scanning electron microscope (SEM).

Effects of Temperature and Heavy Metals on Extractable Lipofuscin in the Blue Crab, Callinectes sapidus

  • Ju, Se-Jong;Harvey, H.R.
    • Journal of the korean society of oceanography
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    • v.37 no.4
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    • pp.232-241
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    • 2002
  • The potential role of environmental factors on extractable lipofuscin accumulation rate in the blue crab was studied by examining the effect of temperature on laboratory reared blue crabs and the effect of trace metals from samples collected at impacted sites (Baltimore Harbor) and a relatively pristine site (outdoor ponds at Horn Point Laboratory, Cambridge, MD, USA). Lipofuscin levels did not significantly related with sampling sites or heavy metal concentrations in the crab tissue. Heavy metal body burden was highly variable among sampling sites and tissue types but significantly higher for both impacted areas (Curtis Creek and Inner Harbor) in comparison to the reference site. Among tissue types, gills showed the highest metal concentrations with the exception of Hg, which was highest in muscle tissue. For two groups of crabs that were held at either ambient (4 to 1$0^{\circ}C$) or heated seawater (19$^{\circ}C$) for two months, normalized-lipofuscin levels were significantly different (P-0.001). Results suggest that temperature may affect lipofuscin accumulation (=0.25ng-lipofuscin/mg-protein/temperature-degree day). Therefore, temperature should be considered for accurate age calibration of crab populations using lipofuscin.

A Short Review on the Principal of Matching Five-Su-Points to O-Haeng Using Hado (하도를 이용한 오수혈 오행배속 원리 고찰)

  • Choi, In Suh;Lee, Bong Hyo
    • Korean Journal of Acupuncture
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    • v.31 no.2
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    • pp.49-55
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    • 2014
  • Objectives : Five transport points are often used in acupuncture treatment. However, there is no clear explanation about the reason why the five transport points are matched five phases in this manner. Therefore, we reviewed the literatures and theses about the principal of matching and researched a new way to understand the reason. Methods : We found 8 theses and 3 literatures related to the matching of five transport points to five phases by searching the web sites. And, we reviewed the principal of matching and researched another new way to understand the reason why they are matched so. Results and Conclusions : In the viewpoint of the natural state and function of five phases, the start points arising in yin- and yang-meridian are matched to wood and metal respectively. Therefore, well point matches the wood and metal in yin- and yang-meridian respectively. And by following the flow of five transport points, the other points match with fire, earth, metal, water in yin-meridian and water, wood, fire, and earth in yang-meridian.

The Research on The Stability as Fill Material of Soil Defiled by Oil Element and Heavy Metals (중금속 및 유류로 오염된 토질의 성토재료로서의 안정성에 관한 연구)

  • Lee, Chung-Sook;Eom, Tae-Kyu;Choi, Yong-Kyu;Lee, Min-Hee
    • Journal of the Korean GEO-environmental Society
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    • v.5 no.2
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    • pp.5-13
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    • 2004
  • In the site for apartment construction, the contaminated soils of the heavy metal and the oil were appeared. The representative soil samples were sampled at 7 sampling points. To confirm the geotechnical stability of the contaminated soils, the environmental checks for the heavy metal and the oil. The soils of 2 sampling points were contaminated heavily, so it was estimated that these soils must be disused. For 1 sampling point of the slightly contaminated soil, to confirm the re-applicability of fill material, the stability analysis was performed and it was concluded that this soil will be able to re-use.

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Synthesis and Photovoltaic Performance of Long Wavelength Absorption Dyes for the Dye Sensitized Solar Cell (장 파장 대 태양광을 흡수하는 염료감응형태양전지에 대한 염료와 합성)

  • Kim, Sangah;Yoon, Jooyoung;Kim, Jaehong
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.89.2-89.2
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    • 2010
  • The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of $TiO_2$ are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

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