• Title/Summary/Keyword: Metal oxide

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Applicability Test of Various Stabilizers for Heavy Metals Contaminated Soil from Smelter Area (제련소 주변 오염토양의 중금속 안정화를 위한 다양한 안정화제의 적용성 연구)

  • Jeon, Jonwon;Bae, Bumhan;Kim, Younghun
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.11
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    • pp.63-75
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    • 2010
  • There are several remediation technologies for heavy metal contaminated soils but increasing cost limits the application of the technology if the contaminated area is large. Therefore, stabilization, which blocks the release of heavy metals or makes slow the release, is one of the applicable technology for the heavy metal contaminated soil. Current study is an applicability test for a smelter area with various stabilizer such as magnetite, hematite, zeolite-A, zeolite-X, zeolite-Y, zinc oxide, calcium oxide, carbon trioxide, manganese oxide, manganese dioxide, fish bone, sodium phosphate. The soil contaminated with arsenic, lead, copper, nickel, and zinc could not be stabilized only one stabilizer which is known to have stability for certain metal. Many of the stabilizer works for a few metal but not all of the heavy metal. In several cases, stabilizers increase the release of the other metals while they stabilize some metals. In general, the stabilizing efficiency was increased with time. For Ni, Pb, calcium oxide, carbon trioxide, manganese oxide had good stabilizing effect in water extractable portion. For Cu, manganese oxide, zeolite showed good results especially in the exchangeable portion of the sequential extraction. For As, magnetite had good ability but most of the metal oxide which showed good result for other heavy metals increased with the release of As. Current study suggest that multiple stabilizers are needed for the contaminated soil and dose of the stabilizer and stabilizing time should be carefully considered for the soil contaminated with various metals.

Study of the Hole Trapping in the Gate Oxide Due to the Metal Antenna Effect (Metal Antenna 효과로 인한 게이트 산화막에서 정공 포획에 관한 연구)

  • 김병일;신봉조박근형이형규
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.549-552
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    • 1998
  • Recently, the gate oxide damage induced by the plasma processes has been one of the most significant reliability issues as the gate oxide thickness falls below 10 nm. The process-induced damage was studied with the metal antenna test structures. In addition to the electron trapping, the hole trapping in a 10 nm thick gate oxide due to the plasma-induced charging was observed in the NMOS's with a metal antenna. The hole trapping gave rise to the decrease of the transconductance (gm) similarly to the case of the electron trapping, but to the extent much less than the electron trapping. It would be because the electrical stress that the plasma-induced charging forced to the gate oxide for the devices with the hole trapping was much smaller than for those with the electron trapping. This hypothesis was strongly supported by the measured characteristics of the Fowler-Nordheim current in the gate oxide.

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Simultaneous Removal of SO$_2$ and NO by Using Metal Oxide( II ) -Oxidative Sorption of SO$_2$ by Metal Oxide- (금속산화물을 이용한 이산화황과 산화질소의 동시재거( II ) -금속산화물과 이산화황의 반응-)

  • 신창섭
    • Journal of the Korean Society of Safety
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    • v.6 no.4
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    • pp.26-33
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    • 1991
  • To remove SO$_2$ from flus gas, cupric oxide, manganese oxide and iron oxide were studied with varying loading value. The experiment was carried out in a flow reactor and the reactants were prepared by impregnation method using alumina. The reaction temperature was varied from 30$0^{\circ}C$ to 45$0^{\circ}C$. Experimental results showed that all of these metal oxides were effective on SO$_2$ removal reaction and cupric oxide was the best reactant. The sample with 10wt% loading value was better reactant than with 20wt% because in case of 20wt% loading, metal dispersion on the alumina surface was not uniform. And the SO$_2$ removal efficiency was increased with the reaction temperature.

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Anodic Growth of Vanadium Oxide Nanostructures (Vanadium Oxide 나노구조 형성)

  • Lee, Hyeon-Gwon;Lee, Gi-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.68-68
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    • 2018
  • Nanoporous or nanotubular metal oxide can be fabricated by anodization of metal substrate in fluoride contained electrolytes. The approach allows various transition metals such as Zr, Hf, Nb, Ta to form highly ordered oxide nanostructures. These oxide nanostructures have various advantages such as high surface area, fast electron transport rate and slow recombination in semiconductive materials. Recently, vanadium oxide nanostructures have been drawn attentions due to their superior electronic, catalytic and ion insertion properties. However, anodization of vanadium metal to form oxide layers is relatively difficult due to ease formation of highly soluble complex in water contained electrolyte during anodization. Yang et al. reported $[TiF_6]^{2-}$ or $[BF_4]^-$ in electrolyte helps to formation of stable oxide layer [1, 2]. However, the reported approaches are very sensitive in other parameters. In this presentation, we deal with the other important key parameters to form ordered anodic vanadium oxide such as pH, temperatures and applied potential.

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Formation of iron oxides from acid mine drainage and magnetic separation of the heavy metals adsorbed iron oxides

  • Kwon, Hee-won;Kim, JeongJin;Ha, Dong-Woo;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.28-32
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    • 2016
  • There are a few thousand abandoned metal mines in South Korea. The abandoned mines cause several environmental problems including releasing acid mine drainage (AMD), which contain a very high acidity and heavy metal ions such as Fe, Cu, Cd, Pb, and As. Iron oxides can be formed from the AMD by increasing the solution pH and inducing precipitation. Current study focused on the formation of iron oxide in an AMD and used the oxide for adsorption of heavy metals. The heavy metal adsorbed iron oxide was separated with a superconducting magnet. The duration of iron oxide formation affected on the type of mineral and the degree of magnetization. The removal rate of heavy metal by the adsorption process with the formed iron oxide was highly dependent on the type of iron oxide and the solution pH. A high gradient magnetic separation (HGMS) system successfully separated the iron oxide and harmful heavy metals.

Functional Designs of Metal oxide for Transparent Electronics

  • Kim, Joondong;Patel, Malkeshkumar;Kim, Hong-Sik;Kim, Hyunki;Yadav, Pankaj;Park, Wanghee;Ban, Dongkyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.387.1-387.1
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    • 2016
  • Transparent materials are necessary for most photoelectric devices, which allow the light generation from electric energy or vice versa. Metal oxides are usual materials for transparent conductors to have high optical transmittance with good electrical properties. Functional designs may apply in various applications, including solar cells, photodetectors, and transparent heaters. Nanoscale structures are effective to drive the incident light into light-absorbing semiconductor layer to improve solar cell performances. Recently, the new metal oxide materials have inaugurated functional device applications. Nickel oxide (NiO) is the strong p-type metal oxide and has been applied for all transparent metal oxide photodetector by combining with n-type ZnO. The abrupt p-NiO/n-ZnO heterojunction device has a high transmittance of 90% for visible light but absorbs almost entire UV wavelength light to show the record fastest photoresponse time of 24 ms. For other applications, NiO has been applied for solar cells and transparent heaters to induce the enhanced performances due to its optical and electrical benefits. We discuss the high possibility of metal oxides for current and future transparent electronic applications.

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Effect of silica coating on bond strength between a gold alloy and metal bracket bonded with chemically cured resin

  • Ryu, Min-Ju;Gang, Sung-Nam;Lim, Sung-Hoon
    • The korean journal of orthodontics
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    • v.44 no.3
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    • pp.105-112
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    • 2014
  • Objective: The purpose of this study was to evaluate the effects of three different surface conditioning methods on the shear bond strength (SBS) of metal brackets bonded directly to gold alloy with chemically cured resin. Methods: Two hundred ten type III gold alloy specimens were randomly divided into six groups according to the combination of three different surface conditioning methods (aluminum oxide sandblasting only, application of a metal primer after aluminum oxide sandblasting, silica coating and silanation) and thermocycling (with thermocycling, without thermocycling). After performing surface conditioning of specimens in accordance with each experimental condition, metal brackets were bonded to all specimens using a chemically cured resin. The SBS was measured at the moment of bracket debonding, and the resin remnants on the specimen surface were evaluated using the adhesive remnant index. Results: Application of metal primer after aluminum oxide sandblasting yielded a higher bond strength than that with aluminum oxide sandblasting alone (p < 0.001), and silica coating and silanation yielded a higher bond strength than that with metal primer after aluminum oxide sandblasting (p < 0.001). There was no significant change in SBS after thermocycling in all groups. Conclusions: With silica coating and silanation, clinically satisfactory bond strength can be attained when metal brackets are directly bonded to gold alloys using a chemically cured resin.

Low Emissivity Property of Amorphous Oxide Multilayer (SIZO/Ag/SIZO) Structure

  • Lee, Sang Yeol
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.1
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    • pp.13-15
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    • 2017
  • Low emissivity glass for high transparency in the visible range and low emissivity in the IR (infrared) range was fabricated and investigated. The multilayers were have been fabricated, and consisted of two outer oxide layers and a middle layer of Ag as a metal layer. Oxide layers were formed by rf sputtering and metal layers were formed using by an evaporator at room temperature. SiInZnO (SIZO) film was used as an oxide layer. The OMO (oxide-metaloxide) structures of SIZO/Ag/SIZO were analyzed by using transmittance, AFM (atomic force microscopye), and XRD (X-ray diffraction). The OMO multilayer structure was designed to investigate the effect of Ag layer thickness on the optical property of the OMO structure.

Production of Fine Metal Oxide Particles in Supercritical Water (초임계수를 이용한 금속산화물 미세입자 제조)

  • Lee, Joo-Heon;Park, Young-Woo
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.173-176
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    • 1999
  • The production of fine metal oxide particles in supercritical water has been studied. Cobalt nitrate solution and manganese nitrate solution have been selected as model solutions for metal salt aqueous solution and the particles of cobalt oxide and manganese oxide have been produced. It was observed that the production of fine metal oxide particles in supercritical water was feasible and the dehydration rate was remarkably high in supercritical water. In spite of a short residence time (3~100 seconds), fine particles ($0.5{\sim}2{\mu}m$) have been produced. In the supercritical water process, the temperature of mixer had a significant effect on particle size and size distribution. It was observed that a change in reaction temperature resulted in the control of particle size.

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Design of a Smart Gas Sensor System for Room Air-Cleaner of Automobile (Thick-Film Metal Oxide Semiconductor Gas Sensor)

  • Kim, Jung-Yoon;Shin, Tae-Zi;Yang, Myung-Kook
    • Journal of Electrical Engineering and Technology
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    • v.2 no.3
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    • pp.408-412
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    • 2007
  • It is almost impossible to secure the reproductibility and stability of a commercial Thick-Film Metal Oxide Semiconductor Gas Sensor since it is very difficult to keep the consistency of the manufacturing environment. Thus it is widely known that the general Semiconductor-Oxide Gas Sensors are not appropriate for precise measurement systems. In this paper, the output characteristic analyzer of the various Thick-Film Metal Oxide Semiconductor Gas Sensors that are used to recognize the air quality within an automobile are proposed and examined. The analyzed output characters in a normal air chamber are grouped by sensor ranks and used to fill out the characteristic table of the Thick-Film Metal Oxide Semiconductor Gas Sensors. The characteristic table is used to determine the rank of the sensor that is equipped in the current air cleaner system of an automobile. The proposed air control system can also adapt the on-demand operation that recognizes the history of the passenger's manual-control.