• Title/Summary/Keyword: Metal hydride

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Characteristics of a Hydrogen Isotope Storage and Accountancy System (수소동위원소 저장 계량 장치 특성 연구)

  • KIM, YEANJIN;JUNG, KWANGJIN;GOO, DAESEO;PARK, JONGCHUL;JEON, MIN-GU;YUN, SEI-HUN;CHUNG, HONGSUK
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.6
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    • pp.541-546
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    • 2015
  • Global energy shortage problem is expected to increase driven by strong energy demand growth from developing countries. Nuclear fusion power offers the prospect of an almost infinite source of energy for future generations. Hydrogen isotope storage and delivery system is a important subsystem of a nuclear fusion fuel cycle. Metal hydride is a method of the high-density storage of hydrogen isotope. For the safety storage of hydrogen isotope, depleted uranium (DU) has been widely proposed. But DU needs a safe test because It is a radioactive substance. The authors studied a small-scale DU bed and a medium-scale DU bed for the safety test. And then we made a large-scale DU bed and stored hydrogen isotopes in the bed. Before the hydriding/dehydriding, we tested it's heating and cooling properties and carried out an activation procedure. As a result, Reaction rate of DU-$H_2$ is more rapid than the other metal hydride ZrCo. Through the successful storage result of our large bed, the development possibility of the hydrogen isotope storage technology seems promising.

Electrochemical Properties of the AB2-type Metal Hydride Electrode Prepared by Ball Milling (Ball milling한 AB2계 금속수소화물 전극의 전기화학적 특성)

  • Choi, Seung-Jun;Shim, Jong-Su;Oh, Se-Ung;Noh, Hak;Choi, Jeon;Seo, Chan-Yeol;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.181-185
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    • 1997
  • The electrochemical properties of the $AB_2$-type (Zr-Ti-V-Ni-Cr-Co-Mn) metal hydride electrodes prepared by ball milling with $AB_5-type\{(LM)Ni_{3.6}Al_{0.4}Co_{0.7}Mn_{0.3}\}$(LM : Lanthanum-rich mischmetal) alloy powder as a surface activator were investigated. By ball milling with $AB_5$ type alloy powder, the activation of $AB_2$ type metal hydride electrode was accelerated resulting in an increase of discharge capacity from 35% to 85% of the maximum capacity at the first cycle. As the amount of surface activator increased the activation rate increased, whereas the discharge capacity increased with 10wt% and decreased with 20wt% addition of the surface activator. When the amount of the surface activator was kept constant as 10wt%, the discharge capacity and the activation rate increased with ball milling time up to 20 hours. However beyond 20 hours of ball milling time, they decreased drastically due to the nano-crystallization or amorphorzation of the alloy powder.

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Analysis of Heat Transfer Characteristics of Metal-Hydride Module for the Actuation of a Rehabilitative System (재활시스템 구동용 수소저장합금 모듈의 열전달 특성 비교 분석)

  • Kim, Kyong;Kim, Seong-Hyun
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.11 no.2
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    • pp.165-171
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    • 2017
  • We suggested the novel actuator mechanism to apply to wearable assistive system for the improvement of quality of life of the elderly or the people with disability using it. Characteristics of metal-hydride (MH) actuator is investigated in the novel actuating concept. The hydrogen equilibrium pressure increases when hydrogen is desorbed by heating a SMH alloys, whereas by cooling that alloys, the hydrogen equilibrium pressure decreases and hydrogen is absorbed. However, there are too long times in heat transfer mechanism to apply the assistive and rehabilitative device. In this study, 3 different SMH module were designed and characteristics of heat transfer in each SMH module were investigated based on the heat simulation.

Operating Strategy Optimization of Metal Hydride based Hydrogen Supply System (수소저장합금을 이용하는 수소공급시스템의 운전 방법 최적화)

  • Kim, Byung-Jun;Sung, Hae-Jung;Lee, Young-Duk;Lee, Sang-Min;Cho, Ju-Hyeong;Ahn, Kook-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.625-633
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    • 2011
  • Characteristics of a commercial metal hydride (MH) hydrogen supply system have been investigated and an operating strategy was developed based on the experimental data. As a prior step, charging/discharging capacity, thermal properties such as heat capacity, heat of reaction of MH system were experimentally measured. And then P-C-T data for various operating conditions were collected and a correlation between P, C and T predicting the behavior of MH was derived. Based on the basic experimental data, an operating strategy of MH system was developed, in which the hot water temperature supplied into the water jacket of MH was controlled depending on the pressure of MH, thereby the pressure of MH could be maintained at a suitable range. By adjusting the temperature of hot water from $40^{\circ}C$ to $60^{\circ}C$, the maximum discharging capacity of hydrogen could be increased by 4.7%, and consequently more stable hydrogen supply and longer operation time of fuel cell system could be achieved.

A Mathematical Model for the Discharge Mechanism of a Metal Hydride Electrode (금속수소 전극의 방전기구에 대한 수학적 모델)

  • Shin, Chee Burm;Hong, Jung Ho;Yun, Kyung Suk;Cho, Byung Won;Cho, Won Il;Jeon, Gui
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.768-773
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    • 1998
  • A mathematical model of discharge mechanism of metal-hydride (MH) electrode was presented. A computer simulation program was developed in order to predict the variation of electrode potential and the distribution of hydrogen concentration within MH particles during discharge. By investigating the effects of the discharge current density, the size of MH particle, the diffusivity of hydrogen in MH particle, and the porosity of the electrode, it was found that these factors exerted a collective effect on the discharge characteristic of the electrode and the utilization of hydrogen in the MH particle. It was confirmed that and optimization of design factors of an MH electrode is necessary in order to execute a high-rate discharge and to improve the utilization of hydrogen in MH particle.

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