• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.309-312
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• 1969

A series of metal ion-2, 5-diamine 1, 4-dihydroxybenzene polymers containing copper(II), nickel(II) or cobalt (II) have been prepared. The structure was postulated on the basis of elementary analysis of polymers. It was found that copper polymer is most likely the coordination polymers by X-ray powder pattern studies. The thermal stability of the polymers was also studied by a simple method, utilizing a thermogravimetric balance. The order of thermal stabilities is Cu(II) > Ni(II) > Co(II). The polymers start to decompose at a relatively low temperature.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.2947-2952
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• 2013

Three coordination polymers, [$ML_2(H_2O)_2$] (M = Co (1), Ni (2), Mn (3)), were prepared from metal acetates ($M(CH_3COO)_2{\cdot}4H_2O$) and 3-pyridinepropionic acid ($HL=(3-py)-CH_2CH_2COOH$) by solvent-layer methods. By contrast, a discrete molecular compound, trans-[$Pd(HL)_2Cl_2$] (4), was synthesized by replacing benzonitrile (PhCN) ligands in trans-[$Pd(PhCN)_2Cl_2$] with HL under microwave-heating conditions. Compounds 1-3 have a 2D framework, and compound 4 contains a square-planar Pd metal.

• Bulletin of the Korean Chemical Society
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• v.26 no.5
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• pp.805-807
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• 2005

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2489-2492
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• 2011

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.1045-1047
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• 2011

• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3875-3878
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• 2012

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.1091-1093
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• 2010

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3727-3732
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• 2013

The interaction between metalloporphyrins and diazine tautomers was investigated using quantum chemistry method. The results showed that the metal atom in the metalloporphyrin was not coplanar with porphin ring, and zinc porphyrin has the most extent of its non-coplanar nature. The most stable complex in nine complexes was iron porphyrin. NBO analysis indicated that the interaction between the lone pair of electrons on the nitrogen atom and the unoccupied lone pair orbital of metal contributes significantly to the stability of the complexes. Through the conceptual DFT parameter and Fukui dual descriptor, the thermodynamic stability and reactivity of complexes were analyzed. The density difference function (DDF) analyzes were performed to explore the rearrangement of electronic density after the coordination interaction. NICS calculation indicated that metalloporphyrin aromaticity was reduced after the coordination interaction, and aromaticity of diazine tautomer was increased along direction vector of the coordination interaction force.

• Journal of Electrical Engineering and Technology
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• v.10 no.3
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• pp.1293-1297
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• 2015

This paper introduces the insulation coordination study results for UHV AC systems which was performed by CIGRE working group. The study results will be discussed within IEC technical committee in order to amend the IEC Insulation Coordination 60071-1 Ed. 8 2010 and 60071-2 Ed. 3, 1996. This paper includes the insulation coordination of transformer, gas insulated switchgear, metal oxide arresters and clearances of transmission towers. This article also illustrates the overvoltage specific to UHV systems such as TOV(temporary overvoltage), switching overvoltage, lightning overvoltage and VFTO(very fast transient overvoltage).

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.153-154
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• 2006

The development of metal catalysts that can polymerize or copolymerize "polar" $Ch_2=CHX$ monomers by insertion mechanisms would significantly expand the scope of metal-catalyzed polymerization and enable the synthesis of new materials with enhanced properties. We have studied the reactions of single-site olefin polymerization catalysts with vinyl chloride, acrylonitrile, and vinyl ethers, in order to probe monomer coordination trends, insertion rates and regioselectivity, and the structures and reactivity of metal alkyls that contain functional groups on the alpha and beta positions of the alkyl chain. These studies provide insights to the key issues that underlie the "polar monomer" problem. Copolymerization of olefins and selected vinyl ethers has been achieved.