• Title/Summary/Keyword: Metal bond

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Low Temperature Cure Film Adhesive

  • Liang, Bin;Zhao, Shenglong
    • Journal of Adhesion and Interface
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    • v.5 no.2
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    • pp.1-7
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    • 2004
  • A novel carboxyl terminated butadiene-acrylonitrile (CTBN) modified, low temperature cure epoxy film adhesive was developed in this paper. It can be cured at as low as $75^{\circ}C$ for 4 hours with a pressure of 0.1MPa. After post cure at $120^{\circ}C$ for 2 hours, the bonding strengths of Phosphoric Acid Anodizing(PAA) surface treated aluminum adherend were similar to those of structural film adhesives curing at $120^{\circ}C$. It is suitable to bond both metal/composite laminate-to-laminate and laminate to honeycomb structure.

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A Study on the Complexation of Copper(Ⅱ) Ion with 2,2-Bis(hydroxymethyl)-2,$2^{\prime},2^{\prime}^{\prime}$-nitrilotriethanol in Aqueous Solution

  • Hong, Gyeong Hui;Ha, Eun Jong;Bae, Gyu Seon
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.406-409
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    • 1995
  • The complex formation from Cu(Ⅱ) ion and 2,2-bis(hydroxymethyl)-2,2',2"-nitrilotriethanol (Bistris) in aqueous solution has been studied potentiometrically and spectrophotometrically. Bistris (L) coordinates to Cu(Ⅱ) as tridentate. The complex CuL2+ undergoes deprotonation in neutral and basic media. The deprotonated complexes involve metal-alcoholate coordinate bond in stable chelate structures.

Thermo mechanical analysis of a ceramic coated piston used in a diesel engine

  • Buyukkaya, Ekrem;Cerit, Muhammet;Coban, Mehmet
    • Steel and Composite Structures
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    • v.21 no.2
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    • pp.429-442
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    • 2016
  • The aim of this paper is to determine temperature and stress distributions in a ceramic based on Partially Stabilized Zirconia coated steel piston crown by using plasma spraying for improving performance of a marine diesel engine. Effects of coating constituent and thickness on temperature and stress distributions were investigated including comparisons with results from an uncoated piston by means of finite element method namely ANSYS. Temperature developed at the coated surface is significantly higher than that of the uncoated piston. The maximum stress components occur between bond coat and adjacent ceramic layer. Provided that coating thickness is constant as 0.5 mm, when numbers of layers increase, magnitude of the normal stress decrease about 34.1% on the base metal surface according to uncoated piston, but the base metal surface temperature of the steel piston increase about 13.1%.

The Hydrogen Binding Property Study by Density Functional Theory for Zr, V, Fe and Al (밀도 함수를 이용한 지르코니움, 바나듐, 철과 수소와의 반응성 연구)

  • Park, Taesung;Lee, Taeckhong
    • Journal of Hydrogen and New Energy
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    • v.25 no.6
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    • pp.602-608
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    • 2014
  • The sequence of bond overlap population of metal hydrogen binding is in Al-H > Fe-H > Zr-H > V-H. This results shows the binding energy of Al-H is the biggest in this metals (Al, Fe, Zr, and V) and hydrogen interaction. The Vanadium-hydrogen binding shows the weakest binding energy compared to other metals and it causes easy hydrogen desorption from the corresponding metals. The net charge of Al-H show the biggest value of 0.2248 and the severe localizations of electrons around aluminum and imply strongest covalent binding nature in these metals. This study is applicable to the purification of hydrogen in other bulk gas.

Dynamics Study with DFT(Density Functional Theory) Calculation for Metal with a few Peripheral Electrons (범밀도함수론을 이용한 백금, 팔라듐, 니켈, 크롬과 수소반응성 연구)

  • Kim, Taewan;Park, Taesung;Jung, Yeonsung;Kang, Youngjin;Lee, Taeckhong
    • Journal of Hydrogen and New Energy
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    • v.25 no.3
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    • pp.234-239
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    • 2014
  • To study catalytic activity and hydrogen embrittlement of Pd, Pt, Ni, and Cr in fuel cell electrode, we used density-functional theory. The calculation tools based electron density give much shorter calculation time and cheap costs. Maximum of bond overlap populations of each metal are 0.6539eV for Pd-H, 0.6711eV for Pt-H, 0.6323eV for Ni-H, 0.6152eV for Cr-H. Electron density of Cr has strongest in related metals, which shows strong localization of electron, implying anti hydrogen embrittlement behaviors.

The Influence of Resin Mixture Ratio for the Use of Prepreg on the Fatigue Behavior Properties in FRMLs

  • Song, Sam-Hong;Kim, Cheol-Woong
    • International Journal of Precision Engineering and Manufacturing
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    • v.1 no.1
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    • pp.33-41
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    • 2000
  • Fiber reinforced metal laminates(FRMLs) were new type of hybrid materials. FRMLs consist of high strength metals(Al 5052-H34) and laminated fiber with structural adhesive bond. The effect of resin mixture ratios on the fatigue crack propagation behavior and mechanical properties of aramid fiber reinforced aluminum composites was investigated. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured with methylene dianiline(MDA) with or without an accelerator(K-54). Eight kinds of resin mixture ratio were used for the experiment ; five kinds of FRMLs(1)(mixture of epoxy and curing agent) and three kinds of FRMLs(2)mixture of epoxy, curing agent and accelerator). The characteristic of fatigue crack propagation behavior and mechanical properties FRMLs(2) shows more effecting than that of FRMLs(1).

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The Dependence of Mechanical Strain on a-Si:H TFTs and Metal Connection Fabricated on Flexible Substrate

  • Lee, M.H.;Ho, K.Y.;Chen, P.C.;Cheng, C.C;Yeh, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.439-442
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    • 2006
  • We evaluated a-Si:H TFTs fabricated on polyimide substrate (PI) at the highest temperature of $160^{\circ}C$ with uniaxial and tensile strain to imitate flexible display. With tensile strain, the threshold voltage of a-Si:H TFTs have positive shift due to extra dangling bond formation in a-Si:H layer. However, no significant degradation of the subthreshold swing and effective mobility with tensile strain of a-Si:H TFTs indicates the similar level of band tail state. The metal wire with the width of $10\;{\mu}m$ for connection on flexible substrate can sustain with curvature radius 2.5 cm.

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A Study on the Development of In-Processor Dressing Lapping Wheel and its Evaluation of Machining Characteristics (연속 전해드레싱용 래핑숫돌 개발 및 성능평가)

  • Choe, Jae-Yeong;Lee, Eun-Sang;Song, Ji-Bok
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.11
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    • pp.132-137
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    • 2001
  • Application of ceramics, carbide, ferrite has grown considerably due to their mechanical properties such as high degree hardness, chemical stability, super wear resistance. Despite these characters, the use of advanced material has not increased because of poor machinability. The application of metal bonded wheel was proposed. But it is difficult that metal bond wheel can be dressed. Recently, to solve this problem, the technology of in-process electrolytic dressing is developed. This method need wheel for electrolytic dressing, power supply and electrolyte. The aim of this study is development of CIB-D wheel for electrolytic and its evaluation of electrolytic characteristics, and achieve ultra-precision lapping of carbide, optic glass.

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The Change of Mechanical Properties on Weld Heat Input in 60kg/mm2 Quenched and Tempered High Strength Steel (60kg/mm2급 조질고장력강의 용접입열량에 따른 기계적 특성 변화)

  • Kim, O.S.;Park, K.C.;Chung, I.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.1
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    • pp.35-43
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    • 1994
  • For the purpose of studying the change of mechanical properties of weld parts, shielded metal are welding, one-pole and two-pole submerged arc welding were accomplished weldability on $60kg/mm^2$ quenched and tempered high strength steel. Charpy impact values of the weld metal in welded parts by SMAW and SAW were lower than those of the heat affected zone and increased in order of bond, coarsened, refined and carbon spheroidized regions in the heat affected zone. Grain size of prior austenite or M-A constituent did not significantly affect toughness of welded parts, but precipitated carbide films which forms at the grain boundaries or within matrix and volume fraction of pearilte were most important factor for toughness.

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The Quality Evaluation on Resistance Spot Welding of 2024 Aluminum Alloy and Zinc Coated Steel (2024 Al합금과 아연도금강판의 점용접에 관한 품질평가)

  • 허인호;이철구;채병대
    • Journal of Welding and Joining
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    • v.19 no.4
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    • pp.379-383
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    • 2001
  • Resistance spot welding has been widely used in the sheet metal joining processes because of low cost, high productivity and convenience. Recently, automobile and aerospace industries are trying to replace partly steel sheets with aluminum alloy sheets. But in the case of dissimilar materials, to apply resistance spot welding has been known to be very difficult owing to the effect of melting temperature. On this study, an effort was made to apply spot welding of dissimilar sheet metals, 2024 aluminum alloy and zinc coated steel sheet, evaluate the spot weld quality with tensile-shear strength test and nondestructive evaluation technique, C-scan image methodology. In this study results, as the current below 11 kA, melting of materials is not achieved well. Also as the current exceeds to 13.5 kA, the more spatters happen at welded zone and tensile-shear strength lowered. So, the feasibility of C-scan image technique proposed in the study is found to be suitable evaluation method for resistance spot weldability.

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