• Journal of Korea Foundry Society
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• v.31 no.5
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• pp.274-283
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• 2011

The vacuum die casting is a promising candidate of the stamping process for fabrication of fuel cell bipolar plate due to its advantages, such as precision casting, mass production and short production time. This study proposes vacuum die casting process to fabricate bipolar plates in fuel cell. Bipolar plates were fabricated under various injection conditions such as molten metal temperature and injection velocity. Also, according to injection velocity conditions, simulation results of MAGMA soft were compared to the experimental results. In case of melt temperature $650^{\circ}C$, misrun occurred. When the melt temperature was $730^{\circ}C$, mechanical properties were low due to dendrite microstructure. Injection velocity has to set at more than 2.0 m/s to fabricate the sound sample. When melt temperature, injection velocity (Fast shot), and vacuum pressure are $700^{\circ}C$, 2.5 m/s and 30 kPa respectively, sample had good formability and few casting defects. Simulation results are mostly in agreement with experimental results.

• Nuclear Engineering and Technology
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• v.45 no.7
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• pp.969-978
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• 2013

A full-sized model for the horizontally oriented metal cask containing 21 spent fuel assemblies has been considered to evaluate the internal natural convection behavior within a dry shield canister (DSC) filled with helium as a working fluid. A variety of two-dimensional CFD numerical investigations using a turbulent model have been performed to evaluate the heat transfer characteristics and the velocity distribution of natural convection inside the canister. The present numerical solutions for a range of Rayleigh number values ($3{\times}10^6{\sim}3{\times}10^7$) and a working fluid of air are further validated by comparing with the experimental data from previous work, and they agreed well with the experimental results. The predicted temperature field has indicated that the peak temperature is located in the second basket from the top along the vertical center line by effects of the natural convection. As the Rayleigh number increases, the convective heat transfer is dominant and the heat transfer due to the local circulation becomes stronger. The heat transfer characteristics show that the Nusselt numbers corresponding to $1.5{\times}10^6$ < Ra < $1.0{\times}10^7$ are proportional to 0.5 power of the Rayleigh number, while the Nusselt numbers for $1.0{\times}10^7$ < Ra < $8.0{\times}10^7$ are proportional to 0.27 power of the Rayleigh number. These results agreed well with the trends of the experimental data for Ra > $1.0{\times}10^7$.

• Journal of Powder Materials
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• v.12 no.2 s.49
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• pp.117-121
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• 2005

Platinum catalysts for the DMFC (Direct Methanol Fuel Cell) were impregnated on several carbon supports and their catalytic activities were evaluated with cyclic voltammograms of methanol electro-oxidation. To increase the activities of the Pt/C catalyst, carbon supports with high electric conductivity such as mesoporous carbon, carbon nanofiber, and carbon nanotube were employed. The Pt/e-CNF (etched carbon nanofiber) catalyst showed higher maximum current density of $70 mA cm^{-2}$ and lower on-set voltage of 0.54 V vs. NHE than the Pt/Vulcan XC-72 in methanol oxidation. Although the carbon named by CNT (carbon nanotube) series turned out to have larger BET surface area than the carbon named by CNF (carbon nanofiber) series, the Pt catalysts supported on the CNT series were less active than those on the CNF series due to their lower electric conductivity and lower availability of pores for Pt loading. Considering that the BET surface area and electric conductivity of the e-CNF were similar to those of the Vulcan XC-72, smaller Pt particle size of the Pt/e-CNF catalyst and stronger metal-support interaction were believed to be the main reason for its higher catalytic activity.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.7
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• pp.2939-2944
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• 2011

The performance and efficiency of a Molten Carbonate Fuel Cell system will improve with the aids of numerical simulations such as finite element analysis. For best simulation results, the virtual model must accurately reflect the actual model including the material properties. It is very difficult, however, to make a detailed numerical model of the stack that consists of hundreds of layers of unit cells composed of various materials like metal, ceramics, polymer, etc. Instead, a practical approach is to find a homogenized material property of the stack as a whole as an approximate replacement. In this paper, the compression ratio of a unit cell is introduced, and a new method is proposed to estimate the homogeneous material properties for both the active and the manifold regions of the stack under the assumption that the compressive deformation occurs only at the separators and matrices in the unit cells. The estimated properties are applied successfully to simulating an actual stack.

• Nuclear Engineering and Technology
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• v.39 no.3
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• pp.193-206
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• 2007

The Korea Atomic Energy Research Institute has developed an advanced fast reactor concept, KALIMER-600, which satisfies the Generation IV reactor design goals of sustainability, economics, safety, and proliferation resistance. The concept enables an efficient utilization of uranium resources and a reduction of the radioactive waste. The core design has been developed with a strong emphasis on proliferation resistance by adopting a single enrichment fuel without blanket assemblies. In addition, a passive residual heat removal system, shortened intermediate heat-transport system piping and seismic isolation have been realized in the reactor system design as enhancements to its safety and economics. The inherent safety characteristics of the KALIMER-600 design have been confirmed by a safety analysis of its bounding events. Research on important thermal-hydraulic phenomena and sensing technologies were performed to support the design study. The integrity of the reactor head against creep fatigue was confirmed using a CFD method, and a model for density-wave instability in a helical-coiled steam generator was developed. Gas entrainment on an agitating pool surface was investigated and an experimental correlation on a critical entrainment condition was obtained. An experimental study on sodium-water reactions was also performed to validate the developed SELPSTA code, which predicts the data accurately. An acoustic leak detection method utilizing a neural network and signal processing units were developed and applied successfully for the detection of a signal up to a noise level of -20 dB. Waveguide sensor visualization technology is being developed to inspect the reactor internals and fuel subassemblies. These research and developmental efforts contribute significantly to enhance the safety, economics, and efficiency of the KALIMER-600 design concept.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.50 no.3
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• pp.326-333
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• 2014

This study was conducted to investigate the fishing efficiency of an improved LED fishing lamp for squids. A total of 31 fishing operations were carried out with six-crew commercial fishing vessel Haengbok-Ho (24 tons) on which 43.2kW LED was installed, along with 14 automatic jigging machines, from October 6 to November 16, 2012. The 19 fishing vessels with Haengbok-Ho were compared with a control subject was 24 tons or 29 tons. A total illuminating power of metal halide (MH) fishing lamps in the control fishing vessel was either 84kW or 120kW. The number of automatic jigging machines in the control vessels was 8-18 and the number of crews engaged for fishing operation was 3-13. Average fuel consumption of LED fishing vessels during fishing operation was 505.1l which led to an average fuel consumption of 42.7l per hour. LED fishing vessel and MH fishing vessel caught on an average 1,946 squids and 2,439 squids, respectively, during the study period. Crews (hand line and hand reel) caught about 2.2 times the automatic jigging machines for LED fishing vessel and about 2.1 times for MH fishing vessel. Meanwhile, catches by the fishing vessels with LED in the combined total number per one line of automatic jigging machine and per crew were 86.6% of that of the control fishing vessel with MH. Also, fishing vessels with LED per automatic jigging machine achieved 71.8% of catches of that with MH fishing lamp. The catches of squids per the fishing vessel with 1W LED fishing lamp were higher by more than 135.5% of that in the fishing vessel with MH, which showed a good fishing performance even with only the use of a LED fishing lamp.

• Resources Recycling
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• v.20 no.2
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• pp.67-73
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• 2011

In this study, for recovery of renewable noble metal from used stack of fuel cell, synthesis of platinum nano particle is established through effect of platinum solution concentration, pH value, reducing agent and dispersing agent at a volume ratio of 1 mM $H_2PtCl_6$:10 mM $NaBH_4$:8 mM Cl4TABr = 1:0.4:0.4(vol.%), pH4, $50^{\circ}C$, 160 rpm and 10min. Less than 5 nm platinum particles were synthesized using Pt leaching solution from used MEA of stack under same condition of method using simulated Pt solution. The characteristics of synthesized nano particles was illustrated by XPS analysis as the reduction of platinum ions into platinum metals(zero-valent).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.5
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• pp.554-560
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• 2021

CRUD (chalk river unidentified deposits) is a porous material deposited on the surface of nuclear fuel during nuclear power plant operation. The CRUD is composed of metal oxides, such as iron, nickel, and chromium. It is essential to investigate the effects of the CRUD layer on the wall heat transfer between the nuclear fuel surface and the coolant in the event of a nuclear accident. CRUD only negatively affects the temperature of the nuclear fuel due to heat resistance because the effects of the CRUD layer on two-phase boiling heat transfer are not considered. In this study, the physical property models for the porous CRUD layer were developed and implemented into the SPACE code. The effects of boiling heat transfer models on the peak cladding temperature and quenching were investigated by simulating a reflood experiment. The calculation results showed some positive effects of the CRUD layer.

• Korean Journal of Materials Research
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• v.28 no.11
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• pp.633-639
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• 2018

In anion exchange membrane fuel cells, Pd nanoparticles are extensively studied as promising non-Pt catalysts due to their electronic structure similar to Pt. In this study, to fabricate Pd nanoparticles well dispersed on carbon support materials, we propose a synthetic strategy using mixed organic ligands with different chemical structures and functions. Simultaneously to control the Pd particle size and dispersion, a ligand mixture composed of oleylamine(OA) and trioctylphosphine(TOP) is utilized during thermal decomposition of Pd precursors. In the ligand mixture, OA serves mainly as a reducing agent rather than a stabilizer since TOP, which has a bulky structure, more strongly interacts with the Pd metal surface as a stabilizer compared to OA. The specific roles of OA and TOP in the Pd nanoparticle synthesis are studied according to the mixture composition, and the oxygen reduction reaction(ORR) activity and durability of highly-dispersed Pd nanocatalysts with different particles sizes are investigated. The results of this study confirm that the Pd nanocatalyst with large particles has high durability compared to the nanocatalyst with small Pd nanoparticles during the accelerated degradation tests although they initially indicated similar ORR performance.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.5
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• pp.69-75
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• 2021

Fuel economy has always been a major issue for the automotive industry due to environmental concerns. In particular, it is known that only 5-20% of the energy generated in a car that mainly uses an internal combustion engine is converted to increase fuel efficiency, many methods have been proposed. Among these methods, weight reduction is most commonly used because it is the simplest and cheapest. Weight is always the main reason for energy consumption, therefore, reducing weight is the best way to increase fuel efficiency while simultaneously saving on material costs. To reduce the weight of a compressor, material substitution is used. However, aluminum (a lighter metal substitute) is more fragile than steel, therefore, structural stability must be verified through testing. In this paper, we performed a 3D analysis to investigate whether aluminum can be used without compromising structural stability. Our investigation included static analysis and thermal analysis. As a result, we found that an aluminum swash plate can be safely applied on a shaft instead of steel; it reduces weight while maintaining stability that is equal to or better than steel.