• Title/Summary/Keyword: Metal Electrode

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Influence on Metal Removal Rate by Material and Size Difference of the Electrode (전극의 재료와 크기가 방전가공량에 미치는 영향)

  • 김희중
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.6
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    • pp.809-815
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    • 1998
  • This study has been performed to investigate MRR(metal removal rate) surface roughness with various pulse-on duration using the copper and graphite electrode according to the electrode size on the heat treated STD 11 which is extensively used for metallic molding steel in the EDM. The results obtained are as follow ;a)MRR increases a lot when pulse-on duration is 100 $\mu{s}$ or less but MRR has little difference with pulse-on duration of 100 $\mu{s}$ or more b) According to the increase of Pulse-on duration the large the electrode size the more MRR c) Safe discharge is needed to make maximum of MRR and the metallic organization must be complicated for discharge induction. d) Actual machining time is longer than theoretical machining time at the short pulse-on duration because of skin effect of current. e) Graphite electrode needs the larger electric discharge energy than copper electrode to remove remained chips completely.

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Reliability of Metal Electrode for Flexible Electronics (유연성 소자용 금속 전극의 신뢰성 연구 동향)

  • Kim, Byoung-Joon
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.4
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    • pp.1-6
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    • 2013
  • Recently, various types of flexible devices such as flexible displays, batteries, e-skins and solar cell panels have been reported. Most of the researches focus on the development of high performance flexible device. However, to realize these flexible devices, the long-term reliability should be guaranteed during the repeated deformations of flexible devices because the direct mechanical stress would be applied on the electronic devices unlike the rigid Si-based devices. Among various materials consisting electronics devices, metal electrode is one of the weakest parts against mechanical deformation because the mechanical and electrical properties of metal films degrade gradually due to fatigue damage during repeated deformations. This article reviews the researches of fatigue behavior of thin metal film, and introduces the methods to enhance the reliability of metal electrode for flexible device.

A Study for Remediation of Heavy Metal Contaminated Soil Using Electrokinetics with Swappable Electrode (전극변환 동전기를 이용한 중금속 오염토양 처리에 관한 연구)

  • Choi, Heechol;Lee, Tae-Jin
    • Journal of Soil and Groundwater Environment
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    • v.17 no.5
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    • pp.75-81
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    • 2012
  • In this study, remediation of heavy metal contaminated soil was attempted by the electrokinetic process equipped with fixed or swappable electrode. Copper was more effectively removed with EDTA than citric acid. Zinc was much more removed than copper with both detergents. When electrokinetic with fixed electrode and detergents were applied to the contaminated soil, copper was removed about 28.52%~35.25% and zinc was removed about 63.44%~71.48%. When electrokinetics with swappable electrode and detergents were applied to the contaminated soil, the pseudo-first order reaction constants was higher about 16~50% than with fixed electrode in the case of zinc. It is conclusive that electrokinetics with swappable electrode could be an effective method for the remediation of heavy metal contaminated soil.

Comparison of Metal Transfer Behavior in Electrodes for Shielded Metal Arc Welding

  • Xu, X.;Liu, S.;Bang, K.S.
    • International Journal of Korean Welding Society
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    • v.4 no.1
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    • pp.15-22
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    • 2004
  • Metal transfer behavior of three shielded metal arc welding electrodes, AWS El1018, E6013 and E6010, were investigated through the characterization of size distribution of droplets and measurement of arc voltage signals. Of the three electrodes, Ell018 electrode showed the largest droplet size with the smallest amount of spatter, while E6010 electrode showed the smallest droplet size with the largest amount of spatter. Even though Ell0l8 electrode showed a good agreement between the frequencies of voltage drop in FFT processed voltage signals and the transfer rate of droplets, E6013 and E6010 electrodes showed weaker correlation because of their dominant explosive transfer behavior. The type of cathode used and electrode baking time also influenced the metal transfer behavior. Compared to bead-on-plate welding using steel plate as a cathode, welding on a water-cooled copper pipe showed less short-circuiting and higher melting rate in all electrodes because of higher arc potential and/or anode drop. When baked for a long time, E6010 electrode showed much more stable arc with less short-circuiting and explosion due to the loss of gas formation ingredients.

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Study on the Anode Electrode Reaction in the Metal-Air Cell (금속-공기전지의 Anode전극 반응에 관한 연구)

  • Kim, Yong-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.1002-1006
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    • 2010
  • In this study, magnesium (Mg), zinc (Zn) and aluminium (Al) as anode electrode and the solution of NaCl dissolved with 2~20 wt% as electrolytes were used for the metal-air cell. The open circuit voltage, short circuit current and I-V characteristics upon different kinds of anode electrode and electrolyte concentration were investigated. The open circuit voltage, initially about 1.45 V, rises to 1.6 V during the first 10 minutes indicating the necessity of an induction time to activate the catalyst on the air cathode. The short circuit current increases with an increased concentration of NaCl, causes an increase in the conductivity of the electrolyte solution, but the open circuit voltage did not under undergo influence of electrolyte. From NaCl 20 wt% electrolyte, the maximum output power of the magnesium electrode materials was measured with 177mW. It is found that the power characteristics of metal-air cell could be improved by using magnesium electrode materials in the NaCl electrolyte.

Resistance Switching Characteristics of Metal/TaOx/Pt with Oxidation degree of metal electrodes

  • Na, Hee-Do;Kim, Jong-Gi;Sohn, Hyun-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.187-187
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    • 2010
  • In this study, we investigated the effect of electrodes on resistance switching of TaOx film. Pt, Ni, TiN, Ti and Al metal electrodes having the different oxidation degree were deposited on TaOx/Pt stack. Unipolar resistance switching behavior in Pt or Ni/TaOx/Pt MIM stacks was investigated, but bipolar resistance switching behavior in TiN, Ti or Al /TaOx/Pt MIM stacks was shown. We investigated that the voltage dependence of capacitance was decreased with higher oxidation degree of metal electrodes. Through the C-V results, we expected that linearity ($\alpha$) and quadratic ($\beta$) coefficient was reduced with an increase of interface layer between top electrode and Tantalum oxide. Transmission Electron Microscope (TEM) images depicted the thickness of interface layer formed with different oxidation degree of top electrode. Unipolar resistance switching behavior shown in lower oxidation degree of top electrode was expected to be generated by the formation of the conducting path in TaOx film. But redox reaction in interface between top electrode and Tantalum oxide may play an important role on bipolar resistance switching behavior exhibited in higher oxidation degree of top electrode. We expected that the resistance switching characteristics were determined by oxidation degree of metal electrodes.

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Au/Ag Bilayer Electrode for Perovskite Solar Cells (Au/Ag 이중층 전극 구조를 이용한 페로브스카이트 태양전지)

  • Lee, Junyeong;Jo, Sungjin
    • Korean Journal of Materials Research
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    • v.32 no.1
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    • pp.51-55
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    • 2022
  • Generally, Au electrodes are the preferred top metal electrodes in most perovskite solar cells (PSCs) because of their appropriate work function for hole transportation and their resistance to metal-halide formation. However, for the commercialization of PSCs, the development of alternative metal electrodes for Au is essential to decrease their fabrication cost. Ag electrodes are considered one of the most suitable alternatives for Au electrodes because they are relatively cheaper and can provide the necessary stability for oxidation. However, Ag electrodes require an aging-induced recovery process and react with halides from perovskite layers. Herein, we propose a bilayer Au/Ag electrode to overcome the limitations of single Au and Ag metal electrodes. The performance of PSCs based on bilayer electrodes is comparable to that of PSCs with Au electrodes. Furthermore, by using the bilayer electrode, we can eliminate the aging process, normally an essential process for Ag electrodes. This study not only demonstrates an effective method to substitute for expensive Au electrodes but also provides a possibility to overcome the limitations of Ag electrodes.

A Study on Contact Arc Metal Cutting for Dismantling of Reactor Pressure Vessel (원자로 해체를 위한 수중 아크 금속 절단기술에 대한 연구)

  • Kim, Chan Kyu;Moon, Do Yeong;Moon, Il Woo;Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.1
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    • pp.22-27
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    • 2022
  • In accordance with the growing trend of decommissioning nuclear facilities, research on the cutting process is actively proceeding worldwide. In general, a thermal cutting process, such as plasma cutting is applied to decommissioning a nuclear reactor pressure vessel (RPV). Plasma cutting has the advantage of removing the radioactive materials and being able to cut thick materials. However, when operating under water, the molten metal remains in the cut plane and re-solidifies. Hence, cutting is not entirely accomplished. For these environmental reasons, it is difficult to cut thick metal. The contact arc metal cutting (CAMC) process can be used to cut thick metal under water. CAMC is a process that cuts metal using a plate-shaped electrode based on a high-current arc plasma heat source. During the cutting process, high-pressure water is sprayed from the electrode to remove the molten metal, known as rinsing. As the CAMC is conducted without using a shielding gas, such as Argon, the electrode is consumed during the process. In this study, CAMC is introduced as a method for dismantling nuclear vessels and the relationship between the metal removal and electrode consumption is investigated according to the cutting conditions.

On eliminating electrochemical impedance signal noise using Li metal in a non-aqueous electrolyte for Li ion secondary batteries

  • Park, Chul-Wan
    • Carbon letters
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    • v.12 no.3
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    • pp.180-183
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    • 2011
  • Li metal is accepted as a good counter electrode for electrochemical impedance spectroscopy (EIS) as the active material in Li-ion and Li-ion polymer batteries. We examined the existence of signal noise from a Li-metal counter quantitatively as a preliminary study. We suggest an electrochemical cell with one switchable electrode to obtain the exact impedance signal of active materials. To verify the effectiveness of the switchable electrode, EIS measurements of the solid electrolyte interphase (SEI) before severe $Li^+$ intercalation to SFG6 graphite (at > ca. 0.25 V vs. Li/$Li^+$) were taken. As a result, the EIS spectra without the signal of Li metal were obtained and analyzed successfully for the following parameters i) $Li^+$ conduction in the electrolyte, ii) the geometric resistance and constant phase element of the electrode (insensitive to the voltage), iii) the interfacial behavior of the SEI related to the $Li^+$ transfer and residence throughout the near-surface (sensitive to voltage), and iv) the term reflecting the differential limiting capacitance of $Li^+$ in the graphite lattice.

Dependance on Metal Electrode of Poly(3-hexylthiophene) EL Device (Poly(3-hexylthiophene) 발광소자의 금속전극 의존성)

  • 서부완;김주승;김형곤;이경섭;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.162-165
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    • 2000
  • To investigate the effect of metal electrode in electroluminescent[EL] devices, we fabricated EL devices of ITO/P3HT/Al, ITO/P3HT/LiF/Al and ITO/P3HT/Mg:In structure. In current-voltage-light power characteristics, turn-on voltage of EL devices using LiF insulating layer and Mg:In(2.8V) metal electrode is lower than EL device using Al(4.2V). Besides the external quantum efficiency is improved also. The reason is related to carrier mobility and carrier injection, which would affect the hole-electron balance. In the device with Al electrode, holes injected from indium-tin-oxide[ITO] to poly(3-hexylthiophene)[P3HT] might reach the Al electrode without interacting with injected electrons, because the electron injection efficiency was very low for this electrode. Besides oxidation of the Al electrode is likely due to holes reaching the cathode without meeting injected electrons. Another possible reason for the higher EL efficiency may be the insulating layer playing the role of a tunneling barrier for holes to the Al electrode. In all EL devices, the orange-red light was clearly visible in a dark room. Maximum peak wavelength of EL spectrum emitted at 640nm in accordance with photon energy 1.9eV

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