• Title/Summary/Keyword: Membrane inlet

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Removal/Recovery of VOCs Using a Rubbery Polymeric Membrane (Rubbery 고분가 막을 이용한 휘발성 유기화학물의 제거 및 회수)

  • Cha, Jun-Seok
    • Membrane Journal
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    • v.6 no.3
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    • pp.173-181
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    • 1996
  • Common volatile organic compounds(VOCs) such as toluene and methanol were removed successfully from N$_{2}$ using a novel silicone-coated hollow fiber membrane module. This novel membrane is a thin film composite(TFC) and was highly efficient in removing VOCs selectively from a N$_{2}$ stream. This membrane had some innate advantages over other silicone-based membrane in that the selective barrier was ultrathin(~1 $\mu$m) and the porosity of the polypropylene substrate was high which leads to a low permeation resistance. The substram was very strongly bonded to the coating layer by plasma polymerization and can withstand a very high pressure. A small hollow fiber module having a length of 25cm and 50 fibers could remove 96~99% of toluene as well as methanol vapors when the feed flow rate was up to 60cc/min. The percent removal of VOCs were even higher when the feed inlet concentration was higher. This process is especially suitable for treating streams having a low flow rate and high VOCs concentration. The permeances of VOCs through this membrane was in the range of $4~30 \times 10^{-9}gmol/sec \cdot cm^{2}\cdot cmHg$ for both toluene and methanol, and nitrogen permeance was between $3~9 \times 10^{-10}gmol/sec \cdot cm^{2} \cdot cmHg$. High separation factor between 10~55 for toluene/N$_{2}$ and 15~125 for methanol/N$_{2}$ were obtained depending on the feed flow rate ranges and feed VOCs concentration levels.

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Position-Dependent Cathode Degradation of Large Scale Membrane Electrode Assembly for Direct Methanol Fuel Cell (직접 메탄올 연료전지용 대면적 막-전극 접합체 공기극의 위치별 열화 현상)

  • Kim, Soo-Kil;Lee, Eun-Sook;Kim, Yi-Young;Kim, Jang-Mi;Joh, Han-Ik;Ha, Heung-Yong
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.148-154
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    • 2009
  • With respect to the durability of large scale ($150cm^2$) membrane electrode assembly (MEA) of direct methanol fuel cell (DMFC), degradation phenomena at cathode is monitored and analyzed according to the position on the cathode surface. After constant current mode operation of large scale MEA for 500 hr, the MEA is divided into three parts along the cathode channel; (close to) inlet, middle, and (close to) outlet. The performance of each MEA is tested and it is revealed that the MEA from the cathode outlet of large MEA shows the worst performance. This is due to the catalyst degradation and GDL delamination caused by flooding at cathode outlet of large MEA during the 500 hr operation. Particularly on the catalyst degradation, the loss of electrochemically active surface area (ECSA) of catalyst gets worse along the cathode channel from inlet to outlet, of which the reason is believed to be loss of catalysts by dissolution and migration rather than their agglomeration. The extent of loss in the performance and catalyst degradation has strong relation to the cathode flooding and it is required to develop proper water management techniques and separator channel design to control the flooding.

A Multicellular Spheroid Formation and Extraction Chip Using Removable Cell Trapping Barriers (한시적 세포포집 구조물을 이용한 다세포 스페로이드 형성 및 추출칩)

  • Jin, Hye-Jin;Kim, Tae-Yoon;Cho, Young-Ho;Gu, Jin-Mo;Kim, Jhin-Gook;Oh, Yong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.2
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    • pp.131-134
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    • 2011
  • We propose a spheroid chip that uses removable cell trapping barriers and that is capable of forming and extracting multicellular spheroids. By using a conventional well plate and flask, it is difficult to form small-sized spheroids, which resemble avascular 3D cell-cell interaction. It was difficult to extract spheroids using conventional microchips and fixed cell trapping barriers. The proposed chip, however, facilitates both formation and extraction of spheroids by using removable cell trapping barriers formed by membrane deflection. The cell trapping barriers, formed at the membrane pressure of 50 kPa, hold the cells in the trapping region at a cell inlet pressure of 145.155 Pa. After incubation for 24 h, the trapped cells form uniform spheroids. We successfully extract the spheroids at a cell inlet pressure of 5 kPa after removing the membrane pressure. The extracted spheroids have a diameter of $197.2{\pm}11.7Bm$ with a viability of $80.3{\pm}7.7%$. Using the proposed chip, uniform spheroids can be formed and these spheroids can be safely extracted for carrying out the post-processing of spheroids.

Degradation of Membrane With Pinholes in PEMFC (고분자 전해질 연료전지에서 Pinhole 있는 막의 열화)

  • Kim, Tae-Hee;Lee, Ho;Lim, Tae-Won;Park, Kwon-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.2
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    • pp.103-110
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    • 2008
  • The most failure mode of PEM fuel cell is gas crossover caused by pinhole formation in MEAs. The degradation phenomena of MEA with pinholes were evaluated in various accelerated operation condition, such as OCV, low humidity and high partial pressure of oxygen. The performances of MEA with pinholes were almost same before and after normal 144 hours operation($70^{\circ}C$, $640mA/cm^2$, 65%RH $H_2/air$). The results of accelerated operation showed that OCV and low humidity condition more deteriorated MEA than gas crossover owing to pinholes. When oxygen was used as cathode gas, the pinholes of MEA were enlarged due to heat of combustion reaction on Pt catalyst of electrodes. This combustion reaction occurred at pinholes near gas inlet and resulted in local MEA failure.

Development of Constant Delivery Micro Pump in a Variable Pressure Environment for Intrathecal Drug Administration System (레져버에 압력이 가해지는 환경에서의 미소 정량 토출 펌프의 개발)

  • Lee, Tae Gyeong;Lee, Cheol Su;Jung, Yu Seok;Park, Gyeong Geun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.26 no.4
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    • pp.387-394
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    • 2017
  • This paper develops a pump system for patient with chronic pain or cancer. The pump module is consists of two micro-valve and membrane. The micro-valve is operated by a solenoid. With two solenoid valves which are connected via a drug transport line, the inlet and outlet are completely blocked. A silicon rubber membrane located between the two valves makes the flow-rate constant without any backflow. This pump module can control the flow-rate of drugs by controlling the time that the valves are opened and closed. The reservoir consists of a drug chamber and a gas chamber. As the gas chamber encloses the drug chamber, propellant gas which is injected into the gas chamber pressurizes the drug chamber regardless of volume of the drug chamber. To design the pump module, analysis a constant efficiency test, and accuracy test for the pump module were conducted.

Experimental Study on the Characteristics of Heat Exchanger of 1 kW PEMFC System for UAV (무인항공기용 고분자전해질형 연료전지 시스템의 열교환기 성능 특성 연구)

  • Kang, Sang-Gyu;Kim, Byung-Jun;Kim, Han-Seok
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.819-826
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    • 2011
  • The proton exchange membrane fuel cell (PEMFC) is regarded as the most promising alternative power sources for unmanned aerial vehicle (UAV) due to its high energy density and silent operation. Since there are many load changes during UAV flight, thermal management is one of the important factor for the performance of PEMFC. In order to reduce the UAV weight for the stable operation of UAV, thermal management system (TMS) studied in this work does not use the fan but use the air flowing into UAV by UAV flight. In order to develop the passive type heat exchanger (HEX) for 1kW PEMFC, four types of HEXs are fabricated and their cooling performances are compared. The parametric study on the cooling performance of HEXs has performed with the variation of operating parameters such as mass flow rates and inlet temperature of air and coolant. Type 4 has the best performance in every case. This study can be helpful to achieve the optimal design of HEX for PEMFC powered UAV.

Measurements of Thermal Characteristics for a Micro-Fabricated Thermal Mass Air Flow Sensor With Real-Time Controller (실시간 제어기를 이용한 마이크로 열식 질량공기 유량센서의 열특성 측정)

  • Park, Byung-Kyu;Lee, Joon-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.8
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    • pp.573-579
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    • 2009
  • A thermal mass air flow sensor, which consists of a micro-heater and thermal sensors on the silicon-nitride thin membrane structure, is micro-fabricated by MEMS processes. Three thermo-resistive sensors, one for the measurement of microheater temperature, the others for the measurement of membrane temperature upstream and downstream of the micro-heater respectively, are used. The micro-heater is operated under the constant temperature difference mode via a real time controller, based on inlet air temperature. Two design models for microfabricated flow sensor are compared with experimental results and confirmed their applicabilities and limitations. The thermal characteristics are measured to find the best flow indicator. It is found that two normalized temperature indicators can be adopted with some advantages in practice. The flow sensor with this control mode can be adopted for wide capability of high speed and sensitivity in the very low and medium velocity ranges.

Electrical Discharge Plasma in a Porous Ceramic Membrane-supported Catalyst for the Decomposition of a Volatile Organic Compound (다공질 세라믹지지 촉매 상에서의 플라즈마 방전을 이용한 휘발성유기화합물의 분해)

  • Jo, Jin-Oh;Lee, Sang Baek;Jang, Dong Lyong;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.433-437
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    • 2013
  • Electrical discharge plasma created in a multi-channel porous ceramic membrane-supported catalyst was applied to the decomposition of a volatile organic compound (VOC). For the purpose of improving the oxidation capability, the ceramic membrane used as a low-pressure drop catalyst support was loaded with zinc oxide photocatalyst by the incipient wetness impregnation method. Alternating current-driven discharge plasma was created inside the porous ceramic membrane to produce reactive species such as radicals, ozone, ions and excited molecules available for the decomposition of VOC. As the voltage supplied to the reactor increased, the plasma discharge gradually propagated in the radial direction, creating an uniform plasma in the entire ceramic membrane above a certain voltage. Ethylene was used as a model VOC. The ethylene decomposition efficiency was examined with experimental variables such as the specific energy density, inlet ethylene concentration and zinc oxide loading. When compared at the identical energy density, the decomposition efficiency obtained with the zinc oxide-loaded ceramic membrane was substantially higher than that of the bare membrane case. Both nitrogen and oxygen played an important role in initiating the decomposition of ethylene. The rate of the decomposition is governed by the quantity of reactive species generated by the plasma, and a strong dependence of the decomposition efficiency on the initial concentration was observed.

Identification of Fouling Phenomena and Establishment for Optimized Removal Process of Alginic Acid Sodium Salt Through Capacitive Deionization (CDI 공정에서 Alginic Acid Sodium Salt의 파울링 현상 확인 및 제거 조건 확립)

  • Lee, Jin Yeon;Rhim, Ji Won
    • Membrane Journal
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    • v.30 no.5
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    • pp.342-349
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    • 2020
  • In this study, we suggest conditions to reduce fouling in capacitive deionization (CDI) caused by alginic acid sodium salt, one of the most common fouling-causing substances in natural water and wastewater management. First, NaCl is used as feed material, which is selected as the control of the experiment. As expected, fouling phenomena is not observed from NaCl. On the other hand, when alginic acid sodium salt is added to the inlet, the fouling phenomena can be observed. In order to minimize the fouling phenomena, the feed concentration of alginic acid sodium salt, applied potential during desorption process, and duration of applied potential to our CDI cell are controlled. With 7 mg/L of feed stream concentration, CDI performed using 1.2 V for 1 min during adsorption followed by desorption with -2 V for 1 min exhibited the highest alginic acid salt removal efficiency reaching 50.07%.

On the Flow and Pumping Characteristics of a Thermopneumatic Micropump with Electromagnetic Resistance for Electrically Conducting Fluids (전자기 저항을 이용한 열공압형 마이크로 펌프에서 통전유체의 유동 및 펌핑 특성에 관한 연구)

  • Oh, Se-Hong;Yong, Jung-Kwon;Kim, Chang-Nyung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.1
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    • pp.23-31
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    • 2011
  • An analysis has been conducted of the flow characteristics and pumping performance of a thermopneumatic micropump with electrically conducting fluid. In the present study, considered is a thermopneumatic micropump for electrically conducting fluids with electromagnetic resistance alternately exerted at the inlet and outlet by alternately applied magnetic fields. A model of Prescribed Deformation is used for the motion of the membrane. Here, the pumping performance of the micropump and flow characteristics of the electrically conducting fluid are investigated in the range of Hartmann number less than 30. The current numerical study shows that the net flow rate through the micropump is almost proportional to the strength of the applied magnetic field.