• 제목/요약/키워드: Melting point

검색결과 843건 처리시간 0.028초

Characterization of PVDF-DBP Materials for Thermally Induced Phase Separation (열유도상분리법 적용을 위한 PVDF-DBP 소재의 특성평가)

  • Kim, Se Jong;Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • 제26권6호
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    • pp.449-457
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    • 2016
  • In this study, polyvinylidene fluoride (PVDF) membrane with excellent mechanical properties and chemical resistance was prepared and characterized for the application of water treatment. Dibutyl-phthalate (DBP) was used as a diluent for making a membranes through temperature induced phase separation (TIPS) method, and the crystallization temperature, melting point, cloud point and SEM image were observed with different ratio of diluent in polymer/diluent mixture. The crystallization temperature and melting point increased proportionally with the content of polymer, while the cloud point temperature decreased. Finally, it was confirmed that stable membrane could be manufactured at a polymer content of 62 wt% and a temperature $125^{\circ}C$ using the phase diagram of PVDF/DBP mixtures with temperatures.

Numerical Investigation on the Urea Melting Characteristics with Coolant and Electric Heaters (냉각수 및 전기 가열 방식에 따른 요소수 해동 특성에 관한 수치해석 연구)

  • Lee, Seung Yeop;Kim, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제40권1호
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    • pp.1-7
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    • 2016
  • A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.

Instability and Transition of Nonparallel Bouyancy-Induced Flows Adjacent to an Ice Surface Melting in Water (얼음 벽면의 융해율을 고려한 비평행 자연대류에서 유동의 불안정성과 천이에 관한 연구)

  • Hwang, Y.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • 제8권3호
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    • pp.437-450
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    • 1996
  • A set of stability equations is formulated for natural convection flows adjacent to a vertical isothermal surface melting in cold pure water. It takes account of the nonparallelism of the base flows. The melting rate is regarded as a blowing velocity at the ice surface. The numerical solutions of the linear stability equations which constitute a two-point boundary value problem are accurately obtained for various values of the density extremum parameter $R=(T_m-T_{\infty})/(T_0-T_{\infty})$ in the range $0.3{\leq}R{\leq}0.6$, by using a computer code COLNEW. The blowing effects on the base flow becomes more significant as ambient temperature ($T_{\infty}$) increases to $T_{\infty}=10^{\circ}C$. The maximum decrease of heat transfer rate is about 6.4 percent. The stability results show that the melting at surface causes the critical Grashof number $G^*$ and the maximum frequency of disturbances to decrease. In comparision with the results for the conventional parallel flow model, the nonparallel flow model has a higher critical Grashof number but has lower amplification rates of disturbances than does the parallel flow model. The spatial amplification contours exhibit that the selective frequency $B_0$ of the nonparallel flow model is higher than that of the parallel flow model and that the effects of melting are rather small. The present study also indicates that the selective frequency $B_0$ can be easily predicted by the value of the frequency parameter $B^*$ at $G^*$, which comes from the neutral stability results of the nonparallel flow model.

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A study on the comparative test of chemical and thermal properties of virgin and recycled PET products (버진 및 리사이클 PET 제품의 화학적·열적 특성 비교시험에 관한 연구)

  • Kim, Kyoung Pil;Seo, Kyung Jin;Park, Soo-Yong;Chung, Ildoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제22권2호
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    • pp.33-39
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    • 2021
  • As the interest and demand in the recycled yarn field has increased rapidly worldwide, domestic companies are also promoting research and development and business on recycled yarn. The chemical and thermal properties of four types of virgin and recycled PET samples from A and B company, which are the leading domestic companies in the recycled polyester yarn business, were confirmed through infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC). Virgin and recycled PET from two companies were compared. FT-IR spectroscopy revealed the typical spectra of PET for both companies and a different peak at 872 cm-1. DSC confirmed that the melting point and crystallization temperature of recycled PET were lower than those of virgin PET. These results indicate that small amounts of contaminants are an important parameter affecting the thermal properties of recycled PET. In the DSC results after seven repeats of the heating and cooling processes, all four samples showed that a lower melting point, crystallization temperature, and low heat flow intensity increased with increasing number of cycles. The results of melting and crystallization enthalpy also showed similar patterns.

Joining strength improvement studies on Fe-Al laser weldment (Fe-Al 레이저 용접시 접합강도 향상에 관한 연구)

  • Ju Seong-Min;Kim Yeong-Pyo;O Jong-In;Rajesh S.R;Bang Han-Seo
    • Proceedings of the KWS Conference
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    • 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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    • pp.126-128
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    • 2004
  • Welding or joining of dissimilar material is difficult and have limitations because physical properties of each material like melting temperature, heat expansion coefficient, conductivity, yielding point, etc. are different. (omitted)

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