• Korea-Australia Rheology Journal
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• 제19권4호
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• pp.183-190
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• 2007

Injection molding is one of the most common operations in polymer processing. Good quality products are usually obtained and major post-processing treatment is not required. However, residual stresses which exist in plastic parts affect the final shape and mechanical properties after ejection. Residual stresses are caused by polymer melt flow, pressure distribution, non-uniform temperature field, and density distribution. Residual stresses are predicted in this study by numerical methods using commercially available softwares, $Hypermesh^{TM},\;Moldflow^{TM}\;and\;ABAQUS^{TM}$. Cavity filling, packing, and cooling stages are simulated to predict residual stress field right after ejection by assuming an isotropic elastic solid. Thermo-viscoelastic stress analysis is carried out to predict deformation and residual stress distribution after annealing of the part. Residual stresses are measured by the hole drilling method because the automotive part selected in this study has a complex shape. Residual stress distribution predicted by the thermal stress analysis is compared with the measurement results obtained by the hole drilling method. The molded specimen has residual stress distribution in tension, compression, and tension from the surface to the center of the part. Viscoelastic deformation of the part is predicted during annealing and the deformed geometry is compared with that measured by a three dimensional scanner. The viscoelastic stress analysis with a thermal cycle will enable us to predict long term behavior of the injection molded polymeric parts.

• 대한원격탐사학회지
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• 제28권3호
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• pp.267-276
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• 2012

Terminal lakes are widely distributed in the arid and semi-arid Gobi of Mongolia, and serves as important water resource for local people and livestock. However, such lakes are subject to great fluctuations in its size depending on climatic conditions and human water utilization. The Orog Lake is one such example that has shown remarkable fluctuation in recent years. In this study, we investigated the temporal changes of Orog Lake surface area by using 16-day MODIS 250 m NDVI products from 2000 to 2010. The results were compared with climate variability represented by monthly precipitation and temperature. Our results show that the Orog Lake gradually shrank for the period from 2000 to 2010, but with a significant range of seasonal and inter-annual variability. The lake area showed considerable seasonal variations, as it expanded in spring and fall, primarily due to snow melt and summer precipitation, respectively. Extreme drought period from 2000 to 2002 triggered the substantial reduction in lake area, leading to dry-up in year 2005, 2006, 2007, and 2009. After dry-up once occurred in 2005, the lake repeated reappearance and disappearance depending on seasonal and annual precipitation. Our findings implicate that the ground water fluctuated around the lake bottom level since 2005. This suggests the highly vulnerable nature of Orog lake, which greatly depends on future precipitation change.

• 폴리머
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• 제29권3호
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• pp.314-319
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• 2005

촉매인 stannous octeate 존재 하에서 글리콜리드를 이관능성 개시제인 1,4-butanediol, 1,6-hexanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol과 반응시켜 4가지 종류의 새로운 지방족 디올을 합성하였다. 이들 새로운 디올과 succinic acid, adipic acid, 혹은 suberic acid와 titanium(IV) isopropoxide 촉매하에서 170, 190, 또는 $220^{circ}C$에서 축합중합 시켜 분자구조가 규칙적으로 배열된 새로운 지방족 폴리에스테르와 무질서한 구조를 갖는 폴리에스테르를 각각 얻었다. 이들 지방족 폴리에스테르들의 유리전이온도($T_g$)는 -40에서 $30^{circ}C$ 사이였다. 또한 $170^{circ}C$에서 제조된 분자구조가 규칙적으로 배열된 폴리에스테르가 높은 온도에서 합성된 구조가 무질서한 폴리에스테르들보다 $T_g$가 $5-10^{circ}C$ 정도 높았다. 체외분해 실험 결과, 분자구조가 규칙적으로 배열된 폴리에스테르가 불규칙한 중합체보다 완충용액 속에서 가수분해속도가 느렸다.

• 한국주조공학회지
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• 제31권2호
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• pp.66-70
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• 2011

Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

• 한국결정성장학회지
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• 제5권3호
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• pp.250-260
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• 1995

일반적으로 floating zone법에 의한 결정성장시에는 소결봉이 원료로서 사용되며 이러한 원료봉의 소결조건에 의해 결정성장시 안정성이 영향을 받게 된다. 그 원인은 FZ법에 의한 결정성장시 소결조건에 따른 원료봉의 미세구조의 변화가 소결봉과 융액사이의 계면형태를 변화시키기 때문이다. 본 연구에서 FZ법에 의해 $TiO_2$(rutile)과 ruby 단결정을 성장하였으며 이를 통해 소결봉의 미세구조가 FZ법에 의한 결정성장시에 용융대의 안정서에 미치는 영향을 분석하였다.$TiO_2$(rutile)과 ruby의 결정성장에 사용되는 원료봉의 소결시 소결온도가 높아지고 소결시간이 길어질수록 원료봉 중앙부와 바깥ㅂ분의 입자크기의 차이가 커져서 결국에는 그로 인하여 원료봉의 용융양상이 바뀌어졌다. FZ법에 의한 결정성장시 원료봉의 최적소결 조건은 입자의 크기가 소결봉 전영역에 걸쳐 균일하게 분포되는 것이었다. 반면 일반 적으로 중요하다고 여기는 소결봉의 porosity는 FZ법에 의한 결정성장시 영향력 있는 인자가 아니라는 점을 소결하지 않은 원료봉을 사용해 결정성장 실험을 행하여 봄으로써 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제14권5호
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• pp.2092-2099
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• 2013

현재 광디스크 드라이브는 오랜 기간 지속된 산업계의 데이터 전송률 경쟁을 통하여 10,000 rpm 이상의 고속으로 구동되고 있다. 고속 구동은 필연적으로 시스템의 진동을 유발하여 픽업의 데이터 읽기/쓰기 서보 제어에 외란을 야기하는데, 통상 진동외란은 방진고무를 통한 진동의 절연 및 서보 제어의 강인성 개선을 통해 해결되고 있다. 본 연구에서는 산업계에서 일상으로 이루어지는 광디스크 드라이브 시스템의 동특성 개선에서 한걸음 더 나아가 광디스크의 동특성을 개선하는데 주목하였다. 이를 위하여 사출성형 공정해석을 수행하여 공정 조건(유량, 사출온도)이 잔류응력에 미치는 영향을 조사하였고, 이 잔류응력의 변화가 광디스크의 진동 모드 및 임계속도 즉, 동특성에 미치는 영향을 모달해석을 통해 살펴보았다. 이러한 일련의 과정을 통해 사출성형 시 발생하는 광디스크의 잔류응력을 제어하여 광디스크의 임계속도를 잔류응력이 없는 경우 대비 약 14.4% 높일 수 있음을 확인하였다.

• 자원환경지질
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• 제33권2호
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• pp.147-163
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• 2000

The Buseok pluton in the Yeongju Batholith is a comagmatic plutonic rocks which haveconcentrically compositional zoning. The lithofacies of the Buseok pluton comprise hornblende biotite tonalite in the southern part of the pluton, porphyritic and equigranular biotite granodiorite in the northern part and biotite granite in the north-central part. The compositional variations change gradually with continuity both within and between the lithofacies. The concentrically zoned pattern is relatively mafic rocks composed of high-temperature mineral assemblages in margin of the southern part, passing inward and northward gradually to more felsic rock in core of the north-central part. Changes in the textures and microstructures, as well as in the mineral content, take place between rock types of the plutons. Darker colored, generally coarse-grained, well foliated tonalite pass inward to light colored, coarse-grained, poorly foliated granodiorite, and finally give way to lighter colored, medium-grained, nearly nonfoliated granite. The foliation are best developed in the marginal part of the tonalite. Here, the regional myolitic foliation in the tonalite is steep northward and parallels to its southeastern contact with the country rock, but the magmatic foliation from disc-shaped mafic microgranitoid enclaves is subvertical and parallels the contacts with the country rock. As the tonalite approaches biotite granite in composition, the foliation is indistinct. Modal and chemical data for the pluton show quantitative compositional variation from the margin of the southern part to the core of the north-central part. Quartz and K-feldspar increase toward the core of the pluton, whereas hornblende, biotite and color index decrease. /Abundances of $SiO_2$and $K_2O$$_2$O increase toward the core according to the variation in quartz and K-feldspar, whereas those of MnO, CaO, $TiO_2$, $Fe_2O_3$, MgO and $P_2O_5$ decrease corresponding to the variation in mafic and accessaries. The compositional zonation resulted from fractional crystallization involving downward settling of earlier crystals, accompanied by upward movement of melt and volatiles, and followed by accessary marginal accretion of crystalline material in the magma to the marginal part. Although a little crustal contamination by the wall rock is recognized from the isotope data, the contamination is not only dominated over but also appropriate for forming the compositional variation in the pluton.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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• pp.135-140
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• 1997

The influences of ZrB$_2$ additions to SiC on microstructural, DDM(Electrical Discharge Machining), mechanical and electrical properties were investigated. composites were prepared by adding 15, 30, 45 vol.% ZrB$_2$particles as a second phase to SiC matrix. SiC-ZrB$_2$ composites obtained by hot pressing for high temperature structural application were fully dense with the relative densities over 99%. The fracture toughness of the composites were increased with the ZrB$_2$contents. In case of composite containing 30vol.% ZrB$_2$, the flexural strength and fracture toughness showed 45% and 60% increase, respectively compared to that of monolithic SiC sample. The electrical resistivities of SiC-ZrB$_2$ composites decreased significantly with the ZrB$_2$ contents. The electrical resistivity of SiC-30vol.% ZrB$_2$ composite showed 6.50$\times$10$^{-4}$ $\Omega$.cm. Cutting velocity of EDM of SiC-ZrB$_2$ composites are directly proportional to duty factor of pulse width. Surface roughness, however, are not all proportional to pulse width. Higher-flexural strength composites show a trend toward smaller crater volumes, leaving a smoother surface; the average surface roughness of the SiC-ZrB$_2$ 15 vol.% composite with the flexural strengthe of 375㎫ was 3.2${\mu}{\textrm}{m}$, whereas the SiC-ZrB$_2$ 30.vol% composite of 457㎫ was 1.35${\mu}{\textrm}{m}$. In the SEM micrographs of the fracture surface of SiC-ZrB$_2$ composites, the SiC-ZrB$_2$ two phases are distinct; the white phase is the ZrB$_2$and the gray phase is the SiC matrix. In the SEM micrographs of the EDM surface, however, these phases are no longer distinct because of thicker recast layer of resolidified-melt-formation droplets present. It is shown that SiC-ZrB$_2$ composites are able to be machined without surface cracking.

• 한국재료학회지
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• 제12권2호
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• pp.140-145
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• 2002

This study was conducted to investigate the brazing characteristics between Zircaloy-4 nuclear fuel cladding tubes and bearing pads with filler metals of amorphous $Zr_{1-x}Be_x$(0.3$\leq$x$\leq$0.5) binary alloy, in which they were produced in the ribbon form by the melt-spinning metod. The crystallization behavior, stability, hardness and micro-structure of brazed zone were examined by X-ray diffraction, differential scanning calorimetry, micro-Vickers hardness test, optical microscopy, and transmission electron microscopy. $Zr_{1-x}Be_x$(0.3$\leq$x$\leq$0.4) amorphous alloys were crystallized to $\alpha$-Zr with increasing the temperature, and the rest were transformed to ZrBe$_2$at higher temperatures. On the other hand, $Zr_{1-x}Be_x$(0.4$\leq$x$\leq$0.5) amorphous alloys were crystallized to $\alpha$-Zr and ZrBe$_2$, simultaneously. The thickness of the layer brazed with amorphous alloy was increased with increasing the beryllium content due to the higher diffusion of Be. The morphology of brazed layer with PVD Be filler metal showed dendrite while that brazed with amorphous alloys appeared globular. Micro-Vickers hardness of brazed zone increased as the beryllium content of filler metal was decreased.

• 한국결정성장학회지
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• 제11권4호
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• pp.180-183
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• 2001

Developed Edge-defined film-fed growth (EFG)법으로 $YVO_{4}$ 및 Nd:$YVO_{4}$ 단결정을 성장하였으며 성장된 결정의 광학적 특성을 측정하였다. $YVO_{4}$ 및 Nd:$YVO_{4}$ 단결정 모두 투명하였으며, 결정성장 동안 융액 표면 온도의 균질 및 meniscus의 안정화로 고품질의 결정을 얻을 수 있었다. 투과 및 흡수 스펙트럼 측정 결과에서 $YVO_{4}$ 단결정은 340 nm에서 1000 nm까지 대체로 넓은 영역에서 높은 투과율이 나타났지만, Nd:$YVO_{4}$ 단결정은 532, 593, 753, 807, 888 nm의 특정한 영역에서 흡수 peak들이 나타남을 획인할 수 있었다. 또한 Photoluminescence (PL) 스펙트럼을 측정한 결과, 800~900 nm의 영역에서 에너지 방출을 관찰할 수 있었다.