• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1988년도 춘계학술대회 논문집
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• pp.49-51
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• 1988

The heat treatment condition and aging behavior of melt spun amorphous $Fe_{78}B_{13}Si_9$(Metglas 26058-2) were studied with investigating its magnetic properties, i.e., Br, $B_l$, Hc. The optimum heat treatment condition was $400^{\circ}C$, 1 hour under the external field of 200e, and aging was due to the surface oxidation and the appearance of local CSRO (chemical short lange order) with time and temperature. In addition. we investigated the effects of the thickness of the amorphous ribbons on the magnetic properties and aging effect of them.

• 한국주조공학회지
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• 제27권4호
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• pp.167-172
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• 2007

In the present study, the microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy have been investigated. Stable (fcc ${\alpha}$-Al and diamond cubic ${\beta}$-Ge) and various metastable crystalline (monoclinic, rhombohedral) phases were produced by competitive phase selection during non-equilibrium processing methods i.e. melt spinning and injection casting. The as-injection casted samples containing metastable-equilibrium eutectic (${\alpha}$-Al + monoclinic) structure showed much higher strength than samples with equilibrium eutectic (${\alpha}-Al+{\beta}-Ge$) structure but plasticity disappointingly diminished. In order to endow the enhanced ductility without significant strength drop, the alloys was heat-treated at transition temperature from metastable phase to stable phase. The annealed specimen displayed the phase transformed microstructural evolution and enhanced macroscopic plasticity.

• Korea-Australia Rheology Journal
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• 제13권1호
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• pp.1-12
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• 2001

This paper describes the application of our recently developed two-phase model for flow-induced crystallization (FIC) to the simulation of fiber spinning and film blowing. 1-D and 2-D simulations of fiber spinning include the combined effects of (FIC), viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity and the process dynamics are modeled from the spinneret to the take-up roll device (below the freeze point). 1-D model fits and predictions are in very good quantitative agreement with high- and low-speed spinline data for both nylon and PET systems. Necking and the associated extensional softening are also predicted. Consistent with experimental observations, the 2-D model also predicts a skin-core structure at low and intermediate spin speeds, with the stress, chain extension and crystallinity being highest at the surface. Film blowing is simulated using a "quasi-cylindrical" approximation for the momentum equations, and simulations include the combined effects of flow-induced crystallization, viscoelasticity, and bubble cooling. The effects of inflation pressure, melt extrusion temperature and take-up ratio on the bubble shape are predicted to be in agreement with experimental observations, and the location of the frost line is predicted naturally as a consequence of flow-induced crystallization. An important feature of our FIC model is the ability to predict stresses at the freeze point in fiber spinning and the frost line in film blowing, both of which are related to the physical and mechanical properties of the final product.l product.

• 한국재료학회지
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• 제13권9호
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• pp.619-624
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• 2003

This paper describes a method to control Mn and Fe contents in recycled AZ91D ingots, based on the mutual solubility of Mn and Fe in AZ91 alloy melts. For this purpose, Fe solubility with the change of Mn content and temperature was investigated in the homogenized and re-precipitated liquid AZ91 alloy. The increase of the amount of Mn added to the melt resulted in the decrease of Fe content. The data obtained in this study was adopted to the pilot plant for recycling of the scrap. As a result, Mn and Fe contents measured in the recycled ingot were in good agreement with ASTM B93 standard.

• 열처리공학회지
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• 제25권3호
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• pp.126-133
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• 2012

Semi-solid forming of the high melting point alloys such as steel is a promising near-net shape forming process for decreasing manufacturing costs and increasing the quality of the final products. This paper presents the microstructure characteristics of SKH51 (high speed tool steel) during heating and holding in the mushy zone between $1233^{\circ}C$ and $1453^{\circ}C$, which has been measured by differential scanning calorimetry (DSC). The results of heating/holding experiments showed that the grain size and the liquid fraction increased gradually with temperature up to $1350^{\circ}C$. The drastic grain growth occurred at heating above $1380^{\circ}C$. The strain-induced melt-activated (SIMA) process has been applied to obtain globular grains in the billet materials. Working by mechanical upsetting and successive heating of SKH51 into the temperatures in the mushy zone resulted in globular grains due to recrystallization and partial melting.

• 한국주조공학회지
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• 제26권1호
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• pp.34-39
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• 2006

In the present study, the possibility of Mg-Zn-Y alloys as high temperature casting alloys has been investigated. The fluidity of alloys containing yttrium were better than that of commercial AZ91 alloy because the oxide layer on the surface reduced the reaction between melt, and air and mold, which would reduce the resistance during the process of filling the mold. However, this oxide film reduced the hot-tearing resistance. In the case of ZAW942, this alloy exhibited fluidity and hot-tearing resistance better than AZ91 alloy. Because of thermally stable quasicrystal and other phases obstructed the movement of grains, the creep resistance of alloys containing rare earth elements more than 2 wt% was better than that of AZ91 alloy.

• 한국주조공학회지
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• 제17권3호
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• pp.267-275
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• 1997

Fabrication of high strength Mg-Li-Al alloys by squeeze casting was established by the stabilization of melt and mold temperatures, applied pressure and the refining method. The entrapment of inclusions during pouring was prevented using 30 ppi alumina foam filter. The as-cast microstructure consists of a mixture of ${\alpha}$ and ${\beta}$ phases including AILi and $MgLi_2$, Al particles, which are distributed in the ${\beta}$ matrix. The grain sizes of gravity and squeeze casting alloys were 288 ${\mu}m$ and 207 ${\mu}m$ respectively. The addition of Al in Mg-Li alloys promoted the formation of second phase particles, which were adjusted to optimize the properties of Mg-Li-Al alloys. The Mg-10wt%Li-5wt%Al alloy after heat treatment at $350^{\circ}C$ for 1 hour showed the maximum hardness value. This is due to the facts that the amounts of ${\alpha}$ and ${\beta}$ phases and their distributions are dependent upon the solution treatment temperature, and that the amounts of AILi and $MgLi_2Al$ particles are dependent upon the Al content.

• 한국세라믹학회지
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• 제34권6호
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• pp.591-600
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• 1997

Al2O3/Al composites were produced by displacement reaction method, which was carried out by immersing the sintered silica preform, which was prepared from fused silica powder, in molten aluminum. Because the molten aluminum did not penetrate into the silica preform with higher than 20% of porosity when the displacement reaction was accomplished at 100$0^{\circ}C$ for 10 hours in air atmosphere, the optimum range of sintering temperature of silica preform was from 135$0^{\circ}C$ to 140$0^{\circ}C$. The microstructure of this Al2O3/Al composites showed three-dimentionally co-continuous alumina, which provides wear resistance and high stiffness, and aluminium which acts as a toughnening phase. The grain size of the alumina in composites did not change with the particle size of the silica preform. The exact shape of the preform was retained and a net-shaped composite was produced. The representative Al2O3/Al composite prepared in this study showed 3.30mg/㎤ of bulk density, 350-430 MPa of flexural strength, 7.0 MPa.m1/2 of fracture toughness, and good machinability.

• Macromolecular Research
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• 제15권7호
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• pp.662-670
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• 2007

The crystallization behavior and fine structure of poly(ethylene terephthalate) (PET)/A-zeolite nanocomposites were assessed via differential scanning calorimetry (DSC) and time-resolved small-angle X-ray scattering (TR-SAXS). The Avrami exponent increased from 3.5 to approximately 4.5 with increasing A-zeolite contents, thereby indicating a change in crystal growth formation. The rate constant, k, evidenced an increasing trend with increases in A-zeolite contents. The SAXS data revealed morphological changes occurring during isothermal crystallization. As the zeolite content increased, the long period and amorphous region size also increased. It has been suggested that, since PET molecules passed through the zeolite pores, some of them are rejected into the amorphous region, thereby resulting in increased amorphous region size and increased long period, respectively. In addition, as PET chains piercing into A-zeolite pores cannot precipitate perfect crystal folding, imperfect crystals begin to melt at an earlier temperature, as was revealed by the SAXS profiles obtained during heating. However, the spherulite size was reduced with increasing nanofiller content, because impingement between adjacent spherulites in the nanocomposite occurs earlier than that of homo PET, due to the increase in nucleating sites.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3252-3258
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• 2010

In this study, the effects of the various parameters of spinning and drawing processes on the properties of polyester full drawn yarn (FDY) prepared by steam processing during high-speed spinning were investigated using several techniques. The wet shrinkage ratio of the FDY was able to be manipulated by controlling the temperature and draw ratio. The FDY made using the steam high speed spinning technique exhibited identical properties (such as tenacity, elongation, and wet shrinkage ratio) to that of regular FDY, made using the spin-draw process. FDY prepared using the steam process during high-speed spinning showed excellent dyeability. The dye pick-up of the polyester yarn spun at high-speed spinning was found to be improved when dyed under an atmospheric pressure of $100^{\circ}C$. This result was the same as regular FDY dyed under a high pressure of $130^{\circ}C$.