• Title/Summary/Keyword: Melt protection

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Melt Protection Property and Ignition Resistance Property of CaO added AZ91D Mg Alloy (CaO이 첨가된 AZ91D 마그네슘 합금의 발화저항특성 및 용탕보호특성 평가)

  • Lee, Jin-Kyu;Ha, Seong-Ho;Kim, Young-Jig;Jo, Hyung-Ho;Kim, Shae-K.
    • Journal of Korea Foundry Society
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    • v.27 no.3
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    • pp.131-134
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    • 2007
  • [ $SF_6$ ] gas that is used as a protective cover gas for Mg and Mg alloys during melting and casting has extremely high greenhouse effect. CaO added Mg alloys could maintain their original mechanical properties and original abilities such as fluidity and hot tearing susceptibility. The ignition temperature increased with increasing CaO addition under ambient atmosphere and nitrogen atmosphere. The minimum amount of $SF_6$ gas decreased by 0.13 wt%CaO added AZ91D Mg alloy in the sealed condition.

ELECTRICAL BREAKDOWN INITIATION OF ANODIC FILMS DURING ANODIZING IN MOLTEN BISULPHATE MELT

  • Han, S.H.;Thompson, G.E.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.341-343
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    • 1999
  • The morphology and composition of anodic films, formed on aluminium at various current densities, in the range $1-100{\;}Am^{-2}$, in the molten bisulphate melt at different temperatures (418-498K), have been studied using transmission electron microscopy of ultramicrotomed film sections, and ion beam thinned films. The first sign of incipient breakdown revealed by transmission electron microscopy of stripped films, is always the appearance of dark regions about 1,000 nm in diameter, representing local overgrowth of the film. The breakdown mechanism is closely related to thermal effects, because temperature rises at regions representing local overgrowth in the stripped films were observed at voltages close to the breakdown voltage, likely arising through impact ionization.

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METALLIC COATING PROTECTION ON DIELECTROMAGNETS PREPARED FROM MIXTURE OF HARD MAGNETIC POWDERS

  • Slusarek, Barbara;Wasenczuk, Andrzej
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.687-689
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    • 1995
  • Our team works on mixture of hard magnetic materials. As hard magnetic material we used mixture of powders: melt-spun ribbon Nd-Fe-B, ferrite and Alnico. Their different mixtures are basic material for dielectromagnets under our investigation. Main disadvantage of dielectromagnets with Nd-Fe-B alloy powder as a component is a low corrosion resistance. Protection against corrosion is covering dielectromagnets with metallic or organic coating film. The coating film protects dielectromagnets from free particles on the surface and low resistance for mechanical stresses too. The surface of dielectromagnets prepared from mixture of powders if formed by metallic particles - powder of Nd-Fe-B and Alnico, particles of oxide - powder of ferrite and particles of resin - bonding materials. Team work on technology of laying the metallic coating on dielectromagnets prepared from mixture of mentioned powders. Papers show the results of initial investigation on metallic coating technology. It shows influence of type and used technology of the metallic coating film on magnetic properties of dielectromagnets.

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A Study on the Electrochemical Properties Fabrication Process of Mg-Ca Sacrificial Anode for the Corrosion Protection of Steel Structures (철 구조물의 부식방지를 위한 Mg-Ca 희생양극의 전기화학적 특성과 제조에 관한 연구)

  • Park, Kang-Geun;Kim, Hye-Sung
    • Journal of Korean Association for Spatial Structures
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    • v.6 no.4 s.22
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    • pp.73-80
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    • 2006
  • It is an object of the present paper to investigate a electrochemical properties of Mg-based sacrificial anodes and the effect of calcium added from calcium chloride into magnesium on the melt protection during the melting. Electrochemical data will be correlated with processing control variables, and the microstructural change by the addition of CaCl2. Small addition of calcium into magnesium from CaCl2 imparts beneficial effect in electrochemical properties of Mg alloys, primarily, through microstructural modifications. In addition, the protection effect of the melts surface of Ca with low melting point modification is obtained by adding Ca not more than 0.6%.

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Studies on the Physico-chemical Properties of Mixed Radioactive Waste Glass

  • Kim, C.W.;Choi, J.R.;Ji, P.K.;Park, J.K.;Shin, S.W.;Ha, J.H.;Song, M.J.;Hwang, T.W.;Park, S.J.
    • Journal of Radiation Protection and Research
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    • v.29 no.1
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    • pp.33-39
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    • 2004
  • In order to vitrify the W1 waste (ion-exchange resin(IER), zeolite, and dry active waste(DAW)) generated from Korean Nuclear Power Plants, a glass formulation development based on waste compositions and production rates was performed. A aluminoborosilicate glass, AG8W1, was formulated to vitrify the W1 waste in an induction cold crucible melter(CCM). The processability, product performance, and economics of the candidate glass were calculated using a computer code and were measured experimentally in the laboratory and CCM. The glass viscosity and electrical conductivity as the process parameters were in the desired ranges. Start-up and maintaining glass melt of the candidate glass were favorable in the CCM. The product quality of the glass such as chemical durability, phase stability, etc. was satisfactory. The vitrification process using the candidate glass was also evaluated to be operated as economically as possible.

CRYSTAL TRANSITION PROCESS DURING POST-BREAKDOWN IN THE MOLTEN SALT

  • Han, S.H.;Thompson, G.E.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.440-443
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    • 1999
  • The morphology and composition of anodic films, formed on aluminium at various current densities, in the range 1-$100{\;}Am^{-2}$, in the molten bisulphate melt at different temperatures (418-498K), have been studied using transmission electron microscopy of ultramicrotomed film sections, and ion beam thinned films. From the structural analysis of the electron diffraction patterns taken from the ultramicrotomed sections and ion beam thinned films, it can be concluded that the crystal modification process from ${\gamma}-Al_2O_3{\;}to{\;}{\alpha}-Al_2O_3$ proceeds in the following steps : (equation omitted)

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Effect of Foaming Temperature on Cell Structure of 606X Series Aluminum Alloy Metallic Foams (Foaming 온도에 따른 606X계 발포 알루미늄의 제조 특성)

  • Song, Yeong-Hwan;Park, Soo-Han;Jeong, Min-Jae;Kang, Kwang-Jung;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.28 no.2
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    • pp.79-84
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    • 2008
  • Metal foam is one of the most interesting materials with various multi-functional properties such as light weight, energy absorption, high stiffness and damping capability. Among them, energy absorption property has keen interests in the field of automotives for passenger protection. Nowadays, researches about pore size and porosity control of the foam are increased to correspond them. However, though energy absorption properties are improved, these results are not cost-effective process. In present research, however, as a part of improving the energy absorption property of metallic foams, 606X aluminum alloy was used for cell wall material which has higher strength than pure aluminum. And its morphological features are characterized. As a results, porosity and pore size are uniformity distribution with increasing foaming temperature in the case of 6061 alloy foams. 6063 alloy foam specimens have opposite tendency because of the influence of alloying element and viscosity of the molten melt.

An investigation of the nuclear shielding effectiveness of some transparent glasses manufactured from natural quartz doped lead cations

  • Kassem, Said M.;Ahmed, G.S.M.;Rashad, A.M.;Salem, S.M.;Ebraheem, S.;Mostafa, A.G.
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.2025-2037
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    • 2021
  • The influence of lead cations on natural quartz (QZ) from Egypt as a glass shielding material for the composition with nominal formula (10Na2O - (90 - x) QZ - xPbO (where x = 30, 35, 40, 45 and 50 mol %)) was examined. The studied samples are synthesized via the melt quenching method at 1050 ℃. The X-ray diffraction XRD patterns were confirmed the glass nature for studied samples. Moreover, the optical properties, and the transparency for all compositions were examined by UV-Vis spectroscopy. Also, the major elemental composition of the natural quartz were estimated via the X-ray fluorescence (XRF) technique. Further, the density and molar volume were determined. Furthermore, the nuclear shielding parameters such as, mass attenuation coefficient, effective atomic number, electronic density, the total atomic, and electronic cross sections as well as the mean free path, and the half value layer with different gamma ray energies (81 keV-1407 keV) were calculated. Besides, the results showed that the shielding behavior towards the gamma ray radiation for all glass samples was increased as the increment in PbO concentration in the glass system.

A Study on the Preparation of Powder Coatings Containing Halogen-Free Flame Retardant and Fire Safety (Halogen-Free 난연제를 포함하는 파우더 코팅소재 제조 및 화재안전성 연구)

  • Lee, Soon-Hong;Chung, Hwa-Young;Kim, Dae-In;Noh, Tae-Joon
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.47-58
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    • 2011
  • Halogen free intumescent flame retardants(IFRS), such as the mixture of melamine phosphate(MP) and char forming agents(pentaerythritol(PER), di-pentaerythritol(DiPER), tris(2-hydroxyethyl) isocyanurate(THEIC)), were prepared and characterized. Polypropylene(PP)/$IFR_S$ composites were also prepared in the presence of ethylene diamine phosphate(EDAP) as a synergist and used into flame retardant PP powder coatings. Thermoplastic PP powder coatings at 20 wt% flame retardant loading were manufactured by extruded and then mechanical cryogenic crushed to bring them in fine powder form. These intumescent flame retardant powder coatings($IFRPC_S$) were applied on mild steel surface for the purpose of protection and decorative. It is a process in which a $IFRPC_S$ particles coming in contact with the preheated mild steel surface melt and form a thin coating layer. The obtained MP flame retardant was analyzed by utilizing FTIR, solid-state $^{31}P$ NMR, ICP, EA and PSA. The mechanical properties as tensile strength, melt flow index(MFI) and the thermal property as TGA/DTA and the fire safety characteristics as limiting oxygen index(LOI), UL94 test, SEM were used to investigate the effect of $IFRPC_S$. The experimental results show that the presence of $IFR_S$ considerably enhanced the fire retardant performances as evidenced by the increase of LOI values 17.3 vol% and 32.6 vol% for original PP and $IFRPC_S$-3(PP/MP-DiPER/EDAP), respectively, and a reduction in total flaming combustion time(under 15 sec) in UL94 test of $IFRPC_S$. The prepared $IFRPC_S$-3 have good comprehensive properties with fire retardancy 3.2 mm UL94 V-0 level, LOI value 32.6%, tensile strength $247.3kg/cm^2$, surface roughness Ra $0.78{\mu}m$, showing a better application prospect. Through $IFRPC_S$-2(PP/MP-PER/EDAP) and $IFRPC_S$-3 a better flame retardancy than that of the $IFRPC_S$-1(PP/MP/EDAP) was investigated which was responsible for the formed more dense and compact char layer, improved synergy effect of MP and PER/DiPER.

A Study on the Operating Characteristics of Molded Case Circuit Breakers according to Temperature Rise (온도상승에 따른 배선용 차단기의 동작특성에 관한 연구)

  • Jung, Da-Woon;Kim, Jae-Ho
    • Journal of the Korean Society of Safety
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    • v.30 no.5
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    • pp.8-13
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    • 2015
  • Molded Case Circuit Breakers (MCCBs) are typically used to provide over current protection for electrical safety caused by short circuit faults and overloads in indoor low voltage power systems. The MCCB automatically connects and disconnects loads from the electrical source when the current reaches a value and duration that will cause an excessive. However, the MCCB sometimes is not interrupted due to a malfunction, nuisance tripping, or in a fire. Ensuring electrical safety is very important in a indoor low voltage power system. This paper presents the operating characteristics of MCCBs according to a temperature rise from room temperature to 160 degrees Celsius delivered by a radiant panel heater. The ABS 54c(rated current: 30A) of the hydraulic magnetic trip type was used in the experiments. The signals of temperature, voltage, and current were measured using the high accuracy Signal Conditioning Extensions for Instrumentation (SCXI) measurement system with the LabVIEW program manufactured by National Instruments. The operating characteristics were measured as functions of current amplitude and ramp-up rate. The MCCB tripping time decreased as a result of increasing current amplitude and ramp-up rate under a temperature rise condition, because the temperature and level of the current are directly proportional to the tripping time. Additionally, an instantaneous operation was observed after 8 times of the rated current, and the MCCB began to melt a surface temperature of around 300 degrees Celsius of. The experimental results coincided well with the operating curve.