• 자원환경지질
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• 제29권4호
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• pp.483-493
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• 1996

중부 옥천대에 분포하는 대보 화강암질 저반의 주원소, 미량원소 조성으로부터 조구조환경과 기원물질의 특징을 연구하였다. 화강암류는 흑운모 화강암, 조립질 반상화강암 및 화강섬록암으로 나눌 수 있다. 화강암류의 불규칙적인 Na, K 함량변화는 분별정출작용만으로 설명될 수 없고 기원물질의 불균질성이나 다양한 기원물질의 불완전한 혼합을 반영하는 것으로 생각된다. 대보 화강암에서 나타나는 친석 원소(LIL element)의 부화와 낮은 Ta/Hf비는 정상적인 칼크 알칼리 계열의 대륙 연변부 호 화강암의 특징과 부합된다. 희토류원소 변화양상으로 보아 $SO_2$ 함량이 높은 흑운모 화강암을 보다 염기성인 화강섬록암의 후기 분화체로 보기는 어렵다. 대보 화강암의 ${\varepsilon}_{Nd}(t)$값과 친석 원소의 함량은 서로 체계적인 변화를 보이지 않아 그들의 지화학적 특징이 초생적인 용융체와 지각 물질 사이의 혼합에 의해 규정되었을 가능성을 배제한다. 대보 화강암의 지구화학적 특징은 주로 기원물질의 고유한 불균질성을 반영한다고 보아진다.

• 한국전기전자재료학회논문지
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• 제26권12호
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• pp.920-923
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• 2013

In this paper, the characteristics of a carbon nanotube composite heat sink proposed to replace the advanced Al heat sinks for LED lighting devices were studied. Proposed CMP-PLA heat sink was made by mixing 20~70 wt% carbon nanotube, 20~70 wt% bio-degradable polymer of melt-blended PLA (poly lactic acid) and PBS (poly butylene succinate) and PLA nucleating agents composed of the mixture of soybean oil and biotites, at $150{\sim}220^{\circ}C$ with 1,000~1,500 rpm. Optical and electric characteristics of 7.5 W LED lighting devices using heat sinks with such prepared CMP-PLA were investigated. And, the properties of the heat, which was not released from the CMP-PLA type heat sinks, was also investigated. The color temperature of LED lighting devices using the CMP-PLA heat sinks was 5,956 K, which is x= 0.32 and y= 0.34 in the XY chromaticity, and the color rendering index was 75. The luminous flux and the luminous efficiency of LED lighting devices using the CMP-PLA heat sinks was 540.6 lm and 72.68 lm/W respectively. Measured initial temperature of the heat sinks was $27^{\circ}C$, and their temperature increased as time to be saturated at $52^{\circ}C$ after an hour.

• 한국주조공학회지
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• 제30권3호
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• pp.115-120
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• 2010

Recently, an advanced raw material supplying system in diecasting industry that molten metal produced by the raw material supplier can be directly delivered to the diecasting shops was proposed. It was known to have advantages of reducing melting process cost and improving working environment. However, for its successful mass production, the development of high insulation ladle is inevitable. In this study, the optimal mixing ratio of $SiO_2-Al_2O_3$ was investigated and the high insulation ladle with computer simulation result was built in a prototype and evaluated. The prototype which has refractory wall of $SiO_233%-Al_2O_3$ 35%-CaO 33% showed high insulation sufficient for carrying the Al molten metal for 138 minutes. Gas quantity result and SEM-EDS analysis on the melt poured in the ladle also showed extremely low level of 0.028 cc / 100 g and no penetration of Al molten metal into the refractory wall, satisfying the requirements for mass production.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.164-165
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• 2006

Carbon nanotube(CNT)-reinforced poly(ethylene-co-ethyl acrylate)(EEA) nanocomposites were prepared by melt mixing with a Haake internal mixer. The CNT loading was vaned from 0 to 20 wt%. The changes m CNT dispersion and shape were investigated with FE-SEM observation with and without the Tensile strain of 40%. The CNT was protruded over the fracture surface upon Tensile strain, which is a very interesting behavior.

• Macromolecular Research
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• 제13권2호
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• pp.81-87
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• 2005

Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared by the melt mixing technique. Mechanical, XRD, thermal and dynamic mechanical investigations are reported for the pure silicone rubber and blends. The mechanical properties, viz. the tensile strength, tear strength and elongation at break, of the silicone rubber decreased with the addition of LCP. The SEM study on the tensile fractured surface of the blends revealed that they had a two phase structure, and that the failure was mainly due to fiber pull out, which suggests that the VMQ and LCP are incompatible in all of the proportions examined in this study. However, the FTIR study shows that there was a partial interaction between the VMQ and LCP, but which may not be sufficient to grip the fibrils under the applied load. In the XRD analysis, it was observed that the crystalline structure of the silicone rubber deteriorated in the presence of LCP. The DMA study suggested that the storage modulus of the silicone rubber was improved with the addition of LCP, due to the high modulus of the LCP phase. The thermal stability of the silicone rubber was greatly reduced by the addition of LCP, due to the latter having a thermal stability lower than that of silicone rubber.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.519-521
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• 1996

Emerald (3BeO.Al2O3.6SiO2 : Cr3+) single crystals were crystals were grown by reflux method of temperature gradient in the flux solution of Li2O-MoO3-V2O5 system. The composition of flux materials were 3 mole ratio of MoO3-V2O5/Li2O, subtituted 0.2 mole% of K2O, Na2O, Nb2O5 etc to Li2O content, solved 10-15% of beryl to flux quantity and doped 1% of Cr2O3 to emerald amount. Those of mixing were melted at 110$0^{\circ}C$ in Pt containers of the 3 zone furnace of melt-growth-return to circulate continniously, specially it has been grown large emerald single crystal when thermal fluctuation was treated for 2hrs of once time a day at 1050-95$0^{\circ}C$ in growth zone, substitutional solid solution effect of Cr+3 ion for Al+3 to the growth of emerald single crystal was good. Emerald single crystals were c(0001) hexagonal crystal face of preferencial growth direction and m(1010) post side. When it had been durated for 5 months emerald single crystals of the firet size of 0.6mm thickness of seed crystal were grown 32$\times$65mm(c x m) of maximum size and 6.2mm thickness.

• 폴리머
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• 제26권4호
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• pp.462-467
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• 2002

Hot embossing 공정을 이용하여 광도파로 소자를 제조하기 위하여 polymethylmeth-acrylate (PMMA)와 polyvinylidenefluoride (PVDF)를 용융 혼합하여 물리적 성질과 광학적 특성을 조사하였다. PMMA/PVDF 혼합물의 유리전이온도 ($T_g$)는 PVDF의 함량이 증가할수록 감소하였다. 하지만 PVDF의 결정은 관찰되지 않았다. PMMA와 비교적 적은 양인 PVDF간의 분자수준의 상호작용에 기인하는 혼화성에 의하여 $T_g$는 감소하고 PVDF의 결정화를 방해하여 무정형성을 유지하는 것으로 판단되었다. PMMA/PVDF 혼합물의 전단점도는 PMMA와 PVDF 사이에서 나타나며 PMMA와 PVDF 사이의 상용성에 의해 PVDF의 함량이 증가할수록 감소하였다. PVDF의 함량이 증가할수록 불소분자의 첨가에 의한 분자의 분극률이 저하되어 혼합물의 굴절률과 흡수손실은 감소하고 투과율은 증가하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 초전도 자성체 연구회
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• pp.80-83
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• 2003

$SrSO_4$ were systematically added on Bi2212 from 0 to 10wt% to study the effect of Bi2212 superconductor tube characteristics. After mixing, the melted solution of Bi2212 and $SrSO_4$ was initially poured into the cylinder type of steel mold preheated at $550^{\circ}C$ for 30min and rotated at 1000rpm. Following that, tube was annealed at $840^{\circ}C$ for 72hrs. The tube dimension was 60 in diameter, 60mm in length and 2mm in thickness. XRD data suggests that there was no typical segregation phase related with $SrSO_4$. Well textured grain with typical 2212 phase was observed and average size was $20{\mu}m$. The measured critical current and critical current density of Bi2212 tube added by 5% $SrSO_4$ at 77K were 495A and $202A/cm^2$ respectively.

• 한국자동차공학회논문집
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• 제11권5호
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• pp.140-146
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• 2003

Metal matrix composites had generated a lot of interest in recent time because of their high specific strength and stiffness in specific properties. It was also highlighted as the material of frontier industry because strength, heat-resistance, corrosion-resistance and wear-resistance were superiored. In this study, the strength properties of $Al_{18}B_{4}O_{33}$/AC4CH composites were represented mixing the binder of $SiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_{4}O_{33}$/AC4CH was fabricated at the melt temperature of $760^{\circ}C$, the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa. Consequently, fatigue life was observed roughly in the order of AC4CH> nobiner> $SiO_2$, independently on crack propagation direction and stress ratio.

• 대한금속재료학회지
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• 제46권8호
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• pp.516-523
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• 2008

The effect of glass-frit size on microstructural evolution and electrical resistance of conductive silver paste was investigated. Silver paste was prepared by mixing 70 wt% commercial silver powder with $1.6{\mu}m$, 3 wt% Bi based glass-frit and 27 wt% organic vehicle. Two different sizes of glass-frit were obtained by ball-milling of commercial glass-frit ($3{\mu}m$) for 3 and 5 days, which had an average particle size of 1.0 and $0.5{\mu}m$. The smaller glass-frit was melt at low sintered temperature and rapidly spread between the silver particles, which is induced the dense networking among silver particles and strong adhesiveness to $Al_2O_3$ substrate. The silver film with smaller glass-frit sintered at $500^{\circ}C$ showed the small pore size and low porosity resulting in low electrical resistivity of $4{\mu}{\Omega}cm$.