• Title/Summary/Keyword: Melamine

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Coolant Effect on Gas Generator Propellant (가스발생기용 추진제에 대한 냉각제 효과)

  • Baek Gookhyun;Yim Yoo-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.2
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    • pp.1-8
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    • 2005
  • The effect of coolants has been studied on the burning properties of low burning rate HTPB/AP composite propellant containing Oxamide or Melamine as coolant for the gas generator. With increasing the content of coolant, the burning rate and the flame temperature could be lowered and the effect on flame temperature was about the same for two coolants. However due to the different thermal decomposition properties of coolant, the burning rate of Melamine propellant was found to abnormally decrease if $200{\mu}m$ AP was partially replaced with $6{\mu}m$ AP.

Curing Behavior and Adhesion Performance of Urea-Melamine-Formaldehyde (UMF) Resin by Staged Addition of Melamine (멜라민 첨가 순서에 따른 UMF 접착제의 경화거동과 접착력의 영향)

  • Xu, Guang-Zhu;Eom, Young-Geun;Lee, Young-Kyu;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.84-89
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    • 2009
  • The objective of this research was to investigate the curing behavior and adhesion performance of urea-melamine-formaldehyde (UMF) resin for the four types of UMF-1, UMF-2, UMF-3, and UMF-4 which synthesized by the staged addition of melamine. Also, various network structures of these resin types were discussed based on their different curing behavior and adhesion performance. The curing behavior was evaluated by DMTA and thermal stability was checked by TGA. Adhesion performance was evaluated by dry and wet shear strengths and the pH value of each cured resin was checked to see its effect on the adhesion performance. The results indicated that the UMF-1 resin type by the addition of melamine initially with the urea and formaldehyde at the same F/(U+M) rate showed the lowest thermal stability, rigidity (${\Delta}E^{\prime}$), temperature of tan ${\delta}$ maximum ($T_{tan}\;_{\delta}$), and wet shear strength, and pH value of cured resin. In wet shear strength, however, the UMF-4 resin type appears to be slightly higher than UMF-1 resin type.

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Studies on Adhesion of Fancy Veneer and Formaldehyde Emission of Wood-Based Floorings by Mole Ratios of Urea and Melamine (요소·멜라민 접착제의 수지 조성에 따른 마루판의 천연무늬단판 접착성 및 포름알데히드 방출에 대한 연구)

  • Kang, Eun-Chang;Park, Jong-Young;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.165-171
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    • 2002
  • This study was to investigate the adhesion properties of fancy veneer and base panels and formaldehyde emission of wood-based floorings bonded with urea-melamine formaldehyde adhesives. We focused on stoichiometric mole ratio of reactive functional groups. The urea-melamine formaldehyde adhesives were made at twelve different formaldehyde/urea-melamine mole ratios. The interlaminated shear strength and formaldehyde emission of wood-based floorings bonded with selected adhesive among these adhesives were examined. The results showed that the bonding properties were high and the formaldehyde emission was low as the adhesive consisted of stoichiometric mole ratio of formaldehyde/urea-melamine. Interlaminated shear strengths of HDF(High Density Fiberboard) flooring were over 14 kgf/cm2 at all mole ratios. At the mole ratio of 1.0, HDF flooring showed low value of formaldehyde emission of 953 mg/L. Interlaminated shear strengths of Plywood flooring were high, 14.02 kgf/cm2 at mole ratio of 1.4. At the mole ratio of 1.0, Plywood flooring showed low value of formaldehyde emission of 0.26 mg/L.

The Change of Housewives' Purchase Behaviors by Food Safety Incidents; in Relation to the Outbreak of 2008 Melamine Incident in Korea (식품안전사건사고에 따른 주부들의 식품 구매행동 변화 -2008년 멜라민 사건을 중심으로-)

  • Chae, Ok-Rye;Ko, Eun-Kyung;Bahk, Gyung-Jin
    • Journal of Food Hygiene and Safety
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    • v.25 no.2
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    • pp.180-184
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    • 2010
  • This study surveyed the change of housewives' purchase behaviors by food safety incidents; the outbreak of 2008 Melamine incident in Korea as for example. 565 housewives in Gunsan were interviewed in March 2009. 52.3% of respondents were regarded as unsatisfactory for food safety management in Korea. Despite the result of scientific assessment for melamine, 74.6% of respondents were yet regarded as health-threatening substance. By the point of before, during and after Melamine-related food safety incident, we were surveyed the level of purchase for melamine-related food items as five scales, the results were $2.47{\pm}0.97$, $1.80{\pm}0.92$ and $1.62{\pm}0.92$, respectively (p < 0.001). After the incident happened, the purchase level was even more reduced. This study also found that there were significance difference (p < 0.05) among the respondents' knowledge for melamine toxicity and food safety management in Korea concerning housewives' purchase behaviors, i.e. the more accurately for melamine toxicity and higher satisfactory of consciousness of food safety, there were less change of purchase behaviors. In conclusion, the consciousness of food safety and accurate knowledge of hazards were significantly affected for the change of housewives' purchase behaviors by food safety incidents. Therefore, it can be suggested that the need for more scientific risk communication strategies with consumer.

Flame Retardant Synergistic Performance between Cyclic Diphosphonate Ester and Melamine in Polyamide 6 (Polymide 6에서 Cyclic Diphosphonate Ester와 Melamine의 난연 효과)

  • Wang, Xueli;Jiang, Jianming;Yang, Shenglin;Jin, Junhong;Li, Guang
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.125-130
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    • 2008
  • A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

Treatment of Melamine by GAC Adsorption According to Adsorbent Size: Kinetics and Dispersion-Diffusion (흡착제 크기에 따른 GAC의 멜라민 흡착 처리 : 반응속도와 분산-확산)

  • Lee, Jai-Yeop;Lee, Sangjung;Han, Ihnsup
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.65-72
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    • 2013
  • Adsorption of melamine was examined using columns packed with granular activated carbon (GAC). Raw GAC was sieved with 20, 40, 60 and 80 mesh to determine the influence of adsorbent particle size on reaction and diffusion. The mass ratio of the adsorption capacity of GAC for melamine ranged from 9.19 to 11.06%, and adsorption rates increased with decreasing particle size within this range. Rate constants between 3.295 ~ 4.799 $min^{-1}$ were obtained using a pseudofirst-order equation that was used to determine adsorption kinetics. A surface diffusion model was adapted to take into account the unsteady-state equation of a spherical adsorbent by converting the surface concentration from a constant to a variable governed by a dispersion equation. The calculated values were fit with the experimental results by using the diffusion coefficients as regression parameters. The modified equation exhibited a more precise agreement with respect to the sum of the absolute error (SAE).

Adhesion Properties of Urea-Melamine-Formaldehyde (UMF) Resin with Different Molar Ratios in Bonding High and Low Moisture Content Veneers

  • Xu, Guang-Zhu;Eom, Young-Geun;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.2
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    • pp.117-123
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    • 2010
  • The objective of this research was executed to investigate the effect of molar ratio of formaldehyde to urea and melamine (F/(U+M)) of urea-melamine-formaldehyde (UMF) resin on bonding high and low moisture content veneers. For that purpose, UMF resin types with 5 different F/(U+M) molar ratios (1.45, 1.65, 1.85, 2.05, and 2.25) synthesized were used in present study. First, their curing behavior was evaluated by differential scanning calorimetry. Second, their adhesion performance in bonding high and low moisture content veneers was evaluated by probe tack and dry and wet shear strength tests. Curing temperature and reaction enthalpy decreased with the increase of F/(U+M) molar ratio. And the dry and wet shear strengthsof plywood manufactured from low moisture content veneers were higher than thoseof plywood manufactured from high moisture content veneers. Also, the maximum initial tack force on the low moisture content veneer was higher than that on the high moisture content veneer.

Corrosion Resistance of Cold Rolled Steel by Organic/Inorganic Hybrid Solution according to Composition of SiO2 polysilicate and Melamine (SiO2 polysilicate 및 Melamine 조성에 따른 유/무기하이브리드 용액에 의한 자동차용 냉연강판의 내식성)

  • Nam, Ki-Woo;Jeong, Hee-Rok;Ahn, Byung-Gun;Lee, Kwang-Ho
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.20-28
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    • 2016
  • This study has developed an organic/inorganic hybrid solution by addition of $SiO_2$ polysilicate and Melamine to the urethane. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. The urethane solution(U) and the urethane solution with $SiO_2$ polysilicate($US_7$) were generate a lot of corrosion. The urethane solution with $SiO_2$ polysilicate and melamine($US_7M_3$) was excellent in corrosion resistance, regardless of the steel type. In addition, corrosion resistance has been shown to depend on the tensile strength. The appearance of coating by U and $US_7$ solution is bumpy surface, and were a lot of fine defects. $US_7M_3$ solution is made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

Densification Characteristics of Softwood Veneers Treated by Resin Impregnation (침엽수단판의 수지함침처리에 의한 압밀화 특성)

  • 서진석
    • Journal of the Korea Furniture Society
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    • v.14 no.2
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    • pp.21-29
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    • 2003
  • This study was carried out to investigate characteristics of plywood overlaid with softwood veneers densified by resin impregnation and compression. The resin impregnability of Korean pine veneer under atmospheric pressure soaking was greater than that of larch, and impregnability of melamine resin was slightly greater than phenolic resin. It was suggested that resin impregnation ratio was affected by density and thickness of veneer. The largest melamine resin impregnation ratio of 50.7% was obtained with 1.26mm thick Korean pine veneer, and the lowest phenolic resin impregnation ratio of 11.7% with 3.41mm thick larch veneer. Therefore, it was suggested that the vacuum-pres sure-soak treatment is required at thick larch veneer. In densifying resin-impregnated veneers, densification ratio from 13.4 to 31.2% was obtained by high pressure from 15.6 to $20.8kgf/cm^2$. Impregnation of melamine resin also showed relatively greater at densification than that of phenolic resin. So it showed the degree of densification of about 20% or greater. It was seemed that adhesive bonding strength of plywood(base panel) which was directly pressed and overlaid with resin-impregnated veneer was affected by resin tackiness after resin impregnation followed by semi-drying. In laboratory scale, melamine resin impregnation was more favorable for the development of adhesive bonding strength owing to moisture control.

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