• Title/Summary/Keyword: Maximum TE

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pphotoemission study of rare-earth metal(Eu) on the CdTe(110) surface

  • Kwanghyun-Cho;Oh, J.H.;Chung, J.;K.H.ppark;Oh, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1994.02a
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    • pp.43-43
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    • 1994
  • We studied chemical reactio of Eu metal on the in situ cleaved CdTe(110) surface by pphotoemission sppectroscoppy using synchrotron radiation. The chamber was maintained with base ppressure $\leq$2${\times}$10-10 mb during the expperiment. The expperiment was carried out in pphoton Factory in Jappan. Core level pphotoemission sppectroscoppy was carried out with Al K${\alpha}$ Line. The CdTe simiconductor was determined to be pp-typpe with low dopping concentration from Hall measurement. We found that there are two reacted pphases of Te with Eu (related to divalent Eu and trivalent Eu, resppectively) from least square fitting of Te 4d sppectra, but three is no indication of Cd reaction. Trivalent Eu exists after roughly one monolayer depposition (600 sec. depposition time is considered as one monolayer), which is also observed at Eu 3d core level sppectra. Overlayer Eu is metallized after roughly 2 monolayers depposition, as can be deduced from the fact that metallic edge near Fermi level begins to appear. The intensity of core-level of Te decreases expponentially at the initial stage (near one monolayer) and after one monolayer depposition it decreases more slowly due to Te out-diffusion. We categorized the growth mode of Eu on CdTe as S-K growth mode (cluster formation after one monolayer deppisition) from the relative intensity pplot of Te 4d normalized to the cleaved surface. At cleaved surface band bending is already established due to surface defects. At first 100 sec. depposition time the shift toward lower binding side by 0.6 eV is found at all core level sppectra of all elements in semiconductor. This shift is considered as the re-adjustment of surface Fermi level to the pposition induced by Eu metal (0.2 eV above the valence band maximum).

Studies on the Selective Oxidation of Niobium Containing Mixed Metal Oxide Catalysts (니오비움 함유 복합 금속산화물 촉매의 선택산화반응에 관한 연구)

  • Kim, Young-Chul;Kim, Hyeong-Ju;Moon, Dong-Ju
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.129-134
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    • 1998
  • Conversion of propane to acrylonitrile via ammoxidation was studied using physically mixed catalysts composed of $Nb_2O_5(10{\sim}30wt%)$ and $V_{0.4}Mo_1Te_{0.1}$. Catalytic activities of ammoxidation were improved by adding strong acidic niobium oxide to $V_{0.4}Mo_1Te_{0.1}$, the selectivities to acrylonitrile+propylene being remained constant. The maximum activity was obtained at the mixing ratio 25wt% niobium oxide in $Nb_2O_5-V_{0.4}Mo_1Te_{0.1}$. Niobium oxide was found to be a selective catalyst for the oxidative dehydrogenation of propane.

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The thermal analysis of te-based media for the optical recording (광기록에 이용되는 Te-based media에 대한 열적 해석)

  • 이성준;천석표;이현용;정홍배
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.64-70
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    • 1995
  • We discussed the thermal analysis for a recording media with the variation of the laser pulse duration, the laser power and the temperature distribution in order to optimize the Te-based antireflection structure from the computer calculations. In the case that the radial heat diffusion is negligible, we can calculate the maximum temperature of the recording layer at the center of the spot by the Simple Model. The temperature profile of the recording layer is obtained from the Numerical Model by considering the total specific heat and the latent heat. As a result, the effect of the heat sinking acting as a thermal loss for the hole formation could be minimized by introducing the pulse with the hole formation duration(.tau.) below the thermal time constant(.tau.$_{D}$) of a dielectric layer. These requirments can be satisfied by using the dielectric thickness of the 2nd ART(Anti-Reflection Trilayer) condition or the dielectric materials with a low thermal diffusivity.y.

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Photoluminescent properties for CdTe crystal grown by Bridgman method (Bridgman 방법으로 성장된 CdTe의 광발광 특성)

  • Hong, Kwang-Joon;You, Sang-Ha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.42-45
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    • 2004
  • High quality CdTe single crystal for the solar cell fabrication was grown by vertical Bridgman method. The etch pits patterns of {111}surfaces of CdTe etched by Nakagawa solution was observed the {111} A composed of Cd atoms with typical triangle etch pits of pyramid mode. From the photoluminescence measurement on {111}A, we observed free exciton($E_x$) existing only higy quality crystal and neytral acceptor bound exciton($A^0$,X) having very strong peak intensity. Then, the full width at half maximum and binding energy of neutral acceptor bound exciton were 7 meV and 5.9 meV, respectively. By Haynes rule, an actibation energy of impurity was 59 meV. Therefore, the origins on impurity level acting as a neutral acceptor were associated Ag or Cu elements.

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Thermoelectric Properties of N-type 90% $Bi_2Te_3$+10% $Bi_2Se_3$ Thermoelectric Materials Produced by Melt spinning method and Sintering (Melt spinning법에 의한 n형 90% $Bi_2Te_3$+10% $Bi_2Se_3$ 열전소결체의 열전특성)

  • 김익수
    • Journal of Powder Materials
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    • v.5 no.1
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    • pp.50-56
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    • 1998
  • A new process using rapid solidification (melt spinning method) followed by pressing and sintering was investigated to produce the n-type thermoelectric ribbons of 90% $Bi_2Te_3$+10% $Bi_2Se_3$ doped with $CdCl_2$. Quenched ribbons are very brittle and consisted of homogeneous $Bi_2Te_3-Bi_2Se_3$ pseudo-binary solid solutions. Property variations of the materials was investigated as a function of variables, such as dopant $CdCl_2$ quantity and sintering temperature. When the process parameters were optimized, the maximum figure of merit was $2.146{\times}10^{-3}K^{-1}$.

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Effects of Sequential Trinexapac-Ethyl Applications and Traffic on Growth of Perennial Ryegrass (Lolium perenne L.)

  • Amiri-Khah, Rahim;Eetemadi, Nematollah;Nikbakht, Ali;Pessarakli, Mohammad
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.340-348
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    • 2015
  • Mowing turfgrasses, especially fast growing species like perennial ryegrass, is one of the most time and money consuming tasks of their management. Trinexapac-ethyl (TE) is a popular plant growth regulator used to reduce mowing requirements, improve stress tolerance, and enhance turf quality. This study was conducted to investigate the effect of TE rate and frequency of applications on growth response and traffic tolerance of perennial ryegrass. The experiment was a split-plot laid out in a randomized complete block (RCB) design with three replications. TE was applied to main plots at 0.00, 0.25, and $0.50kg\;a.i.\;ha^{-1}$. Application pattern included an initial application, followed by two sequential applications at 6-wk intervals. Traffic treatment was applied to subplots with a cleated roller. Results demonstrated that TE consistently reduced vertical shoot growth, clippings dry weight, with maximum growth reduction of 59% and 65%, for 0.25 and $0.50kg\;a.i.\;ha^{-1}$, respectively, occurring at 2 weeks after initial TE treatment (WAT). Traffic also dramatically reduced vertical shoot growth and clippings dry weight. Overall, quality of perennial ryegrass was enhanced by sequential TE applications, however, turf quality and surface coverage reduced greatly under traffic, regardless of TE treatment. Total chlorophyll, chlorophyll a and chlorophyll b and total carbohydrates (TC) contents were also positively influenced following sequential TE application. Our results indicated that TE reduces mowing frequency and enhances turf quality rather than influencing traffic resistance.

The Direct TM01-TE11 Mode Converter Using Circular Waveguide for High Power Applications (원형 도파관을 이용한 초고출력용 TM01-TE11 직접 모드 변환기)

  • Lee Byoung-Moo;Lee Sang-Heun;Yoon Young-Joong;Yang Gi-Joo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.4 s.107
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    • pp.351-357
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    • 2006
  • In this paper, a direct $TM_{01}-TE_{11}$ mode converter of circular waveguide which is used the approximated design method of mode conversion between $TM_{01}$ and $TE_{11}$ modes is designed for radiation with the maximum directivity of high power energy into air (rom high power microwave antenna system. The proposed direct $TM_{01}-TE_{11}$ mode converter is calculated and designed with an approximated method for non-linear function about an extended non-constant serpentine type of circular waveguide. Then, the designed mode converter is optimized by length of 200 mm and efficiency above 95% by FIM simulation and achieved short length and high efficiency of the antenna by results of fabricated and measured characteristics.

Influence of the thermal preheating for the GaAs(100) substrate exerted on ZnTe epilayer (GaAs(100) 기판에 대한 열에칭이 ZnTe 에피층에 미치는 영향)

  • 남성운;유영문;오병성;이기선;최용대;정호용
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.348-354
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    • 1998
  • To investigate an influence of the thermal preheating for the substrates exerted on the heteroepilayers, the ZnTe epilayers are grown on the GaAs (100) at the substrate temperature of 450~$630^{\circ}C$ by hot wall epitaxy (HWE). For this purpose, double crystal rocking curve (DCRC) and photoluminescence (PL) are measured. The full width at half maximum of DCRC are the smallest in the ZnTe epilayers grown on the GaAs thermally etched at around both $510^{\circ}C$ and $590^{\circ}C$. However, at around $550^{\circ}C$ they increase due to the reconstruction of the atoms in the surface. And they increase due to the oxide layer at below $490^{\circ}C$ and due to the surface defects at above $610^{\circ}C$. From PL analysis, the full width at half maximum of the light hole exciton $X_{1s,th}$ and of the second-order Raman line increase at around $550^{\circ}C$. With the increasing preheating temperature, the intensities of Y-bands and of the oxygen bound exciton (OBE) peak related to an oxide layer on the GaAs surface generally decrease. From these experimental results, it's confirmed that the GaAs substrate thermally etched influences the ZnTe pilayers.

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Fabrication and Performance of $Bi_{0.5}Sb_{1.5}Te_{3}/Bi_{2}Te_{2.4}Se_{0.6}$ Thin Film Thermoelectric Generators ($Bi_{0.5}Sb_{1.5}Te_{3}/Bi_{2}Te_{2.4}Se_{0.6}$계 박막형 열전발전 소자의 제작과 작동 특성)

  • Kim Il-Ho;Jang Kyung-Wook
    • Journal of the Korean Vacuum Society
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    • v.15 no.2
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    • pp.180-185
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    • 2006
  • Microwatt power level at relatively high voltage(order of volt) was produced by $Bi_{0.5}Sb_{1.5}Te_{3}/Bi_{2}Te_{2.4}Se_{0.6}$ thin film thermoelectric generators, and maximum output power varied with temperature difference in the square-law relation. Output voltage and current were possible to control by changing the way of electrical connection as well as the number of stacking plate-modules. Variation of open circuit voltage and short circuit current with temperature difference showed a linear relationship. There were, however, some differences in variations; open circuit voltage were dependent on the number of plate-module when connected in series, but it was not for parallel connection. On the other hand, short circuit current showed the opposite behavior to the case of open circuit current.

A Fault Diagnosis and Control Integrated System for an SP-100 Space Reactor (SP-100 우주선 원자로를 위한 고장진단 및 제어 통합 시스템)

  • Na, Man-Gyun;Yang, Heon-Young;Lim, Dong-Hyuk;Lee, Yoon-Joon
    • Proceedings of the KIEE Conference
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    • 2007.10a
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    • pp.231-232
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    • 2007
  • In this paper, a fault diagnosis and control integrated system (FDCIS) was developed to control the thermoelectric (TE) power in the SP-100 space reactor. The objectives of the proposed model predictive control were to minimize both the difference between the predicted TE power and the desired power, and the variation of control drum angle that adjusts the control reactivity. Also, the objectives were subject to maximum and minimum control drum angle and maximum drum angle variation speed. A genetic algorithm was used to optimize the model predictive controller. The model predictive controller was integrated with a fault detection and diagnostics algorithm so that the controller can work properly even under input and output measurement faults. With the presence of faults, the control law was reconfigured using online estimates of the measurements. Simulation results of the proposed controller showed that the TE generator power level controlled by the proposed controller could track the target power level effectively even under measurement faults, satisfying all control constraints.

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